| dbo:abstract |
Pillararenes are macrocycles composed of hydroquinone or units (5 to 10) linked in the para position by methylene bridges. They are structurally similar to the cucurbiturils and calixarenes that play an important part in host–guest chemistry. The first pillararene was the five membered dimethoxypillar[5]arene. (en) Les pillararènes sont des molécules macrocycliques composées d'unités hydroquinones (para-dihydroxybenzène) reliées en position para. Ils sont proches structurellement des cucurbituriles et des calixarènes, qui jouent un rôle important en chimie supramoléculaire. La première structure pillar[n]arène synthétisée fut celle comportant cinq unités. (fr) |
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dbr:Catalyst dbr:Methylene_bridge dbr:Nanoparticle dbr:Transmembrane_channels dbr:Boron_tribromide dbr:Host–guest_chemistry dbr:Human_papillomavirus dbr:Hydroquinone dbr:Cucurbituril dbr:Methoxy dbr:Planar_chirality dbr:Macrocycles dbr:1,4-dimethoxybenzene dbc:Hydroquinones dbc:Macrocycles dbr:Chlorocyclohexane dbr:Racemization dbr:Electron_Paramagnetic_Resonance dbr:Symmetric dbr:Lewis_acid dbc:Cyclophanes dbr:Clockwise dbr:Trifluoromethanesulfonic_acid dbr:Drug_delivery dbr:Paraformaldehyde dbr:Ionic_liquids dbr:Acid dbr:Jilin_University dbr:Phenylene dbr:Cahn-Ingold-Prelog_priority_rules dbr:P-toluenesulfonic_acid dbr:Friedel-Crafts dbr:Para_isomer dbr:Calixarenes dbr:Condensation_(chemistry) dbr:Steric dbr:Dialkoxybenzene dbr:File:DMpillar_5_arene_planar_chirality.tiff dbr:File:Enantiomers_of_Pillararene.png dbr:File:Memantine_and_WP7.tif dbr:File:Pillar5arene_Feb2013.png |
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dbt:Reflist dbt:Short_description |
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dbc:Hydroquinones dbc:Macrocycles dbc:Cyclophanes |
| gold:hypernym |
dbr:Macrocycles |
| rdf:type |
dbo:ChemicalCompound |
| rdfs:comment |
Pillararenes are macrocycles composed of hydroquinone or units (5 to 10) linked in the para position by methylene bridges. They are structurally similar to the cucurbiturils and calixarenes that play an important part in host–guest chemistry. The first pillararene was the five membered dimethoxypillar[5]arene. (en) Les pillararènes sont des molécules macrocycliques composées d'unités hydroquinones (para-dihydroxybenzène) reliées en position para. Ils sont proches structurellement des cucurbituriles et des calixarènes, qui jouent un rôle important en chimie supramoléculaire. La première structure pillar[n]arène synthétisée fut celle comportant cinq unités. (fr) |
| rdfs:label |
Pillararène (fr) Pillararene (en) |
| owl:sameAs |
freebase:Pillararene wikidata:Pillararene dbpedia-fr:Pillararene https://global.dbpedia.org/id/N92J |
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wikipedia-en:Pillararene?oldid=1123590306&ns=0 |
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