Merlinoite (original) (raw)

A valid IMA mineral species

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About MerlinoiteHide

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Formula:

(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O

Specific Gravity:

2.14 - 2.27

Crystal System:

Orthorhombic

Name:

Named in 1977 by Elio Passaglia, D. Pongiluppi and R. Rinaldi in honour of Stefano Merlino (1938 - ), Professor of crystallography, University of Pisa, Italy.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2651:8

3da70ecc-f226-4c9d-ad07-0b15069d5c4d

IMA Classification of MerlinoiteHide

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IMA Formula:

K5Ca2(Si23Al9)O64 · 24H2O

Type description reference:

Classification of MerlinoiteHide

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9.GC.15

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
C : Chains of doubly-connected 4-membered rings

77.1.3.11

77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites

16.12.14

16 : Silicates Containing Aluminum and other Metals
12 : Aluminosilicates of Sr, Ba and Zn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Mrl IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MerlinoiteHide

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Density:

2.14 - 2.27 g/cm3 (Measured) 2.21(2) g/cm3 (Calculated)

Optical Data of MerlinoiteHide

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RI values:

_n_α = 1.499 _n_β = 1.500 _n_γ = 1.501

2V:

Measured: 56° , Calculated: 88°

δ = 0.002

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X = b; Y = c; Z = a.

Chemistry of MerlinoiteHide

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Mindat Formula:

(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O

Crystallography of MerlinoiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 14.116(7) Å, b = 14.229(6) Å, c = 9.946(6) Å

Ratio:

a:b:c = 0.992 : 1 : 0.699

Unit Cell V:

1,997.72 ų (Calculated from Unit Cell)

Morphology:

Rectangular prisms formed by the {100} and {010} pinacoids, terminated by two orthorhombic prisms with different development. Radiating fibrous spheroidal aggregates.

Comment:

Pseudo-tetragonal.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0014759 Merlinoite Galli E, Gottardi G, Pongiluppi D (1979) The crystal structure of the zeolite merlinoite Neues Jahrbuch fur Mineralogie, Monatshefte 1979 1-9 1979 in a vug of a lava from Cupaello, Rieti, Italy 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.176 Å (100)
7.115 Å (90)
7.080 Å (88)
3.258 Å (44)
3.241 Å (41)
5.359 Å (40)
3.226 Å (38)

Comments:

Cupaello Quarry, Lazio, Italy. Data from the type description.

Geological EnvironmentHide

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Type Occurrence of MerlinoiteHide

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General Appearance of Type Material:

Spheroidal radial aggregates with a diameter less than 1 mm.

Place of Conservation of Type Material:

Municipal Museum of Natural History, Milan, 18078; University of Modena, Modena, Italy; Natural History Museum, Paris, France; National Museum of Natural History, Washington, D.C., USA, 137087.

Geological Setting of Type Material:

In cavities in kalsilite-melilite rock.

Associated Minerals at Type Locality:

Reference:

Passaglia, E., Pongiluppi, D., Rinaldi, R. (1977) Merlinoite, a new mineral of the zeolite group. Neues Jahrbuch für Mineralogie, Monatshefte: 355-364.

Synonyms of MerlinoiteHide

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Other Language Names for MerlinoiteHide

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Relationship of Merlinoite to other SpeciesHide

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Other Members of this group:

