Argyrodite (original) (raw)

A valid IMA mineral species - grandfathered

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About ArgyroditeHide

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Up to about 40 mol-% of the sulfur may be replaced by selenium (Wang et al., 1984). Intermediate members of the argyrodite-canfieldite series are common and many specimens of that series prove to be different members of the series than the label suggests.

Crystal System:

Orthorhombic

Name:

Named by Julius A. Weisbach in 1886 from the Greek αργυρώδης ("argyrodes"), "silver-bearing", in allusion to its silver content.

Type locality material is usually botryoidal with crystallized surfaces are uncommon.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:331:3

3a203f74-6c11-42c1-8855-4a11702cae97

IMA Classification of ArgyroditeHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of ArgyroditeHide

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2.BA.70

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
B : Metal Sulfides, M: S > 1: 1 (mainly 2: 1)
A : With Cu, Ag, Au

2.5.6.1

2 : SULFIDES
5 : AmBnXp, with (m+n):p = 3:2

6.2.4

6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
2 : Sulphogermanates

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Agy IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Agy The Canadian Mineralogist (2019) The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of ArgyroditeHide

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Fracture:

Irregular/Uneven, Conchoidal

Density:

6.29 g/cm3 (Measured) 6.32 g/cm3 (Calculated)

Optical Data of ArgyroditeHide

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Reflectivity:

Wavelength R1 R2
400nm 28.9% 29.5%
420nm 27.9% 28.5%
440nm 27.1% 27.7%
460nm 26.3% 26.9%
480nm 25.8% 26.3%
500nm 25.3% 25.8%
520nm 25.0% 25.4%
540nm 24.7% 25.2%
560nm 24.6% 25.0%
580nm 24.5% 24.9%
600nm 24.4% 24.9%
620nm 24.5% 24.8%
640nm 24.6% 24.9%
660nm 24.5% 24.9%
680nm 24.6% 25.0%
700nm 24.7% 25.0%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 29.5%.
R1 shown in black, R2 shown in red

Colour in reflected light:

Grey-white with violet tint

Chemistry of ArgyroditeHide

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Mindat Formula:

Ag8GeS6

Up to about 40 mol-% of the sulfur may be replaced by selenium (Wang et al., 1984). Intermediate members of the argyrodite-canfieldite series are common and many specimens of that series prove to be different members of the series than the label suggests.

Common Impurities:

Fe,Sb,Sn

Crystallography of ArgyroditeHide

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Crystal System:

Orthorhombic

Class (H-M):

m _m_2 - Pyramidal

Cell Parameters:

a = 15.149(1) Å, b = 7.476(2) Å, c = 10.589(1) Å

Ratio:

a:b:c = 2.026 : 1 : 1.416

Unit Cell V:

1,199.25 ų (Calculated from Unit Cell)

Morphology:

Pseudo-octahedral, dodecahedral, cubes to 18cm

Twinning:

Pseudospinel {111}

Crystallographic forms of ArgyroditeHide

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Crystal Atlas:

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0014663 Argyrodite Eulenberger G (1977) Die kristallstrukture der tieftemperaturmodifikation von Ag8GeS6 Monatshefte fur Chemie 108 901-913 1977 synthetic 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.14 Å (30)
3.02 Å (100)
2.77 Å (10)
2.66 Å (40)
2.57 Å (5)
2.44 Å (30)
2.32 Å (5)
2.16 Å (10)
2.03 Å (30)
1.949 Å (10)
1.863 Å (50)
1.784 Å (20)
1.585 Å (10)
1.414 Å (5)
1.482 Å (10)
1.379 Å (5)
1.287 Å (5)
1.244 Å (10)
1.228 Å (5)
1.166 Å (20)

Comments:

ICDD 14-356 Machacamarca, Bolivia.

Geological EnvironmentHide

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Geological Setting:

Low temperature polymetallic deposits, high temperature Ag-Sn deposits.

