Cooperative Bimetallic Effects on New Iridium(III) Pyrazolate Complexes:  Hydrogen−Hydrogen, Carbon−Hydrogen, and Carbon−Chlorine Bond Activations (original) (raw)

C−H Activation Reactions on Rh(I)−Ethylene Complexes of the Hydrotris(3,5-dimethylpyrazolyl)borate Ligand, Tp Me 2

Antonio Pizzano

Organometallics, 1999

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Hydrogen bonds, coordination isomerism, and catalytic dehydrogenation of alcohols with the bifunctional iridium pincer complex ^{{{\left( {HOC{H_2}} \right)}_2}}\left( {P{C_{s{p^3}}}P} \right)$$ ( H O C H 2 ) 2 ( P C s p 3 P ) IrHCl

Natalia Belkova

Russian Chemical Bulletin, 2015

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Labile Hydrido Complexes of Iridium(III): Synthesis, Dynamic Behavior in Solution, and Reactivity toward Alkenes

Jose Lopez

Organometallics, 1999

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Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexes

Dmitry Gusev, Alberto Albinati, Vladimir Bakhmutov

Journal of the …, 1993

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Activation of H–H, HO–H, C(sp2)–H, C(sp3)–H, and RO–H Bonds by Transition-Metal Frustrated Lewis Pairs Based on M/N (M = Rh, Ir) Couples

Fernando Lahoz

Inorganic Chemistry, 2022

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Polynuclear iridium hydrido complexes

Pierre Braunstein

Coordination Chemistry Reviews, 1989

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Vinylic C−H Bond Activation and Hydrogenation Reactions of Tp‘Ir(C2H4)(L) Complexes

Pedro Ferrer Perez

Inorganic Chemistry, 1998

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Protonation Reactions of Dinuclear Pyrazolato Iridium(I) Complexes

Cristina Tejel

Inorganic Chemistry, 2003

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Heterolytic H 2 Activation by Dihydrogen Complexes. Effects of the Ligand X in [M(X)H 2 {Ph 2 P(CH 2 ) 3 PPh 2 } 2 ] n + (M = Ru, Os; X = CO, Cl, H)

Alessandro Del Zotto, Antonio Mezzetti

Inorganic Chemistry, 1997

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Preparation and reactivity of iridium(III) hydride complexes with pyrazole and imidazole ligands

Gabriel Chc

Journal of Organometallic Chemistry, 2006

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Ruthenium Hydride Complexes of 1,2-Dicyclohexylimidazol-2-ylidene

Gabriele Kociok-köhn

Organometallics, 2005

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Iridium alkoxide and amide hydride complexes. Synthesis, reactivity, and the mechanism of oxygen-hydrogen and nitrogen-hydrogen reductive elimination

David Glueck

Organometallics, 1991

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Dihydrogen-Catalyzed Reversible Carbon-Hydrogen and Nitrogen-Hydrogen Bond Formation in Organometallic Iridium Complexes

Joaquín López-serrano

Angewandte Chemie International Edition, 2012

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Activation of C H bonds in acetylene and terminal alkynes by rhodium (I) species. Crystal structure of cis-(ethynyl) hydride [(NP 3) Rh (H)(C CH)] BPh 4· 1.5 C 4 H 8 O (NP 3= N (CH 2 CH 2 PPh 2) 3)

Carlo Mealli

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C–H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study

Werner Kaminsky

Organometallics, 2012

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Hydrido formyl, methoxycarbonyl, hydroxymethyl, and methyl complexes of iridium: syntheses and reactivities

David Thorn

Organometallics, 1982

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Methyleneimine CH2dNH as a Unidentate Ligand in Rhenium Complexes This work was supported by MIUR (Rome)—Programmi di Ricerca Scientifica di Rilevante Interesse Nazionale, Cofinanziamento 2000–2001. We thank Daniela Baldan for technical assistance

Gabriele Albertin, Stefano ANTONIUTTI

Angewandte Chemie International Edition, 2002

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Stereochemical investigations of the mechanism of CH bond activation. Diastereomeric and isotopic scrambling in (hydrido)alkyliridium complexes

T. Andrew Mobley

Organometallics, 1998

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New Rh(III) complexes of 5‐methyl‐5‐(pyridyl)‐2,4‐imidazolidenedione: Synthesis, X‐ray structure, electrochemical study and catalytic behaviour for hydrogenation of ketones

Davood Nematollahi

Applied Organometallic Chemistry, 2017

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Stoichiometric and Catalytic H/D Incorporation by Cationic Iridium Complexes: A Common Monohydrido-Iridium Intermediate

Marc Skaddan

Journal of the American Chemical Society, 2004

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Thermal and photochemical carbon-hydrogen bond reactions of alkenes in (tris(pyrazolyl)borato)iridium(I) complexes

Robin Tanke

Inorganic Chemistry, 1989

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NMR spectra and the products of interaction of iridium monohydrides IrHCl2L2 (LP(CH(CH3)2)3 and P(c-C6H11)3) with molecular hydrogen

Vladimir Bakhmutov

Inorganica Chimica Acta, 1990

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η5-Indenylruthenium(II) hydride complexes: synthesis and protonation reactions

Covadonga González-Bernardo

Inorganica Chimica Acta, 2003

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Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H3(M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal

Rinaldo Poli

Russian Chemical Bulletin, 2003

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Rhodium(I) Complexes with OPPy2Ph and OPPy3 (Py = 2-Pyridyl), and Their Behavior in Hydrogenation Reactions

Pablo Espinet

European Journal of Inorganic Chemistry, 2001

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Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes

Natalia Belkova

Mendeleev Communications, 2019

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Substitution and Hydrogenation Reactions on Rhodium(I)−Ethylene Complexes of the Hydrotris(pyrazolyl)borate Ligands Tp‘ (Tp‘ = Tp, Tp Me2

tp tp

Inorganic Chemistry, 2000

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Hydridobipyridine rhodium complexes as a result of the C–H bond activation in coordinated ligand, NMR studies

Florian Pruchnik

Polyhedron, 2006

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Evidence for a possible trans oxidative addition of hydrogen to an iridium complex

John Harrod

Journal of the American Chemical Society, 1979

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Reactivity of Tp Me2 -Containing Hydride–Iridafurans with Alkenes, Alkynes, and H 2

Eleuterio Alvarez

Organometallics, 2014

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Reactions of the Rhenium(I) Fragment [{MeC(CH2PPh2)3}Re(CO)2]+. Synthesis and Characterization of a Stable Cationic .eta.2-H2 Complex of Rhenium

Roberto Rossi

Organometallics, 1995

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