Alflarsenite NaCa2Be3Si4O13(OH) · 2H2O Mon. 2 : _P_21
Amicite K2Na2Al4Si4O16 · 5H2O Mon. 2
Ammonioleucite (NH4)(AlSi2O6) Tet. 4/m : _I_41/a
Analcime Na(AlSi2O6) · H2O Tric. 1 : _P_1
Bellbergite (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O Hex.
Bikitaite LiAlSi2O6 · H2O Tric. 1 : _P_1
Boggsite Ca8Na3(Si,Al)96O192 · 70H2O Orth. m m m _(_2/_m_2/_m_2/m ) : I m m a
Brewsterite Subgroup Zeolite Group.
Chabazite-Levyne Subgroup M[Al2Si4O12] · 6H2O
Chiavennite CaMnBe2Si5O13(OH)2 · 2H2O Mon. 2/m : _P_21/b
Clinoptilolite Subgroup M3-6(Si30Al6)O72 · 20H2O
Cowlesite CaAl2Si3O10 · 6H2O Orth. m m m _(_2/_m_2/_m_2/m )
Dachiardite Subgroup Zeolite Group.
Direnzoite NaK6MgCa2(Al13Si47O120) · 36H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
Edingtonite Ba[Al2Si3O10] · 4H2O Orth. 222 : _P_212121
Epistilbite CaAl2Si6O16 · 5H2O Mon.
Erionite Subgroup M2[Al4Si14O36] · 15H2O
Faujasite Subgroup M3.5[Al7Si17O48] · 32H2O
Ferrierite Subgroup Zeolite Group.
Ferrochiavennite Ca1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2O Mon. 2/m : _P_21/b
Flörkeite (K3Ca2Na)[Al8Si8O32] · 12H2O Tric. 1 : _P_1
Garronite Subgroup
Gaultite Na4Zn2Si7O18 · 5H2O Orth. m _m_2 : F d _d_2
Gismondine Subgroup Zeolite Group.
Gmelinite Subgroup In 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
Gobbinsite Na5(Si11Al5)O32 · 11H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
Goosecreekite Ca[Al2Si6O16] · 5H2O Mon. 2 : _P_21
Gottardiite Na3Mg3Ca5Al19Si117O272 · 93H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
Heulandite Subgroup (Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O
Hsianghualite Ca3Li2(Be3Si3O12)F2 Iso. 432 : _I_4132
Kirchhoffite Cs(BSi2O6) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
Laumontite CaAl2Si4O12 · 4H2O Mon. 2/m : _B_2/m
Loomisite Ba[Be2P2O8] · H2O Mon. m
Lovdarite K2Na6Be4Si14O36 · 9H2O Orth. m _m_2
Maricopaite Pb7Ca2(Si,Al)48O100 · 32H2O Orth.
Martinandresite Ba2(Al4Si12O32) · 10H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
Mazzite Subgroup Zeolite Group.
Montesommaite (K,Na)9Al9Si23O64 · 10H2O Orth. m _m_2 : F d _d_2
Mordenite (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O Orth.
Mutinaite Na3Ca4Si85Al11O192 · 60H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
Nabesite Na2BeSi4O10 · 4H2O Orth. 222 : _P_212121
Natrolite Subgroup A subgroup of the Zeolite Group.
Offretite KCaMg(Si13Al5)O36 · 15H2O Hex. 6_m_2 : _P_6_m_2
Pahasapaite Li8(Ca,Li,K)10.5Be24(PO4)24 · 38H2O Iso. 23 : _I_23
Parthéite Ca2(Si4Al4) O15 (OH)2 · 4H2O Mon. 2/m : _B_2/b
Paulingite Subgroup Paulingite was originally described in 1960.
Perlialite K9Na(Ca,Sr)[Al2Si4O12]6 · 15H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
Phillipsite Subgroup Zeolite Group.
Pollucite (Cs,Na)2(Al2Si4O12) · 2H2O Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
Roggianite Ca2Be(OH)2Al2Si4O13 · 2.5H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m c m
Stilbite Subgroup M6-7[Al8-9Si27-28O72] · nH2O
Terranovaite (Na,Ca)8(Si68Al12)O160 · 29H2O Orth.
Thomsonite Subgroup The large majority of "thomsonite" is thomsonite-Ca.
Tschernichite (Ca,Na2)[Al2Si4O12] · 4-8H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/m m m
Tschörtnerite Ca4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2O Iso. m_3_m _(_4/_m_32/m ) : F m_3_m
UM1996-38-SiO:AlCaHNa Na-Ca-Al-Si-O-H
UM1999-33-SiO:AlHKNa K7Na5Al12Si20O64 · 24H2O
UM2002-40-SiO:AlCaHKMgNa (Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2O Tet. 422 : _P_4122
Unnamed (Ca analogue of Merlinoite) (Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ?
Wairakite Ca(Al2Si4O12) · 2H2O Mon. 2/m : _B_2/m
Weinebeneite CaBe3(PO4)2(OH)2 · 4H2O Mon. m : B b
Wenkite (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O Hex. 6_m_2 : P_62_m
Willhendersonite KCa[Al3Si3O12] · 5H2O Tric. 1 : _P_1
Yugawaralite CaAl2Si6O16 · 4H2O Mon. m : P b

