| dbo:abstract |
Magnesium monoperoxyphthalate (MMPP) is a water-soluble peroxy acid used as an oxidant in organic synthesis. Its main areas of use are the conversion of ketones to esters (Baeyer-Villiger oxidation), epoxidation of alkenes (Prilezhaev reaction), oxidation of sulfides to sulfoxides and sulfones, oxidation of amines to produce amine oxides, and in the oxidative cleavage of hydrazones. Due to its insolubility in non-polar solvents MMPP has seen less use than the more widely used meta-chloroperoxybenzoic acid (mCPBA). Although work up procedures are more simply handled in polar solvents, usage of MMPP to oxidize nonpolar substrates in biphasic media combined with a phase transfer catalyst have been inefficient. Despite this MMPP has certain advantages over mCPBA including a lower cost of production and increased stability. MMPP is also used as the active ingredient in certain surface disinfectants such as Dismozon Pur. As a surface disinfectant MMPP exhibits a broad spectrum biocidal effect including inactivation of endospores. Its wide surface compatibility enables its use on sensitive materials, such as plastic and rubber equipment used in hospitals. Additionally MMPP has been investigated as a potential antibacterial agent for mouthwashes and toothpaste. (en) |
| dbo:alternativeName |
H48; MMPP (en) |
| dbo:iupacName |
Magnesium bis(2-carbonoperoxoylbenzoate) (en) |
| dbo:thumbnail |
wiki-commons:Special:FilePath/Magnesium_monoperoxyphthalate.svg?width=300 |
| dbo:wikiPageID |
41404633 (xsd:integer) |
| dbo:wikiPageLength |
3724 (xsd:nonNegativeInteger) |
| dbo:wikiPageRevisionID |
1026734843 (xsd:integer) |
| dbo:wikiPageWikiLink |
dbr:Amine_oxide dbr:Prilezhaev_reaction dbr:Baeyer-Villiger_oxidation dbc:Magnesium_compounds dbc:Benzene_derivatives dbc:Oxidizing_agents dbc:Reagents_for_organic_chemistry dbr:Ester dbr:Sulfone dbr:Ketone dbr:Organic_synthesis dbr:Alkenes dbr:Amine dbc:Disinfectants dbc:Organic_peroxy_acids dbr:Sulfide dbr:Endospores dbr:Meta-Chloroperoxybenzoic_acid dbr:Peroxy_acid dbr:Sulfoxide dbr:Epoxidation dbr:Oxidant |
| dbp:imagefile |
Magnesium monoperoxyphthalate.svg (en) |
| dbp:othernames |
H48; MMPP (en) |
| dbp:pin |
Magnesium bis (en) |
| dbp:wikiPageUsesTemplate |
dbt:Chembox dbt:Chembox_Hazards dbt:Chembox_Identifiers dbt:Chembox_Properties dbt:Reflist |
| dct:subject |
dbc:Magnesium_compounds dbc:Benzene_derivatives dbc:Oxidizing_agents dbc:Reagents_for_organic_chemistry dbc:Disinfectants dbc:Organic_peroxy_acids |
| gold:hypernym |
dbr:Acid |
| rdf:type |
owl:Thing dul:ChemicalObject dbo:ChemicalSubstance wikidata:Q11173 yago:WikicatOrganicPeroxides yago:WikicatOxidizingAgents yago:Agent114778436 yago:CausalAgent100007347 yago:ChemicalAgent114779550 yago:Disinfectant103208229 yago:HydrogenPeroxide114781225 yago:Matter100020827 yago:Oxidant114780040 yago:PhysicalEntity100001930 yago:Reagent114778982 dbo:ChemicalCompound yago:Substance100020090 yago:WikicatDisinfectants yago:WikicatReagentsForOrganicChemistry |
| rdfs:comment |
Magnesium monoperoxyphthalate (MMPP) is a water-soluble peroxy acid used as an oxidant in organic synthesis. Its main areas of use are the conversion of ketones to esters (Baeyer-Villiger oxidation), epoxidation of alkenes (Prilezhaev reaction), oxidation of sulfides to sulfoxides and sulfones, oxidation of amines to produce amine oxides, and in the oxidative cleavage of hydrazones. (en) |
| rdfs:label |
Magnesium monoperoxyphthalate (en) |
| owl:sameAs |
freebase:Magnesium monoperoxyphthalate yago-res:Magnesium monoperoxyphthalate wikidata:Magnesium monoperoxyphthalate dbpedia-fa:Magnesium monoperoxyphthalate https://global.dbpedia.org/id/YhEE |
| prov:wasDerivedFrom |
wikipedia-en:Magnesium_monoperoxyphthalate?oldid=1026734843&ns=0 |
| foaf:depiction |
wiki-commons:Special:FilePath/Magnesium_monoperoxyphthalate.svg |
| foaf:isPrimaryTopicOf |
wikipedia-en:Magnesium_monoperoxyphthalate |
| is dbo:wikiPageRedirects of |
dbr:Magnesium_Monoperoxyphthalate dbr:MMPP |
| is dbo:wikiPageWikiLink of |
dbr:List_of_cleaning_products dbr:Cyclohexene_oxide dbr:Magnesium_Monoperoxyphthalate dbr:MMPP |
| is foaf:primaryTopic of |
wikipedia-en:Magnesium_monoperoxyphthalate |
