Activation Energy Research Papers - Academia.edu (original) (raw)

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The electrical properties of double perovskite Ho2NiTiO6 (HNT) are investigated by impedance spectroscopy in the temperature range 30–420 °C and frequency range 100 Hz to 1 MHz. The X-ray diffraction analysis reveals that the compound... more

The electrical properties of double perovskite Ho2NiTiO6 (HNT) are investigated by impedance spectroscopy in the temperature range 30–420 °C and frequency range 100 Hz to 1 MHz. The X-ray diffraction analysis reveals that the compound crystallizes in monoclinic phase. The imaginary part of impedance (Z″) as a function of frequency shows Debye type relaxation. The frequency dependence of Z″ peak is found to obey an Arrhenius law with an activation energy of 0.129 eV. Impedance data presented in the Nyquist plot (Z″ vs. Z′) are used to identify an equivalent circuit and to know the bulk and interface contributions. The complex impedance analysis of HNT exhibits the appearance of both the grain and grain-boundary contribution. The results of bulk ac conductivity as a function of temperature and frequency are presented. The activation energy (0.129 eV), calculated from the slope of log τ versus 103/T plot, is found to be the nearly same as calculated (0.130 eV) from dc conductivity. The frequency dependent conductivity spectra obey the power law.

In this study an artificial neural network (ANN) model was developed to predict the oxidation behavior of magnesia graphite composites. After mechanism evaluation in different conditions, the kinetic parameters such as effective diffusion... more

In this study an artificial neural network (ANN) model was developed to predict the oxidation behavior of magnesia graphite composites. After mechanism evaluation in different conditions, the kinetic parameters such as effective diffusion coefficient and diffusion activation energy of oxidation were calculated from ANN predicted results at different graphite content. The obtained mechanism and kinetic parameters were compared with experimental data.First of all, the reliability of the model was checked with different available data. It was found that the model results were in good agreement with experimental data prediction.The results showed that the main mechanism of oxidation was pore diffusion and effective diffusion coefficient as well as diffusion activation energy were comparable with previous works.Effective diffusion coefficient and diffusion activation energy which were calculated versus graphite content are in good agreement with experimental values.

The kinetic consequences of resonance tunnelling processes that may occur in chemical reactions are investigated in terms of a multi-centered unsymmetrical Eckart potential barrier. This potential function does not only simulate the... more

The kinetic consequences of resonance tunnelling processes that may occur in chemical reactions are investigated in terms of a multi-centered unsymmetrical Eckart potential barrier. This potential function does not only simulate the possible existence of intermediate wells in the effective potential energy cut along the reaction path, but also is amenable to analytic solutions. The reaction rate as well as its dependence on temperature, reduced mass,Q-value, activation energy and barrier diffuseness are evaluated for successively increasing the number of barrier stages. Comparisons between results due to single and multi-humped potential energy barriers are made and discussed.

Siliceous, aluminosilicate and niobosilicate mesoporous molecular sieves of MCM-41 type have been used as matrices for nickel incorporated via the wet impregnation. The N 2 adsorption, XRD, H 2 -TPR and Ni dispersion study were applied... more

Siliceous, aluminosilicate and niobosilicate mesoporous molecular sieves of MCM-41 type have been used as matrices for nickel incorporated via the wet impregnation. The N 2 adsorption, XRD, H 2 -TPR and Ni dispersion study were applied for the characterization of the ...

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