Chalcopyrite (original) (raw)
A valid IMA mineral species - grandfathered
About ChalcopyriteHide
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Colour:
Brass yellow, often with an iridescent tarnish.
Specific Gravity:
4.1 - 4.3
Crystal System:
Tetragonal
Name:
Named in 1725 by Johann Friedrich Henckel from the Greek "chalkos", copper, and "pyrites", strike fire.
Chalcopyrite Group. Chalcopyrite-Eskebornite Series.
A major ore of copper. Common in sulfide veins and disseminated in igneous rocks.
Weathering may lead to the formation of malachite, azurite, brochantite, langite and numerous other secondary copper minerals.
A Zn-rich variety is known from Atlantis II Deep (see zincian chalcopyrite). Also, the Mid-Atlantic-ridge isocubanite may transform to chalcopyrite and UM1994-22-S:CuFe (Cu1-xFe3+xS4 (Wintenberger et al., 1994).
Compare, e.g., UM1991-16-S:CuFeTl, UM1988-17-S:CuFe, UM1988-18-S:CuFe, and UM2003-19-S:CuFe.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:955:7
IMA Classification of ChalcopyriteHide
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Approved, 'Grandfathered' (first described prior to 1959)
Classification of ChalcopyriteHide
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2.CB.10a
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2.9.1.1
2 : SULFIDES
9 : AmBnXp, with (m+n):p = 1:1
3.1.25
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
1 : Sulphides etc. of Cu
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Ccp | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Ccp | Kretz (1983) | Kretz, R. (1983) Symbols of rock-forming minerals. American Mineralogist, 68, 277–279. |
Ccp | Siivolam & Schmid (2007) | Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download |
Ccp | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Cp | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Pronunciation of ChalcopyriteHide
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Pronunciation:
Play | Recorded by | Country |
---|---|---|
Sorry, your browser doesn't support HTML5 audio. | Jolyon Ralph | United Kingdom |
Physical Properties of ChalcopyriteHide
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Colour:
Brass yellow, often with an iridescent tarnish.
Hardness:
VHN100=187 - Vickers
Cleavage:
Poor/Indistinct
Indistinct on {011}, sometimes distinct.
Fracture:
Irregular/Uneven
Density:
4.1 - 4.3 g/cm3 (Measured) 4.18 g/cm3 (Calculated)
Optical Data of ChalcopyriteHide
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Anisotropism:
Weak, but distinct blue-gray to yellow-green
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
400nm | 16.0% | 17.3% |
420nm | 20.0% | 21.3% |
440nm | 24.8% | 26.1% |
460nm | 30.2% | 31.4% |
480nm | 34.9% | 35.9% |
500nm | 38.9% | 39.9% |
520nm | 41.9% | 42.7% |
540nm | 44.0% | 44.9% |
560nm | 45.4% | 46.4% |
580nm | 46.6% | 47.6% |
600nm | 47.1% | 48.3% |
620nm | 47.5% | 48.6% |
640nm | 47.6% | 48.7% |
660nm | 47.6% | 48.7% |
680nm | 47.6% | 48.6% |
700nm | 47.6% | 48.6% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 48.7%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Yellow against a white/gray phase, greenish-yellow when next to gold.
Internal Reflections:
None
Chemistry of ChalcopyriteHide
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Common Impurities:
Ag,Au,In,Tl,Se,Te
Age distributionHide
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Recorded ages:
Phanerozoic : 299.7 ± 1.8 Ma to 57 Ma - based on 7 recorded ages.
Crystallography of ChalcopyriteHide
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Crystal System:
Tetragonal
Class (H-M):
42_m_ - Scalenohedral
Cell Parameters:
a = 5.289 Å, c = 10.423 Å
Unit Cell V:
291.57 ų (Calculated from Unit Cell)
Morphology:
Typically found as equant to wedge-shaped pseudo-tetrahedral disphenoidal crystals, often modified by tetragonal scalenohedral faces. Mostly found massive or in disseminated grains and major deposits of such material are known.