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.GC. Garronite-Na Na6(Al6Si10O32) · 8.5H2O Mon. 2
9.GC. Gismondine-Sr Sr4(Si8Al8O32) · 9H2O Orth. 222 : _C_2221
9.GC.05 Amicite K2Na2Al4Si4O16 · 5H2O Mon. 2
9.GC.05 Garronite-Ca Na2Ca5Al12Si20O64 · 27H2O Tet. 42_m_ : _I_4_m_2
9.GC.05 Gismondine-Ca CaAl2Si2O8 · 4H2O Mon. 2/m : _P_21/b
9.GC.05 Gobbinsite Na5(Si11Al5)O32 · 11H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
9.GC.05 Gismondine-Ba Ba2Al4Si4O16 · 4-6H2O
9.GC.10 Harmotome Ba2(Si12Al4)O32 · 12H2O Mon. 2/m : _P_21/m
9.GC.10 Phillipsite-Ca Ca3(Si10Al6)O32 · 12H2O Mon. 2/m : _P_21/m
9.GC.10 Phillipsite-K (K,Na,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O Mon. 2/m : _P_21/m
9.GC.10 Phillipsite-Na (Na,K,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] · 12H2O Mon. 2/m : _P_21/m
9.GC.10 Flörkeite (K3Ca2Na)[Al8Si8O32] · 12H2O Tric. 1 : _P_1
9.GC.10 Martinandresite Ba2(Al4Si12O32) · 10H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
9.GC.20 Mazzite-Mg (Mg,K,Ca)5(Si26Al10)O72 · 28H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.GC.20 Mazzite-Na Na8[Al4Si14O36]2 · 30H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.GC.25 Perlialite K9Na(Ca,Sr)[Al2Si4O12]6 · 15H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
9.GC.30 Boggsite Ca8Na3(Si,Al)96O192 · 70H2O Orth. m m m _(_2/_m_2/_m_2/m ) : I m m a
9.GC.35 Paulingite-Ca (Ca,K,Na,Ba, ◻)10 (Si, Al)42O84 · 34H2O Iso. m_3_m _(_4/_m_32/m )
9.GC.35 Paulingite-K (K2,Ca,Na2,Ba)5[Al10Si35O90] · 45H2O Iso. m_3_m _(_4/_m_32/m )
9.GC.35 Paulingite-Na (Na2,K2,Ca,Ba)5[Al10Si35O90] · 45H2O Iso.

Other InformationHide

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IR Spectrum:

The IR spectrum distinguishes between merlinoite and phillipsite.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for MerlinoiteHide

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Reference List:

Coombs, Douglas S., Alberti, Alberto, Armbruster, Thomas, Artioli, Gilberto, Colella, Carmine, Galli, Ermanno, Grice, Joel D., Liebau, Friedrich, Mandarino, Joseph A., Minato, Hideo, Nickel, Ernest H., Passaglia, Elio, Peacor, Donald R., Quartieri, Simona, Rinaldi, Romano, Ross, Malcolm I., Sheppard, Richard A., Tillmanns, Ekkehart, Vezzalini, Giovanna (1997) Recommended nomenclature for zeolite minerals; report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. The Canadian Mineralogist, 35 (6) 1571-1606

Gatta, G. Diego, Rotiroti, Nicola, Bersani, Danilo, Bellatreccia, Fabio, Ventura, Giancarlo Della, Rizzato, Silvia (2015) A multi-methodological study of the (K,Ca)-variety of the zeolite merlinoite. Mineralogical Magazine, 79 (7) 1755-1767 doi:10.1180/minmag.2015.079.7.03

Localities for MerlinoiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

France
Auvergne-Rhône-Alpes Haute-Loire Le Puy-en-Velay Saint-Pierre-Eynac Mont Peylenc quarry Galli et al. (2008)
Germany
Baden-Württemberg Freiburg Region Tuttlingen Immendingen Höwenegg Quarry (Hewenegg Quarry) Tschernich (1992)
Bavaria Lower Franconia Haßberge District Maroldsweisach Zeilberg Quarry Wittern (2001)
Hesse Darmstadt Wetteraukreis Nidda Unter-Widdersheim Unter-Widdersheim quarry Betz (2019)
Ortenberg Gaulsberg quarry
Iceland
Northeastern Region Tjörneshreppur Tjörnes Hallbjarnarstaðará SCHNORRER-KÖHLER (1990)
Italy
Campania Metropolitan City of Naples Ercolano San Vito San Vito Quarry Elmar Lackner collection +1 other reference
Pollena Trocchia Pollena quarries Collection of Alex Earl
Sant'Anastasia Lagno Amendolare Russo et al. (2004) +1 other reference
Somma Vesuviana Trapolino Quarry (Cava Nuova) Badham (1997) +1 other reference
Terzigno Vitiello Quarry (Cava Vitiello) Chinellato Matteo
Lazio Metropolitan City of Rome Capital Magliano Romano Fosso Attici Giancarlo Della Ventura et al. (1993)
Sacrofano Biachella Valley
Rieti Province Rieti Santa Rufina Cupaello Quarry (TL) Sabatini (1903) +6 other references
Russia
Murmansk Oblast Khibiny Massif Koashva Mt PEKOV et al. (2013)
Kukisvumchorr Mt Pekov et al. (2004)
Spain
Canary Islands Las Palmas Province Lanzarote Haría Famara cliff Strasser et al. (2006)
USA
California San Bernardino County Searles Lake Donahoe et al. (1984) +1 other reference