Type Occurrence of ArgyroditeHide

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General Appearance of Type Material:

Small crystals with edges <1 mm, generally in aggregates.

Place of Conservation of Type Material:

Mining Academy, Freiberg, Germany, 7058.

Geological Setting of Type Material:

Low-temperature polymetallic deposit.

Reference:

Weisbach, A. (1886) Argyrodit, ein neues Silbererz. Neues Jahrbuch für Mineralogie, Geologie und Paläontologie: 2: 67-71.

Synonyms of ArgyroditeHide

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Other Language Names for ArgyroditeHide

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Relationship of Argyrodite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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2.BA. Orileyite (Fe,Cu)2As
2.BA. Alburnite Ag8GeTe2S4 Iso.
2.BA. Dzierżanowskite CaCu2S2 Trig. 3_m_ _(_32/m ) : _P_3_m_1
2.BA. Makotoite Ag12(Cu3Au)S8 Trig. 3_m_ _(_32/m ) : R_3_c
2.BA. Xuwenyuanite Ag9Fe3+Te2S4 Iso. 43_m_ : F_43_m
2.BA. Juxingite Bi6Cu140Fe30S125 Iso. 43_m_ : F_43_m
2.BA.05 Chalcocite Cu2S Mon. 2/m : _P_21/b
2.BA.05 Djurleite Cu31S16 Mon. 2/m
2.BA.05 Geerite Cu8S5 Trig. 3
2.BA.05 Roxbyite Cu9S5 Tric. 1 : _P_1
2.BA.10 Anilite Cu7S4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
2.BA.10 Digenite Cu9S5 Trig. 3_m_ _(_32/m ) : R_3_m
2.BA.15 Bornite Cu5FeS4 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
2.BA.20 Bellidoite Cu2Se Tet. 4/m : _P_42/n
2.BA.20 Berzelianite Cu2-xSe (x ≈ 0.12) Iso. m_3_m _(_4/_m_32/m ) : F m_3_m
2.BA.25 Athabascaite Cu5Se4 Orth.
2.BA.25 Umangite Cu3Se2 Tet. 42_m_ : P_421_m
2.BA.30 Rickardite Cu7Te5 Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
2.BA.30 Weissite Cu2-xTe Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
2.BA.35 Acanthite Ag2S Mon. 2/m : _P_21/m
2.BA.35 Spryite Ag8(As3+0.5As5+0.5)S6 Orth. m _m_2 : P n _a_21
2.BA.40 Mckinstryite Ag5-xCu3+xS4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
2.BA.40 Stromeyerite AgCuS Orth. m m m _(_2/_m_2/_m_2/m )
2.BA.40d UM2003-13-S:AgAuCu Ag6AuCu2S5
2.BA.42 Honeaite Au3TlTe2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c m
2.BA.45 Jalpaite Ag3CuS2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
2.BA.45 Kurilite Ag8Te3Se Trig. 3 : _R_3
2.BA.45 Selenojalpaite Ag3CuSe2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
2.BA.47 Spiridonovite (Cu1-xAgx)2Te Trig. 3_m_ _(_32/m ) : _P_3_c_1
2.BA.50 Eucairite AgCuSe Orth.
2.BA.50 Wuyanzhiite Cu2S Tet. 422 : _P_43212
2.BA.52 Argentite Ag2S Iso.
2.BA.55 Aguilarite Ag4SeS Mon. 2/m
2.BA.55 Naumannite Ag2Se Orth. 222 : _P_212121
2.BA.60 Cervelleite Ag4TeS Mon. 2/m
2.BA.60 Hessite Ag2Te Mon. 2/m : _P_21/b
2.BA.60 Chenguodaite Ag9Fe3+Te2S4 Orth.
2.BA.65 Henryite (Cu,Ag)3+xTe2 , with x ~ 0.40 Iso. m_3_m _(_4/_m_32/m ) : F d_3_c
2.BA.65 Stützite Ag5-xTe3, x = 0.24-0.36 Hex. 6 : _P_6
2.BA.70 Canfieldite Ag8SnS6 Orth. m _m_2
2.BA.70 Putzite (Cu4.7Ag3.3)GeS6 Iso. 43_m_ : F_43_m
2.BA.75 Fischesserite Ag3AuSe2 Iso. 432 : _I_4132
2.BA.75 Penzhinite (Ag,Cu)4Au(S,Se)4 Hex. 622 : _P_6322
2.BA.75 Petrovskaite AuAgS Mon.
2.BA.75 Petzite Ag3AuTe2 Iso. 432 : _I_4132
2.BA.75 Uytenbogaardtite Ag3AuS2 Trig. 3_m_ _(_32/m ) : R_3_c
2.BA.80 Bezsmertnovite (Au,Ag)4Cu(Te,Pb) Orth.
2.BA.80 Bilibinskite PbCu2Au3Te2 Iso.
2.BA.80 Bogdanovite (Au,Te,Pb)3(Cu,Fe) Iso.