Twinning:
Twinned on {112} and {012}, penetration or cyclic.
Comment:
Subcell: I-centred tetragonal, a = 3.74, c = 5.21 Å.
Crystallographic forms of ChalcopyriteHide
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Crystal Atlas:
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Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0018622 | Chalcopyrite | Knight K S, Marshall W G, Zochowski S W (2011) The low-temperature and high-pressure thermoelastic and structural properties of chalcopyrite, CuFeS2 The Canadian Mineralogist 49 1015-1034 | 2011 | Palabora mine, South Africa | 0 | 300 | |
0018623 | Chalcopyrite | Knight K S, Marshall W G, Zochowski S W (2011) The low-temperature and high-pressure thermoelastic and structural properties of chalcopyrite, CuFeS2 The Canadian Mineralogist 49 1015-1034 | 2011 | Palabora mine, South Africa | 0 | 4.2 | |
0009476 | Chalcopyrite | Hall S R, Stewart J M (1973) The crystal structure refinement of chalcopyrite, CuFeS2 Acta Crystallographica B29 579-585 | ![]() |
1973 | 0 | 293 | |
0017661 | Chalcopyrite | Pauling L, Brockway L (1932) The Crystal Structure of Chalkopyrite Cu Fe S2 _cod_database_code 1010940 Zeitschrift fur Kristallographie 82 188-194 | 1932 | 0 | 293 | ||
0017651 | Chalcopyrite | Burdick C, Ellis J (1917) The Crystal Structure of Chalcopyrite Determined by X-Rays _cod_database_code 1010929 Journal of the American Chemical Society 39 2519-2525 | 1917 | 0 | 293 |
CIF Raw Data - click here to close
Epitaxial Relationships of ChalcopyriteHide
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Epitaxy Comments:
Pyrite on chalcopyrite from Ege-Khay, Yakutia, Russia (Novgorodova 1977).
X-Ray Powder DiffractionHide
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Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.04 Å | (100) |
2.64 Å | (10) |
1.87 Å | (20) |
1.86 Å | (40) |
1.59 Å | (300 |
1.57 Å | (10) |
1.21 Å | (10) |
1.08 Å | (10) |
Geological EnvironmentHide
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Geological Setting:
Chalcopyrite is a prevalent sulfide mineral in ore deposits and hosts various trace elements such as Ag, Co, As, Se, Sb, Te, Bi, etc. The variations in trace element contents, as well as Fe, S, and Cu isotopic compositions of chalcopyrite are controlled by a series of factors including metallogenic temperature and pressure, fluid compositions, metal sources, and sulfide equilibrium. Chalcopyrite is found in porphyry Cu deposits (PCDs), sedimentary rock-hosted stratiform Cu deposits (SSCs), iron oxide Cu-Au deposits (IOCGs), sedimentary exhalative deposits (SEDEXs), magmatic Cu-Ni sulfide deposits (MSDs), and volcanogenic massive sulfide deposits (VMSs), etc. Different types of ore deposits show significantly distinct chalcopyrite geochemical characteristics. For example, in PCDs, chalcopyrite is notably enriched in Zn and Pb, with negative δ34S values (−2.1 ± 3.64 ‰, n = 32) due to sediment contributions. Positive δ65Cu values (1.5 ± 2.00 ‰, n = 140) indicate a mantle-crustal mixed source, while negative δ57Fe values (−4.3 ± 5.10 ‰, n = 32) likely result from Fe isotope fractionation during magnetite precipitation or continental crust contamination. In MSDs, Cr is the most enriched element, with positive δ34S values (1.0 ± 2.14 ‰, n = 185) and slightly negative δ⁶5Cu values (−0.46 ± 0.50 ‰, n = 52). Chalcopyrite in SSCs is enriched in Zn and As, characterized by negative δ34S (−3.6 ± 0.12 ‰, n = 190) and δ65Cu values (−0.59 ± 0.98 ‰, n = 118).
