Evidence for a possible trans oxidative addition of hydrogen to an iridium complex (original) (raw)

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Hydrido formyl, methoxycarbonyl, hydroxymethyl, and methyl complexes of iridium: syntheses and reactivities

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NMR spectra and the products of interaction of iridium monohydrides IrHCl2L2 (LP(CH(CH3)2)3 and P(c-C6H11)3) with molecular hydrogen

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The interaction of a cyclo-octa-1,5-diene-iridium complex with molecular hydrogen

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Stereochemical investigations of the mechanism of CH bond activation. Diastereomeric and isotopic scrambling in (hydrido)alkyliridium complexes

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Cooperative Bimetallic Effects on New Iridium(III) Pyrazolate Complexes: Hydrogen−Hydrogen, Carbon−Hydrogen, and Carbon−Chlorine Bond Activations

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Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexes

Dmitry Gusev, Alberto Albinati, Vladimir Bakhmutov

Journal of the …, 1993

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Characterization and oxidative addition reactions of rhodium(I) carbonyl cupferrate diphenyl-2-pyridylphoshine complexes

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2013

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Homogeneous hydrogenations and related reductive reactions catalyzed by rhenium complexes

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Oxidative dehydrodimerization of rhenium vinylidene complex (η5-C5H5)(CO)2ReCC(H)Ph: two competitive routes of coupling of σ-phenylethynyl intermediate [(η5-C5H5)(CO)2ReCCPh]. X-ray structures of rhenium mononuclear (η5-C5H5)(CO)2ReCC(H)Ph and binuclear [(η5-C5H5)(CO)2Re]2(μ2-CC(Ph)CCPh) vinylide...

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The reactivity of the [Re≡O]3+ core toward aromatic 1,2-diamines: the formation of rhenium(V)-imido complexes

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Oxidative Addition Reactions of I2 with [HIr4(CO)10-n(PPh3 )n(μ-PPh2)] (n = 1 and 2) and Crystal and Molecular Structure of [HIr4(μ-I)2(CO)7 (PPh3)(μ-PPh2)&#93

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Journal of the Brazilian Chemical Society, 2002

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IR induced isomerisation of HDO complexes: a method for the observation of FIR spectra of matrix isolated water complexes

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Chemical Physics, 1996

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Activation of the CH bond. Pentahydridobis(tertiary- phosphine)iridium and related complexes as homogeneous catalysts for hydrogen transfer involving monoolefins

Federico Maspero

Journal of Organometallic Chemistry, 1975

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Reactivity of an Aromatic sigma, sigma, sigma-Triradical: The 2, 4, 6-Tridehydropyridinium Cation

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Vinylic C−H Bond Activation and Hydrogenation Reactions of Tp‘Ir(C2H4)(L) Complexes

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Effect of CO on the Oxidative Addition of Arene CH Bonds by Cationic Rhodium Complexes

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Gas-phase reactions. 55. O=C=C=C=S: Synthesis and PE spectrum

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Rhenium complexes in homogeneous hydrogen evolution

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Trihydrogen complexes of iridium

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Journal of the American Chemical Society, 1988

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Vibrational spectra of ligands and complexes—III Dimethylphenylarsine, methyldiphenylarsine, triphenylarsine and o-phenylenebis(dimethylarsine)

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Spectrochimica Acta Part A: Molecular Spectroscopy, 1968

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The reaction of M(CO)3(Ph2PCH2CH2PPh2) (M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products

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Temperature-dependent stereoselectivity and hydrogen deuterium kinetic isotope effect for .gamma.-hydrogen transfer to 2-hexyloxy radical. The transition state for the Barton reaction

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Journal of the American Chemical Society, 1986

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Reactions of the cis-Dicarbonyl Compound Ir(.eta.1-OC(O)CH3)(CO)2(PCy3) with HSnPh3, HSiR3 (R = Ph, Et), and Hx+1SiPh3-x (x = 1, 2)

Fernando Lahoz

Organometallics, 1994

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Hydridometallacycloalkane complexes of iridium. Unassisted intramolecular distal carbon-hydrogen bond activation

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Journal of the American Chemical Society, 1981

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Activation of carbon-hydrogen bonds in alkanes and other organic molecules by Ir(I), Rh(I) and Ir(III) complexes

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Pure and Applied Chemistry, 1995

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