Fluorescence of ArgyroditeHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for ArgyroditeHide

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Reference List:

Evain, M., Gaudin, E., Boucher, F., Petříček, V., Taulelle, F. (1998) Structures and phase transitions of the A7PSe6(A= Ag, Cu) argyrodite-type ionic conductors. I. Ag7PSe6. Acta Crystallographica: B54: 376-383.

Tamas, C.G., Bailly, L., Ghergari, L., O'Connor, G., Minut, A. (2006) New occurrences of tellurides and argyrodite in Rosia Montana, Apuseni Mountains, Romania, and their metallogenic significance. The Canadian Mineralogist: 44: 367-383.

Localities for ArgyroditeHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Arctic Ocean
Kolbeinsey Ridge North Kolbeinsey Ridge Seven Sisters vent field Marques et al. (2020)
Argentina
Catamarca Province Andalgalá Department Capillitas mining district La Argentina vein PUTZ +1 other reference
Ortiz vein PUTZ +1 other reference
Jujuy Province Rinconada Department Mina Pirquitas Pirquitas Mine Coira et al. (1995) +2 other references
San Miguel Open pit Oploca Vein System Strübel
Rinconada Pan de Azucar Mine Coira et al. (1995) +1 other reference
La Rioja Province Chilecito department Chilecito Cerro Negro mining district de Brodtkorb (2009) +1 other reference
Peregrina mine Brodtkorb (2002)
San Luis Province Coronel Pringles Department Carolina Gallard-Esquivel et al. (2018)
Santa Cruz Province Deseado Department Cerro Moro deposit Mugas Lobos et al. (2020)
Australia
New South Wales Phillip Co. Lue Bowdens Silver Project Pringle and Elliot 1998
Queensland Whitsunday Region Mount Carlton district Mount Carlton Mine Sahlström et al. (2017)
Bolivia
Oruro Poopó Province Poopó ? Salomon Rivas y Federico Ahlfeld (1998) +1 other reference
Potosí Antonio Quijarro Province Porco Municipality Agua de Castilla Porco Canfield (1907)
Huaylla Vinto Kempff et al. (La Paz, 2009)
Santiago Alto mine Kempff et al. (La Paz, 2009)
Tornohuaico mine Kempff et al. (La Paz, 2009) +1 other reference
Uyuni Municipality Carguaicollo Mine Federico Ahlfeld and Alejandro Schneider-Scherbina (1964)
Chayanta Province Colquechaca Municipality Colquechaca Federico Ahlfeld y Jorge Muñoz Reyes (1955) +1 other reference
Cornelio Saavedra Province Machacamarca subdistrict ? Mineralogical Society of America - ...
Sud Chichas Province Atocha Municipality Chocaya-Animas mining district (Animas-Chocaya mining district) Ánimas Mine Wilson (2001)
Chocaya mine Wilson (2001) +1 other reference
Tomás Frías Province Potosí (Potosí Municipality) Cerro de Potosí (Cerro Rico) ? Federico Ahlfeld and Alejandro Schneider-Scherbina (1964)
Bosnia and Herzegovina
Republika Srpska Srebrenica Čumavići deposit Slobodan A. Radosavljević et al. (2016)
Canada
British Columbia Atlin Mining Division Atlin-Ruffner Mine Peatfield (n.d.)