Synonyms of ChalcopyriteHide
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Other Language Names for ChalcopyriteHide
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Simplified Chinese:黄铜矿
Traditional Chinese:黃銅礦
Varieties of ChalcopyriteHide
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Relationship of Chalcopyrite to other SpeciesHide
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Other Members of Chalcopyrite Group:
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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2.CB. | Richardsite | Zn2CuGaS4 | Tet. 42_m_ : I_42_m |
---|---|---|---|
2.CB. | Okruginite | Cu2SnSe3 | Mon. m : B b |
2.CB. | Hanswilkeite | KFeS2 | Mon. 2/m : _B_2/b |
2.CB. | Auroselenide | AuSe | Mon. 2/m : _B_2/m |
2.CB. | Ruizhongite | (Ag2◻)Pb3Ge2S8 | Iso. 43_m_ : I_43_d |
2.CB. | Agmantinite | Ag2MnSnS4 | Orth. |
2.CB. | Tolstykhite | Au3S4Te6 | Tric. 1 : _P_1 |
2.CB. | Gachingite | Au(Te1-xSex) | Orth. m m m _(_2/_m_2/_m_2/m ) |
2.CB.05a | Hawleyite | CdS | Iso. 43_m_ : F_43_m |
2.CB.05 | UM1998-15-S:CuFeZn | Cu2Fe3Zn5S10 | |
2.CB.05a | Coloradoite | HgTe | Iso. 43_m_ : F_43_m |
2.CB.05a | Metacinnabar | HgS | Iso. 43_m_ : F_43_m |
2.CB.05a | Tiemannite | HgSe | Iso. 43_m_ : F_43_m |
2.CB.05a | Sphalerite | ZnS | Iso. 43_m_ : F_43_m |
2.CB.05b | Sakuraiite | (Cu,Zn,Fe)3(In,Sn)S4 | Iso. |
2.CB.05c | Polhemusite | (Zn,Hg)S | Tet. |
2.CB.05a | Rudashevskyite | (Fe,Zn)S | Iso. 43_m_ : F_43_m |
2.CB.05a | Stilleite | ZnSe | Iso. 43_m_ : F_43_m |
2.CB.05a | Ishiharaite | (Cu,Ga,Fe,In,Zn)S | Iso. 43_m_ : F_43_m |
2.CB.07a | Unnamed (Cu-Mn-Sn Sulphide) | Cu2MnSnS4 | |
2.CB.07a | Shenzhuangite | NiFeS2 | Tet. 42_m_ : I_42_d |
2.CB.10b | Talnakhite | Cu9(Fe,Ni)8S16 | Iso. 43_m_ : I_43_m |
2.CB.10b | Haycockite | Cu4Fe5S8 | Orth. 222 |
2.CB.10a | Lenaite | AgFeS2 | Tet. 42_m_ : I_42_d |
2.CB.10a | Gallite | CuGaS2 | Tet. 42_m_ : I_42_d |
2.CB.10a | Roquesite | CuInS2 | Tet. 42_m_ : I_42_d |
2.CB.10a | Eskebornite | CuFeSe2 | Tet. 42_m_ : P_42_c |
2.CB.10a | UM1984-30-S:CuFeSn | Cu2Fe2Sn3S7 | |
2.CB.10c | Omariniite | Cu8Fe2ZnGe2S12 | Orth. 222 : _I_222 |
2.CB.10a | Unnamed (Cu-Zn-In Sulphide) | CuZn2InS4 | |
2.CB.10b | Mooihoekite | Cu9Fe9S16 | Tet. 42_m_ : P_42_m |
2.CB.10a | Laforêtite | AgInS2 | Tet. 42_m_ : I_42_d |
2.CB.10b | Putoranite | Cu1.1Fe1.2S2 | Iso. m_3_m _(_4/_m_32/m ) : P n_3_m |
2.CB.15a | Velikite | Cu2HgSnS4 | Tet. 4 : _I_4 |
