Pinakiolite (original) (raw)

A valid IMA mineral species - grandfathered

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About PinakioliteHide

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Formula:

(Mg,Mn2+)2Mn3+(BO3)O2

Colour:

Black; deep reddish brown in transmitted light

Crystal System:

Monoclinic

Name:

From the Greek πινάκιον, a small tablet, and λίθος, stone, in allusion to the thin tabular shape of the crystals.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3214:4

IMA Classification of PinakioliteHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

(Mg,Mn)2(Mn3+,Sb5+)O2(BO3)

Type description reference:

Classification of PinakioliteHide

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6.AB.35

6 : BORATES
A : Monoborates
B : BO3, with additional anions; 1(D) + OH, etc.

24.2.4.1

24 : ANHYDROUS BORATES
2 : A2BO2[XO3]

9.7.1

9 : Borates
7 : Borates of Mn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Pki IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PinakioliteHide

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Transparency:

Translucent, Opaque

Comment:

brilliant on {010}, to pearly

Colour:

Black; deep reddish brown in transmitted light

Cleavage:

Distinct/Good
On {010}.

Density:

3.88 g/cm3 (Measured) 3.94(15) g/cm3 (Calculated)

Optical Data of PinakioliteHide

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RI values:

_n_α = 1.908(5) _n_β = 2.050(1) _n_γ = 2.060(10)

2V:

Measured: 31° to 33°, Calculated: 64°

δ = 0.152

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X = b; Y = c; Z = a.

Comments:

X = Deep reddish brown
Y = Nearly opaque
Z = Reddish yellow

Chemistry of PinakioliteHide

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Mindat Formula:

(Mg,Mn2+)2Mn3+(BO3)O2

Crystallography of PinakioliteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 5.36 Å, b = 5.98 Å, c = 21.79 Å
β = 120.57°

Ratio:

a:b:c = 0.896 : 1 : 3.644

Unit Cell V:

601.35 ų (Calculated from Unit Cell)

Morphology:

Thin rectangular tablets {010}. Short prismatic [001], rare. Crystals often bent or broken.

Twinning:

On {011} common as contact and/or cruciform interpenetrant twins.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0000416 Pinakiolite Moore P B, Araki T (1974) Pinakiolite, Mg2MnO2[BO3]; warwickite, Mg(Mg0.5Ti0.5)O[BO3]; wightmanite, Mg5(O)(OH)5[BO3].nH2O: Crystal chemistry of complex 3 Angstrom wallpaper structures American Mineralogist 59 985-1004 1974 Langban, Sweden 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.51 Å (10)
2.70 Å (9)
5.42 Å (8)
1.986 Å (6)
2.165 Å (4)
1.623 Å (4)
1.496 Å (4)

Geological EnvironmentHide

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Type Occurrence of PinakioliteHide

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General Appearance of Type Material:

Place of Conservation of Type Material:

Swedish Museum of Natural History, Stockholm, Sweden, 531826.

Geological Setting of Type Material:

Bands in granular dolomite.

Associated Minerals at Type Locality:

Synonyms of PinakioliteHide

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Other Language Names for PinakioliteHide

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Varieties of PinakioliteHide

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Sb-rich pinakiolite Described by Hansen et al. (1988) and Norrestam & Hansen (1990) as a Sb-bearing pinakiolite, a new structural variety from Långban, Sweden.