Kamloops Mining Division Siwash Creek Dolly Varden group Traill (1970)
Skeena Mining Division Alice Arm Dolly Varden Mine Peatfield (n.d.)
Yukon Mayo mining district Keno Hill Watson et al. (1996)
China
Fujian Nanping Jianyang District Shuiji Pb-Zn-(Ag) deposit Fengshanlin ore block Anthony
Hubei Yichang Xingshan Co. Baiguoyuan Ag-V deposit Chao Chen and Fapeng Xie (1986) +1 other reference
Jiangxi Ganzhou Xingguo Co. Xiaolong Mine Deqing Xu (1993)
Czech Republic
Central Bohemian Region Kutná Hora District Kutná Hora St. Antonín de Padua Adit Pažout et al. (2019)
France
Auvergne-Rhône-Alpes Cantal Aurillac Laroquebrou Saint-Santin-Cantalès Le Cazaret
Saint-Flour Molèdes Fournial Mine R. Pierrot +1 other reference
Haute-Loire Brioude Saint-Pal-de-Senouire Monlimard Pélisson (1989)
Le Puy-en-Velay Bellevue-la-Montagne Joux Pélisson (1989)
Nouvelle-Aquitaine Haute-Vienne Limoges Rilhac-Lastours Bessous P. Picot
Provence-Alpes-Côte d'Azur Alpes-Maritimes Nice Arrondissement Roure Baume des Rances R. Pierrot
Germany
Baden-Württemberg Freiburg Region Emmendingen Waldkirch Suggental Hornbühl Walenta (1992)
Saxony Mittelsachsen Brand-Erbisdorf Himmelsfürst Mine (TL) F. Angel and R. Scharizer in "Grundriss der Mineralparagenese" (Wien)
Vereinigt Feld Mine Simon Bogners Neuwerk Mine A. Frenzel (1900)
Freiberg Himmelfahrt Mine Alice Kraissl
Zug Beschert Glück Mine ? 90. +2 other references
India
Rajasthan Udaipur Division Udaipur District Udaipur Zawar deposit Mochia Mine Chauhan (1984)
Indonesia
Central Sulawesi Province Talau Poboya Gold Mine River Reef zone Rivai +1 other reference
Ireland
Leinster Meath County Navan (An Uaimh) Navan Mine (Tara Mine) Ryback et al. (1988)
Munster Tipperary County Silvermines District Mogul Mine (Garryard Mine; International Mogul Mines) Economic Geology (1984) +2 other references
Japan
Akita Prefecture Odate Ezuri mine Suji Ohno & Juichi Sato Ganko Vol. 90 (1995)
Hokkaidō Prefecture Hiyama Subprefecture Hiyama District Kaminokuni Johkoku mine (Jôkoku mine; Jokoku mine) Ishiyama (1982)
Matahachi deposit Ishiyama et al. (1989)
Okhotsk Subprefecture Monbetsu City Numanoue mine Geology and Mineral Resources of Japan (Geological Survey of Japan, 1960)
Tochigi Prefecture Nikko City Kuriyamamura Nishizawa mine Shimizu et al. (2007)
Kazakhstan
Pavlodar Region Bayanaul District Maikain Au deposit Baibatsha et al. (2015) +1 other reference
Mexico
Guanajuato Guanajuato Municipality Guanajuato San Juan de Rayas Mine (Rayas Mine; Reyes Mine)
Oaxaca Natividad Municipality Natividad Dulce Nombre mine Natividad vein Cano et al. (2024)
Morocco
Drâa-Tafilalet Region Bou Azzer mining district S. Weiß: Lapis 31 (7/8)
Namibia
Oshikoto Region Tsumeb Tsumeb Mine (Ongopolo Mine) Bowell +1 other reference
New Zealand
Auckland Region Great Barrier Island Railton et al. (1990)