2.CB.15c | UM2006-11-S:CuFeGeZn | Cu8(Fe,Zn)3Ge2S12 (?) | |
2.CB.15a | Hocartite | Ag2(Fe2+,Zn)SnS4 | Tet. 42_m_ : I_42_m |
2.CB.15a | Kësterite | Cu2ZnSnS4 | Tet. 4 : _I_4 |
2.CB.15a | Pirquitasite | Ag2ZnSnS4 | Tet. 4 : _I_4 |
2.CB.15a | Stannite | Cu2FeSnS4 | Tet. 42_m_ : I_42_m |
2.CB.15c | Stannoidite | Cu+6Cu2+2(Fe2+,Zn)3Sn2S12 | Orth. 222 : _I_222 |
2.CB.15b | Mohite | Cu2SnS3 | Mon. |
2.CB.15a | Černýite | Cu2(Cd,Zn,Fe)SnS4 | Tet. 42_m_ : I_42_m |
2.CB.15a | Idaite | Cu5FeS6 | Hex. |
2.CB.15a | Ferrokësterite | Cu2FeSnS4 | Tet. 4 : _I_4 |
2.CB.15a | Kuramite | Cu3SnS4 | Tet. 42_m_ : I_42_m |
2.CB.17a v | Arsenic-bearing Renierite | Cu11GeAsFe4S16 | |
2.CB.20 | Mawsonite | Cu6Fe2SnS8 | Tet. 42_m_ : _P_4_m_2 |
2.CB.20 | Chatkalite | Cu6FeSn2S8 | Tet. 42_m_ : _P_4_m_2 |
2.CB.30 | Frieseite | Ag2Fe5S8 (?) | |
2.CB.30 | Nekrasovite | Cu26V2(Sn,As,Sb)6S32 | Iso. 43_m_ : P_43_n |
2.CB.30 | Argyropyrite | near Ag2Fe7S11 | |
2.CB.30 | Maikainite | Cu20(Fe,Cu)6Mo2Ge6S32 | Iso. m_3_m _(_4/_m_32/m ) |
2.CB.30 | Colusite | Cu13VAs3S16 | Iso. 43_m_ : P_43_n |
2.CB.30 | Germanite | Cu13Fe2Ge2S16 | Iso. 43_m_ : P_43_n |
2.CB.30 | Germanocolusite | Cu26V2(Ge,As)6S32 | Iso. 43_m_ : P_43_m |
2.CB.30 | Stibiocolusite | Cu13V(Sb,Sn,As)3S16 | Iso. 43_m_ : P_43_m |
2.CB.30 | Ovamboite | Cu20(Fe,Cu,Zn)6W2Ge6S32 | Iso. 43_m_ : P_43_n |
2.CB.35a | Morozeviczite | (Pb,Fe)3Ge1-xS4 | Iso. |
2.CB.35a | Renierite | (Cu1+,Zn)11Fe4(Ge4+,As5+)2S16 | Tet. 42_m_ : P_42_c |
2.CB.35a | Hemusite | Cu6SnMoS8 | Iso. |
2.CB.35b | Catamarcaite | Cu6GeWS8 | Hex. 6_m_ m : P_63_m c |
2.CB.35a | Vinciennite | Cu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16 | Tet. |
2.CB.35a | Kiddcreekite | Cu6SnWS8 | Iso. 43_m_ : F_43_m |
2.CB.35a | Polkovicite | (Fe,Pb)3(Ge,Fe)1-xS4 | Iso. |
2.CB.40 | Lautite | CuAsS | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
2.CB.42 | Lingbaoite | AgTe3 | Trig. 3_m_ : R_3_m |
2.CB.45 | Cadmoselite | CdSe | Hex. 6_m_ m : P_63_m c |
2.CB.45 | Rambergite | MnS | Hex. 6_m_ m : P_63_m c |
2.CB.45 | Buseckite | (Fe,Zn,Mn)S | Hex. 6_m_ m : P_63_m c |
2.CB.45 | Maletoyvayamite | Au3Se4Te6 | Tric. 1 : _P_1 |
2.CB.45 | Greenockite | CdS | Hex. 6_m_ m : P_63_m c |
2.CB.45 | Wurtzite | (Zn,Fe)S | Hex. 6_m_ m : P_63_m c |
2.CB.47 | Murchisite | Cr5S6 | Trig. 3_m_ _(_32/m ) : P_31_c |
2.CB.50 | Zincselenide | ZnSe | |
2.CB.50 | Wassonite | TiS | Trig. 3_m_ _(_32/m ) : R_3_m |