Relationship of Pinakiolite to other SpeciesHide

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Other Members of Pinakiolite Group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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6.AB. Chubarovite KZn2(BO3)Cl2 Trig. 32 : _R_32
6.AB. Rhabdoborite-(Mo) Mg12Mo6+1.33O6(BO3)6F2 Hex. 6 : _P_63
6.AB.05 Hambergite Be2(BO3)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
6.AB.10 Berborite Be2(BO3)(OH,F) · H2O Trig.
6.AB.15 Jeremejevite Al6(BO3)5(F,OH)3 Hex. 6/m : _P_63/m
6.AB.20 Yuanfuliite Mg(Fe3+,Al)O(BO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
6.AB.20 Warwickite (Mg,Ti,Fe,Al)2O(BO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
6.AB.25 Karlite (Mg,Al)6.5(BO3)3(OH)4(◻,Cl)0.5 Orth. 222 : _P_21212
6.AB.30 Marinaite Cu2Fe3+O2(BO3) Mon. 2/m : _P_21/b
6.AB.30 Savelievaite Mg2Cr3+O2(BO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Fredrikssonite Mg2(Mn3+,Fe3+)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Vonsenite Fe2+2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Ludwigite Mg2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Azoproite (Mg,Fe2+)2(Fe3+,Ti,Mg)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Bonaccordite Ni2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.35 Folvikite Sb5+Mn3+(Mg,Mn2+)10O8(BO3)4 Mon. 2 : _P_2
6.AB.40 Takéuchiite (Mg,Mn2+)2(Mn3+,Fe3+)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
6.AB.40 Blatterite Sb5+3(Mn3+,Fe3+)9(Mn2+,Mg)35(BO3)16O32 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
6.AB.40 Orthopinakiolite (Mg,Mn2+)2Mn3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
6.AB.40 Chestermanite Mg2(Fe3+,Mn3+,Al,Sb3+)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m )
6.AB.45 Aluminomagnesiohulsite (Mg,Fe2+)2(Al,Mg,Sn)(BO3)O2 Mon. 2/m : _P_2/m
6.AB.45 Hulsite (Fe2+,Mg)2(Fe3+,Sn)(BO3)O2 Mon. 2/m : _P_2/m
6.AB.45 Magnesiohulsite (Mg,Fe2+)2(Fe3+,Sn,Mg)(BO3)O2 Mon. 2/m : _P_2/m
6.AB.50 Fluoborite Mg3(BO3)(F,OH)3 Hex. 6/m : _P_63/m
6.AB.50 Hydroxylborite Mg3(BO3)(OH)3 Hex. 6/m : _P_63/m
6.AB.55 Shabynite Mg5(BO3)(OH)5(Cl,OH)2 · 4H2O Mon.
6.AB.55 Wightmanite Mg5(BO3)O(OH)5 · 2H2O Mon. 2/m
6.AB.60 Gaudefroyite Ca4Mn3+2-3(BO3)3(CO3)(O,OH)3 Hex.
6.AB.65 Sakhaite Ca48Mg16(BO3)32(CO3)16 · 2(H2O,HCl) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
6.AB.70 Harkerite Ca48Mg16[AlSi4O15(OH)]4(BO3)16(CO3)16 · 2(H2O,HCl) Trig. 3_m_ _(_32/m ) : R_3_m
6.AB.75 Pertsevite-(F) Mg2(BO3)(F,OH) Orth. m _m_2 : P n _a_21
6.AB.75 Pertsevite-(OH) Mg2(BO3)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
6.AB.80 Jacquesdietrichite Cu2(H2BO3)(OH)3 Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
6.AB.85 Rhabdoborite-(V) Mg12(V5+,Mo6+,W6+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1) Hex. 6 : _P_63
6.AB.85 Rhabdoborite-(W) Mg12(W6+,V5+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} Hex. 6 : _P_63
6.AB.85 Painite CaZrAl9(BO3)O15 Hex. 6/m : _P_63/m
6.AB.90 Mengxianminite (Ca,Na)2Sn2(Mg,Fe)3Al8[(BO3)(BeO4)O6]2 Orth. m _m_2 : F d _d_2

Other InformationHide

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Notes:

Soluble in concentrated HCl with the evolution of elemental chlorine.

Health Risks:

Emits poisonous chlorine gas when contacted by concentrated HCl.

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References for PinakioliteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.324-325

Dunn, Pete J., Chao, George Y., Fitzpatrick, Joan J., Langley, Richard H., Fleischer, Michael, Zilczer, Janet A. (1986) New Mineral Names. American Mineralogist, 71 (1-2). 227-232

Localities for PinakioliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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