o-Phenylenediamine Research Papers - Academia.edu (original) (raw)
Abstract A simple and efficient method is demonstrated for the synthesis of benzimidazoles via cyclocondensation of o-phenylenediamine with aldehydes in the presence of catalytic amount of tert-butyl nitrite. All the reactions were... more
Abstract A simple and efficient method is demonstrated for the synthesis of benzimidazoles via cyclocondensation of o-phenylenediamine with aldehydes in the presence of catalytic amount of tert-butyl nitrite. All the reactions were carried out at room temperature while the desired products were obtained in good to excellent yields.
A simple, highly efficient and green procedure for the condensation of o-phenylenediamine with α-diketones in the presence of catalytic quantity of phthalic acid(0.0083 g, 5mol%) at room temperature was done. Using this method,... more
A simple, highly efficient and green procedure for the condensation of o-phenylenediamine with α-diketones in the presence of catalytic quantity of phthalic acid(0.0083 g, 5mol%) at room temperature was done. Using this method, quinoxaline derivatives as biological fascinating compound are produced in good to excellent yields and short reaction times. Keywords:Quinoxaline, o-Phenylenediamine, α-Diketone, Phthalic acid, Green chemistry.