2.CB.52 | Dzhezkazganite | ReMoCu2PbS6 ? | Trig. 3_m_ : R_3_m |
2.CB.55b | Isocubanite | CuFe2S3 | Iso. m_3_m _(_4/_m_32/m ) : F m_3_m |
2.CB.55a | Cubanite | CuFe2S3 | Orth. m m m _(_2/_m_2/_m_2/m ) |
2.CB.60 | Raguinite | TlFeS2 | Orth. |
2.CB.60 | Picotpaulite | TlFe2S3 | Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m |
2.CB.65 | Argentopyrite | AgFe2S3 | Mon. 2/m |
2.CB.65 | Sternbergite | AgFe2S3 | Orth. m m m _(_2/_m_2/_m_2/m ) |
2.CB.70 | Sulvanite | Cu3VS4 | Iso. 43_m_ : P_43_m |
2.CB.75 | Vulcanite | CuTe | Orth. m m m _(_2/_m_2/_m_2/m ) |
2.CB.80 | Empressite | AgTe | Orth. m m m _(_2/_m_2/_m_2/m ) |
2.CB.85 | Muthmannite | AuAgTe2 | Mon. 2/m : _P_2/m |
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
It is the principal ore of copper.
Chalcopyrite in petrologyHide
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Internet Links for ChalcopyriteHide
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References for ChalcopyriteHide
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Reference List:
Boekema, C, Krupski, A.M, Varasteh, M, Parvin, K, van Til, F, van der Woude, F, Sawatzky, G.A (2004) Cu and Fe valence states in CuFeS2. Journal of Magnetism and Magnetic Materials, 272. 559-561 doi:10.1016/j.jmmm.2003.11.206
Goh, Siew Wei, Buckley, Alan N., Lamb, Robert N., Rosenberg, Richard A., Moran, Damian (2006) The oxidation states of copper and iron in mineral sulfides, and the oxides formed on initial exposure of chalcopyrite and bornite to air. Geochimica et Cosmochimica Acta, 70 (9) 2210-2228 doi:10.1016/j.gca.2006.02.007
Pearce, C.I., Pattrick, R.A.D., Vaughan, D.J., Henderson, C.M.B., van der Laan, G. (2006) Copper oxidation state in chalcopyrite: Mixed Cu d9 and d10 characteristics. Geochimica et Cosmochimica Acta, 70 (18) 4635-4642 doi:10.1016/j.gca.2006.05.017
[1]Tang, Yao, Sun, Deyou, Gou, Jun, Ni, Xinran, Zeng, Xiaohui, Zhang, Xingmin, Liu, Weipeng, Liang, Shanshan, Deng, Changzhou (2025) Chalcopyrite geochemistry: Advancements and implications in ore deposit research. Ore Geology Reviews, 179. 106528 doi:10.1016/j.oregeorev.2025.106528
Significant localities for ChalcopyriteHide
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Showing 34 significant localities out of 33,213 recorded on mindat.org.
This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The
symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed.
- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.