Te Ahumata (White Cliffs) January 2010 An assessment of the value ...
Lees Reef Simon et al. (1997)
Peru
Lima Oyón Province Oyón District Uchucchacua area Uchucchacua Mine EDS Analysis Frank Keutsch
Poland
Lower Silesian Voivodeship Karkonosze County Szklarska Poręba Mount Spławna Czerwony Potok quarry Kozłowski et al. (2022)
Legnica County Piestrzyński (Main Ed.)
Lubin–Głogów mining district Piestrzyński et al. (2012)
Lubin County Lubin Lis et al. (1986)
Portugal
Vila Real Sabrosa Vale das Gatas Mines (São Lourenço de Riba Pinhão and Souto Maior) Bowles (1987)
Romania
Alba County Bucium Bucium Bucium Tarnita porphyry Cu-Au deposit Cioacă et al. (2014)
Lupșa Mușca Roșia Poieni Mine Cioacă et al. (2014)
Roșia Montană Roşia Montană Bailly +9 other references
Hunedoara County Buceș Stănija Larga Cook et al. (2003) +1 other reference
Certeju de Sus Măgura veins Săbău et al. (2016)
Maramureș County Baia Mare Bailly et al. (1998)
Russia
Chelyabinsk Oblast Verkhneuralsky District Babaryk VHMS occurrence (Babarykinskoye Pb-Zn-Cu occurrence) Belogub et al. (2005) +1 other reference
Chukotka Autonomous Okrug Okhotsk-Chukotka belt Corrida deposit Kolova et al. (2021)
Rudnaya Sopka Ag-Au deposit Pekov (1998)
Kamchatka Krai Yelizovsky District Rodnikovoe Tolstykh et al. (2022)
Magadan Oblast Omsukchansky District Rogovik deposit R.G. Kravtsova et al. (2015) +3 other references
Severo-Evensky District Burgali deposit Volkov et al. (2021)
Seymchan ore cluster Goryachev et al. (2014)
Primorsky Krai Nizhne-taezhnyi ore cluster Kumirnogo Ag Deposit Ivin et al. (2021)
Ol’ga ore district Shirokaya Pad Kazachenko et al. (2008, August)
Slovakia
Prešov Region Prešov District Zlatá Baňa Zlatá Baňa deposit Ďuďa R. & Košarková M. (1999)
Base metal deposit Ďuďa R. & Košarková M. (1999)
South Korea
North Chungcheong province Yeongdong County Wolyu Mine Mineralogical Society of America - ... +1 other reference
Spain
Andalusia Jaén Linares Coto La Luz Colectivo Arrayanes et al. (2008)
Castile-La Mancha Guadalajara Hiendelaencina Calvo et al. (1992)
Santa Cecilia Mine Calvo et al. (1992)
Sweden
Värmland County Säffle Långserud Södra Botten Mine
Switzerland
Uri Reuss Valley Amsteg Amsteg power station Pfaffensprung-Amsteg water tunnel Huttenlocher (1936)
USA
Alaska Denali Borough Denali National Park and Preserve Kantishna Hills District Kantishna Hills lode deposits USGS OFR 2004-1200 (Hawley,2004)
Juneau Admiralty Mining District Greens Creek (Big Sore Mine) Taylor
Colorado Dolores County Rico Mountains Rico Mining District (Pioneer Mining District) Expectation Mountain Iron Clad Mine Barnes (1985)
Nevada Nye County San Antonio Mountains Tonopah Mining District ? Kleinhampl et al. (1984)
Utah Box Elder County Grouse Creek Mts (Grouse Creek Range) Ashbrook Mining District Vipont Mine Bullock (1981)