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Papers by Simon King
SSRN Electronic Journal, 2021
ENERGY & ENVIRONMENTAL MATERIALS, 2021
Thermoelectrics are a promising solution to the recovery of some of the 60% of the worldwide ener... more Thermoelectrics are a promising solution to the recovery of some of the 60% of the worldwide energy wasted as heat. However, their conversion efficiency is low and the best performing materials are brittle, toxic, and made of expensive ceramics. The challenge in developing better performing materials is in disrupting the electrical vs thermal conductivity correlation, to achieve low thermal conductivity simultaneously with a high electrical conductivity. Carbon nanotubes allow for the decoupling of the electronic density of states from the phonon density of states and this paper shows that flexible, thin films of double‐walled carbon nanotube (DWCNT) can form effective n‐ and p‐doped semiconductors that can achieve a combined Seebeck coefficient of 157.6 µV K−1, the highest reported for a single DWCNT device to date. This is achieved through selected surfactant doping, whose role is correlated with the length of the hydrocarbon chain of the hydrophobic tail group of the surfactant’s...
ACS Applied Materials & Interfaces, 2020
Advanced Manufacturing: Polymer & Composites Science, 2019
Electrospun nonwoven veils comprising thermoplastic fibres (average diameter 400-600 nm) based on... more Electrospun nonwoven veils comprising thermoplastic fibres (average diameter 400-600 nm) based on polysulfone (PSU), polyamide (PA-6,6), and polyetherimide (PEI) have been fabricated and used as interlaminar reinforcements in carbon fibre composites containing a commercial epoxy resin (8552/IM7). Samples were tested for their interlaminar properties and improvements were observed in the initial mode I interlaminar toughness of 30% (PA-6,6), 36% (PEI), and 44% (PSU), while improvements of 7% (PSU) and 8% (PEI) were observed in the propagation of the mode I interlaminar toughness. A reduction of 11% was observed for the propagation of the mode I interlaminar toughness for PA-6,6. Post-testing analysis of the cross-section and the fracture surface revealed that the crack front avoids the reinforcement significantly for PA-6,6. For mode II, however, this failure mechanism leads to improvements of 30% in interlaminar toughness for the PA-6,6, whereas the other reinforcements display negligible (PEI) and 31% reduction (PSU) interlaminar toughness.
Advanced Electronic Materials, 2018
The version in the Kent Academic Repository may differ from the final published version. Users ar... more The version in the Kent Academic Repository may differ from the final published version. Users are advised to check http://kar.kent.ac.uk for the status of the paper. Users should always cite the published version of record.
Journal of Materials Chemistry, 2009
A series of donoracceptor diblock copolymers with varying molecular weight are studied in thin f... more A series of donoracceptor diblock copolymers with varying molecular weight are studied in thin film and compared with an 'equivalent' blend formed from donor and acceptor homopolymers. Steady-state and transient spectroscopies are used to demonstrate a ...
SSRN Electronic Journal, 2021
ENERGY & ENVIRONMENTAL MATERIALS, 2021
Thermoelectrics are a promising solution to the recovery of some of the 60% of the worldwide ener... more Thermoelectrics are a promising solution to the recovery of some of the 60% of the worldwide energy wasted as heat. However, their conversion efficiency is low and the best performing materials are brittle, toxic, and made of expensive ceramics. The challenge in developing better performing materials is in disrupting the electrical vs thermal conductivity correlation, to achieve low thermal conductivity simultaneously with a high electrical conductivity. Carbon nanotubes allow for the decoupling of the electronic density of states from the phonon density of states and this paper shows that flexible, thin films of double‐walled carbon nanotube (DWCNT) can form effective n‐ and p‐doped semiconductors that can achieve a combined Seebeck coefficient of 157.6 µV K−1, the highest reported for a single DWCNT device to date. This is achieved through selected surfactant doping, whose role is correlated with the length of the hydrocarbon chain of the hydrophobic tail group of the surfactant’s...
ACS Applied Materials & Interfaces, 2020
Advanced Manufacturing: Polymer & Composites Science, 2019
Electrospun nonwoven veils comprising thermoplastic fibres (average diameter 400-600 nm) based on... more Electrospun nonwoven veils comprising thermoplastic fibres (average diameter 400-600 nm) based on polysulfone (PSU), polyamide (PA-6,6), and polyetherimide (PEI) have been fabricated and used as interlaminar reinforcements in carbon fibre composites containing a commercial epoxy resin (8552/IM7). Samples were tested for their interlaminar properties and improvements were observed in the initial mode I interlaminar toughness of 30% (PA-6,6), 36% (PEI), and 44% (PSU), while improvements of 7% (PSU) and 8% (PEI) were observed in the propagation of the mode I interlaminar toughness. A reduction of 11% was observed for the propagation of the mode I interlaminar toughness for PA-6,6. Post-testing analysis of the cross-section and the fracture surface revealed that the crack front avoids the reinforcement significantly for PA-6,6. For mode II, however, this failure mechanism leads to improvements of 30% in interlaminar toughness for the PA-6,6, whereas the other reinforcements display negligible (PEI) and 31% reduction (PSU) interlaminar toughness.
Advanced Electronic Materials, 2018
The version in the Kent Academic Repository may differ from the final published version. Users ar... more The version in the Kent Academic Repository may differ from the final published version. Users are advised to check http://kar.kent.ac.uk for the status of the paper. Users should always cite the published version of record.
Journal of Materials Chemistry, 2009
A series of donoracceptor diblock copolymers with varying molecular weight are studied in thin f... more A series of donoracceptor diblock copolymers with varying molecular weight are studied in thin film and compared with an 'equivalent' blend formed from donor and acceptor homopolymers. Steady-state and transient spectroscopies are used to demonstrate a ...