Bentorite (original) (raw)

A valid IMA mineral species

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About BentoriteHide

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Formula:

Ca6Cr2(SO4)3(OH)12 · 26H2O

Cr(III) may be partly replaced by Al.

Colour:

Violet to rose-purple

Lustre:

Resinous, Waxy, Earthy

Name:

Named in 1977 by Shulamit Gross in honor of Professor Yaakov K. Ben-Tor [February 13, 1910 Königsberg, East Prussia, Germany - October 29, 2002 La Jolla, California, USA], petrologist and geologist, Scripps Institute of Oceanography, University of California, San Diego, California, USA and Department head of Geology, Hebrew University, Jerusalem, Israel from 1954-1966, for his contributions to the geology and mineralogy of Israel and the Middle East.

Ettringite Group.
The Cr(III) analogue of ettringite.

Type locality: The late Gary Weinberger, who first found bentorite and sent it to a mineralogist for characterization, said that his discovery was made a short hike from the road "near" Arad.

Not to be confused with bentonite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:627:7

d3de445d-cd5c-4340-a1be-fa8145f83f4a

IMA Classification of BentoriteHide

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Classification of BentoriteHide

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7.DG.15

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3

31.10.2.2

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
10 : Miscellaneous

25.4.14

25 : Sulphates
4 : Sulphates of Ca, Sr and Ba

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Bto IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BentoriteHide

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Comment:

Originally said to be vitreous

Colour:

Violet to rose-purple

Cleavage:

Perfect
{1010} perfect; {0001} good

Density:

2.025 g/cm3 (Measured) 2.021 g/cm3 (Calculated)

Optical Data of BentoriteHide

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RI values:

_n_ω = 1.478 _n_ε = 1.484

δ = 0.006

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Parallel

Comments:

O = colorless; E = pale violet purple

Comments:

Absorption E > O

Chemistry of BentoriteHide

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Mindat Formula:

Ca6Cr2(SO4)3(OH)12 · 26H2O

Cr(III) may be partly replaced by Al.

Crystallography of BentoriteHide

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Class (H-M):

3_m_ - Ditrigonal Pyramidal

Cell Parameters:

a = 11.1927 (5) Å, c = 21.7121(5) Å

Unit Cell V:

2,355.60 ų (Calculated from Unit Cell)

Morphology:

Euhedral crystals very rare. Minute crystals (<< 1 mm) show first- and second-order prisms.

X-Ray Powder DiffractionHide

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Image Loading


Radiation - Copper Kα

Data Set:

Data courtesy of RRUFF project at University of Arizona, used with permission.

Powder Diffraction Data:

d-spacing Intensity
10.6 Å (1)
9.656 Å (100)
6.110 Å (4)
5.592 Å (40)
4.980 Å (4)
4.640 Å (3)
4.290 Å (3)
4.030 Å (3)
3.890 Å (8)
3.650 Å (6)
3.600 Å (10)
3.470 Å (6)
3.230 Å (10)
3.020 Å (5)
2.772 Å (10)
2.680 Å (3)
2.610 Å (3)
2.560 Å (6)
2.486 Å (3)
2.410 Å (3)
2.400 Å (3)
2.359 Å (6)
2.206 Å (8)
2.156 Å (4)
1.942 Å (20)
1.908 Å (5)
1.766 Å (3)
1.714 Å (3)
1.671 Å (3)
1.656 Å (3)
1.622 Å (6)
1.515 Å (6)

Geological EnvironmentHide

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Type Occurrence of BentoriteHide

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General Appearance of Type Material:

Fine-grained deep purple to light rosey purple masses and veinlet filling.

Place of Conservation of Type Material:

Geochemistry Department, Geological Survey of Israel, Jerusalem, Israel, number SG644.
Fairleigh-Dickinson University, Madison, New Jersey, USA.

Geological Setting of Type Material:

Auto-metamorphosed marble: Hatrurim Formation.

Associated Minerals at Type Locality:

Synonyms of BentoriteHide

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Other Language Names for BentoriteHide

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Relationship of Bentorite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.DG. Mathesiusite K5(UO2)4(SO4)4(VO5) · 4H2O Tet. 4/m : _P_4/n
7.DG.05 Darapskite Na3(SO4)(NO3) · H2O Mon. 2/m : _P_21/m
7.DG.10 Clinoungemachite (Na, K, Fe, SO4) Mon. 2/m
7.DG.10 Humberstonite Na7K3Mg2(SO4)6(NO3)2 · 6H2O Trig. 3 : _R_3
7.DG.10 Ungemachite K3Na8Fe(SO4)6(NO3)2 · 6H2O Trig. 3 : _R_3
7.DG.15 Charlesite Ca6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Ettringite Ca6Al2(SO4)3(OH)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Jouravskite Ca3Mn4+(SO4)(CO3)(OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Sturmanite Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12 · 25H2O Trig. 3_m_ : P_31_c
7.DG.15 Thaumasite Ca3(SO4)[Si(OH)6](CO3) · 12H2O Hex. 6 : _P_63
7.DG.15 Carraraite Ca3(SO4)[Ge(OH)6](CO3) · 12H2O Hex.
7.DG.15 Buryatite Ca3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2O Trig. 3_m_ : P_31_c
7.DG.15 Birunite Ca18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?)
7.DG.15 Hielscherite Ca3Si(SO4)(SO3)(OH)6 · 11H2O Hex. 6 : _P_63
7.DG.15 Kottenheimite Ca 3Si(SO4)2(OH)6 · 12H2O Hex. 6/m : _P_63/m
7.DG.15 Imayoshiite Ca3Al(CO3)[B(OH)4](OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Tatarinovite Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Siwaqaite Ca6Al2(CrO4)3(OH)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Chiyokoite Ca3Si(CO3)[B(OH)4]O (OH)5 · 12H2O Hex. 6 : _P_63
7.DG.20 Rapidcreekite Ca2(SO4)(CO3) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
7.DG.25 Tatarskite Ca6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2O Orth.
7.DG.30 Nakauriite Cu8(SO4)4(CO3)(OH)6 · 48H2O Orth.
7.DG.35 Chessexite (Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2O Orth.
7.DG.40 Carlosruizite K6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DG.40 Fuenzalidaite K6(Na,K)4Na6Mg10(SO4)12(IO3)12 · 12H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DG.45 Chelyabinskite (Ca,Mg)3(SO4,CO3)2[Si(OH)6] · 9H2O (?) Orth.
7.DG.55 Ramazzoite [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36] Iso. 43_m_ : P_43_m
7.DG.60 Witzkeite Na4K4Ca(NO3)2(SO4)4 · 2H2O Mon. 2/m : _B_2/b

Fluorescence of BentoriteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for BentoriteHide

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Localities for BentoriteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Israel
Southern District (HaDarom District) Arad Arad Stone Quarry Krüger +2 other references
Middle East (TL)
Hatrurim Formation (TL) Gross (1977)
Palestine
West Bank Jericho Governorate Nabi Musa Ella V. Sokol et al. (2011)
Quds Governorate Ma'ale Adumim - (n.d.) +5 other references