Hantz reactions (original) (raw)

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dbo:abstract Hantz reactions are a class of pattern-forming precipitation reactions in gels implementing a reaction–diffusion system. The precipitation patterns are forming as a reaction of two electrolytes: a highly concentrated "outer" one diffuses into a hydrogel, while the "inner" one is dissolved in the gel itself. The colloidal precipitate which builds up the patterns is trapped by the gel and kept at the location where it is formed., similar to the Liesegang rings. The first representative of this class of reactions was the NaOH (outer electrolyte)+CuCl2 (inner electrolyte). Later the NaOH+AgNO3, the CuCl2+K3[Fe(CN)6], the NaOH+AlCl3, and the NH3+AgNO3 reactions in several hydrogels have also proved to show similar behavior. Precipitate patterns forming in these reactions are exceptionally rich. Besides the macroscopic shapes like layered structures, helices and cardioids, regular sheets of colloidal precipitate may also emerge with a periodicity even less than 20 micrometers (microscopic patterns). (en)
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dbo:wikiPageExternalLink http://hantz.web.elte.hu/cikk1/data.html http://www.insilico.hu/liesegang/helix/helix.html https://malagabay.wordpress.com/2013/10/29/liesegang-rings-2-spirals-helices-and-polygons/ http://hantz.web.elte.hu/cikk2/data2.html
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rdfs:comment Hantz reactions are a class of pattern-forming precipitation reactions in gels implementing a reaction–diffusion system. The precipitation patterns are forming as a reaction of two electrolytes: a highly concentrated "outer" one diffuses into a hydrogel, while the "inner" one is dissolved in the gel itself. The colloidal precipitate which builds up the patterns is trapped by the gel and kept at the location where it is formed., similar to the Liesegang rings. (en)
rdfs:label Hantz reactions (en)
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