Azoproite (original) (raw)

A valid IMA mineral species

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About AzoproiteHide

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Formula:

(Mg,Fe2+)2(Fe3+,Ti,Mg)(BO3)O2

Crystal System:

Orthorhombic

Name:

A Russian acronym honoring the Study of Deep Zones of the Earth’s Crust (AZOPRO in Russian) sponsored in 1969 by the International Geological Association. It was found during the preparation of a guidebook for the Association's 12th meeting at Baikal.

This page provides mineralogical data about Azoproite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:442:8

cd0bf1a1-a243-4c61-b548-ebd4accdd2fb

IMA Classification of AzoproiteHide

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IMA Formula:

Mg2[(Ti,Mg),Fe3+]O2(BO3)

Type description reference:

Classification of AzoproiteHide

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6.AB.30

6 : BORATES
A : Monoborates
B : BO3, with additional anions; 1(D) + OH, etc.

24.2.1.3

24 : ANHYDROUS BORATES
2 : A2BO2[XO3]

9.6.2

9 : Borates
6 : Borates of Ti, Sn and Ta

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Azo IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AzoproiteHide

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Transparency:

Translucent, Opaque

Cleavage:

Distinct/Good
Good on (010), less good on (001)

Density:

3.63(2) g/cm3 (Measured) 3.63 g/cm3 (Calculated)

Optical Data of AzoproiteHide

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RI values:

_n_α = 1.799(2) _n_β = 1.822(3) _n_γ = 1.855(5)

δ = 0.056

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X pale green with bluish tint, Y dark green, nearly opaque, Z reddish-brown, absorption Y>Z>X.

Chemistry of AzoproiteHide

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Mindat Formula:

(Mg,Fe2+)2(Fe3+,Ti,Mg)(BO3)O2

Crystallography of AzoproiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 9.26(1) Å, b = 12.25(1) Å, c = 3.01(1) Å

Ratio:

a:b:c = 0.756 : 1 : 0.246

Unit Cell V:

341.44 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.52 Å (10d)
5.07 Å (8)
2.16 Å (6)
2.02 Å (6)
2.77 Å (5b)
2.11 Å (5)
1.900 Å (5)

Geological EnvironmentHide

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Type Occurrence of AzoproiteHide

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General Appearance of Type Material:

Prismatic crystals 1 to 20 mm long and 0.1 to 5 mm wide.

Place of Conservation of Type Material:

Mining Institute, St. Petersburg, Russia, 1481/1–1481/3.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 72890–72892.
Natural History Museum, Paris, France.
National School of Mines, Paris, France, V16383.

Geological Setting of Type Material:

Magnesian skarns in the contact aureole of the Tazheran alkalic massif.

Associated Minerals at Type Locality:

Reference:

Konev, A.A., Lesedeva, V.S., Kashaev, A.A., Ushchapovskaya, Z.F. (1970) Azoproite, a new mineral of the ludwigite group. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 99(2): 225-231.

Synonyms of AzoproiteHide

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Other Language Names for AzoproiteHide

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Relationship of Azoproite to other SpeciesHide

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Other Members of this group:

Bonaccordite Ni2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
Fredrikssonite Mg2(Mn3+,Fe3+)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
Ludwigite Mg2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
Marinaite Cu2Fe3+O2(BO3) Mon. 2/m : _P_21/b
Savelievaite Mg2Cr3+O2(BO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
Vonsenite Fe2+2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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6.AB. Rhabdoborite-(Mo) Mg12Mo6+1.33O6(BO3)6F2 Hex. 6 : _P_63
6.AB. Chubarovite KZn2(BO3)Cl2 Trig. 32 : _R_32
6.AB.05 Hambergite Be2(BO3)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
6.AB.10 Berborite Be2(BO3)(OH,F) · H2O Trig.
6.AB.15 Jeremejevite Al6(BO3)5(F,OH)3 Hex. 6/m : _P_63/m
6.AB.20 Warwickite (Mg,Ti,Fe,Al)2O(BO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
6.AB.20 Yuanfuliite Mg(Fe3+,Al)O(BO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
6.AB.25 Karlite (Mg,Al)6.5(BO3)3(OH)4(◻,Cl)0.5 Orth. 222 : _P_21212
6.AB.30 Bonaccordite Ni2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Fredrikssonite Mg2(Mn3+,Fe3+)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Ludwigite Mg2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Vonsenite Fe2+2Fe3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.30 Marinaite Cu2Fe3+O2(BO3) Mon. 2/m : _P_21/b
6.AB.30 Savelievaite Mg2Cr3+O2(BO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
6.AB.35 Pinakiolite (Mg,Mn2+)2Mn3+(BO3)O2 Mon. 2/m : _B_2/m
6.AB.35 Folvikite Sb5+Mn3+(Mg,Mn2+)10O8(BO3)4 Mon. 2 : _P_2
6.AB.40 Blatterite Sb5+3(Mn3+,Fe3+)9(Mn2+,Mg)35(BO3)16O32 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
6.AB.40 Chestermanite Mg2(Fe3+,Mn3+,Al,Sb3+)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m )
6.AB.40 Orthopinakiolite (Mg,Mn2+)2Mn3+(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
6.AB.40 Takéuchiite (Mg,Mn2+)2(Mn3+,Fe3+)(BO3)O2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
6.AB.45 Hulsite (Fe2+,Mg)2(Fe3+,Sn)(BO3)O2 Mon. 2/m : _P_2/m
6.AB.45 Magnesiohulsite (Mg,Fe2+)2(Fe3+,Sn,Mg)(BO3)O2 Mon. 2/m : _P_2/m
6.AB.45 Aluminomagnesiohulsite (Mg,Fe2+)2(Al,Mg,Sn)(BO3)O2 Mon. 2/m : _P_2/m
6.AB.50 Fluoborite Mg3(BO3)(F,OH)3 Hex. 6/m : _P_63/m
6.AB.50 Hydroxylborite Mg3(BO3)(OH)3 Hex. 6/m : _P_63/m
6.AB.55 Shabynite Mg5(BO3)(OH)5(Cl,OH)2 · 4H2O Mon.
6.AB.55 Wightmanite Mg5(BO3)O(OH)5 · 2H2O Mon. 2/m
6.AB.60 Gaudefroyite Ca4Mn3+2-3(BO3)3(CO3)(O,OH)3 Hex.
6.AB.65 Sakhaite Ca48Mg16(BO3)32(CO3)16 · 2(H2O,HCl) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
6.AB.70 Harkerite Ca48Mg16[AlSi4O15(OH)]4(BO3)16(CO3)16 · 2(H2O,HCl) Trig. 3_m_ _(_32/m ) : R_3_m
6.AB.75 Pertsevite-(F) Mg2(BO3)(F,OH) Orth. m _m_2 : P n _a_21
6.AB.75 Pertsevite-(OH) Mg2(BO3)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
6.AB.80 Jacquesdietrichite Cu2(H2BO3)(OH)3 Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
6.AB.85 Painite CaZrAl9(BO3)O15 Hex. 6/m : _P_63/m
6.AB.85 Rhabdoborite-(V) Mg12(V5+,Mo6+,W6+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1) Hex. 6 : _P_63
6.AB.85 Rhabdoborite-(W) Mg12(W6+,V5+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} Hex. 6 : _P_63
6.AB.90 Mengxianminite (Ca,Na)2Sn2(Mg,Fe)3Al8[(BO3)(BeO4)O6]2 Orth. m _m_2 : F d _d_2

Other InformationHide

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Notes:

Readily dissolved by dilute HCl, not dissolved in 1:3 HNO3.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for AzoproiteHide

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Reference List:

Bilohuščin, Vladimír, Uher, Pavel, Koděra, Peter, Milovská, Stanislava, Mikuš, Tomáš, Bačík, Peter (2017) Evolution of borate minerals from contact metamorphic to hydrothermal stages: Ludwigite-group minerals and szaibélyite from the Vysoká – Zlatno skarn, Slovakia. Mineralogy and Petrology, 111 (4) 643-658 doi:10.1007/s00710-017-0518-y

Biryukov, Y.P., Zinnatullin, A.L., Levashova, I.O., Shablinskii, A.P., Cherosov, M.A., Bubnova, R.S., Vagizov, F.G., Krzhizhanovskaya, M.G., Filatov, S.K., Shilovskikh, V.V., Pekov, I.V. (2022): X-ray diffraction and Mössbauer spectroscopy study of oxoborate azoproite (Mg,Fe2+)2(Fe3+,Ti,Mg,Al)O2(BO3): an in situ temperature-dependent investigation (5 ≤ T ≤ 1650 K). Acta Crystallographica: B78: 809-816.

Localities for AzoproiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia
Krasnoyarsk Krai Taymyrskiy Autonomous Okrug Taimyr Peninsula Putoran Plateau Norilsk-Talnakh Mining Region Noril'sk Cu-Ni deposit Noril'sk-1 Cu-Ni deposit Medvezhyi Ruchei Mine Noril'sk I intrusive Shevko et al. (2019, September)
Lake Baikal area Tazheranskii Massif (TL) Konev A A et al. (1970) +2 other references
Sakha Polar Yakutia Dogdo River Basin Tas-Khayakhtakh Range Titovskoe B deposit Izvestkovyi Stream Snezhnoe B ore occurrence Galuskin +1 other reference
Slovakia
Banská Bystrica Region Banská Štiavnica District Vysoká Zlatno Bilohuščin et al. (2016)
Spain
Murcia Cartagena La Aljorra La Aljorra Quarries in the collection of Christof Schäfer
USA
Alaska Nome Census Area Port Clarence Mining District Brooks Mountain Aleksandrov et al. (2008)