Pseudobrookite (original) (raw)
A valid IMA mineral species - grandfathered
About PseudobrookiteHide
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Colour:
Brownish black, reddish brown, or black
Lustre:
Adamantine, Greasy, Metallic
Specific Gravity:
4.33 - 4.39
Crystal System:
Orthorhombic
Name:
From the Greek ψευδής, false, and brookite since its resemblance to brookite is misleading.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:3302:8
IMA Classification of PseudobrookiteHide
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Approved, 'Grandfathered' (first described prior to 1959)
IMA status notes:
Redefined by the IMA
Approval history:
Redefined 1988 s.p.: Bowles (1988).
Type description reference:
Classification of PseudobrookiteHide
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4.CB.15
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations
7.7.1.1
7 : MULTIPLE OXIDES
7 : AB2X5
7.9.16
7 : Oxides and Hydroxides
9 : Oxides of Ti
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Pbrk | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Psb | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Physical Properties of PseudobrookiteHide
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Adamantine, Greasy, Metallic
Transparency:
Transparent, Opaque
Comment:
Greasy on fractures, may be tarnished iridescent
Colour:
Brownish black, reddish brown, or black
Streak:
Reddish brown to ocher-yellow
Cleavage:
Distinct/Good
On {010} distinct
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
4.33 - 4.39 g/cm3 (Measured) 4.39 g/cm3 (Calculated)
Optical Data of PseudobrookiteHide
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RI values:
_n_α = 2.350 - 2.380 _n_β = 2.360 - 2.390 _n_γ = 2.380 - 2.420
2V:
Measured: 50° , Calculated: 80°
δ = 0.030 - 0.040
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Optical Extinction:
Y = a; Z = c; X ∧ a = 26°.
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
400nm | 22.8% | 24.0% |
420nm | 21.9% | 23.1% |
440nm | 21.2% | 22.3% |
460nm | 20.5% | 21.4% |
480nm | 19.8% | 20.7% |
500nm | 19.4% | 20.4% |
520nm | 19.0% | 19.9% |
540nm | 18.5% | 19.3% |
560nm | 18.1% | 18.8% |
580nm | 17.8% | 18.5% |
600nm | 17.5% | 18.1% |
620nm | 17.3% | 17.9% |
640nm | 17.1% | 17.7% |
660nm | 17.0% | 17.6% |
680nm | 16.8% | 17.4% |
700nm | 16.7% | 17.3% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 24.0%.
R1 shown in black, R2 shown in red
Chemistry of PseudobrookiteHide
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Crystallography of PseudobrookiteHide
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Crystal System:
Orthorhombic
Class (H-M):
m m m _(_2/_m_2/_m_2/m ) - Dipyramidal
Cell Parameters:
a = 9.7965(25) Å, b = 9.9805(25) Å, c = 3.7301(1) Å
Ratio:
a:b:c = 0.982 : 1 : 0.374
Unit Cell V:
364.71 ų (Calculated from Unit Cell)
Morphology:
Crystals usually tabular {100} and elongated [001]; long prismatic at times or needle-like [001]. {100} and {hk0} striated [001].
Twinning:
Reported on various {hk0} planes (doubtful).
Comment:
Space Group: Bbmm
Crystallographic forms of PseudobrookiteHide
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Crystal Atlas:
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Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0002073 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 0 | 293 | |
0002074 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 1.03 | 293 | |
0002075 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 2.16 | 293 | |
0002076 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 3.22 | 293 | |
0002077 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 4.34 | 293 | |
0002078 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 6.2 | 293 | |
0002079 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 7.51 | 293 | |
0002080 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 0 | 293 | |
0002081 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 1.03 | 293 | |
0002082 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 2.16 | 293 | |
0002083 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 3.22 | 293 | |
0002084 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 4.34 | 293 | |
0002085 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 6.2 | 293 | |
0002086 | Pseudobrookite | Yang H, Hazen R M (1999) Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with different ordering states American Mineralogist 84 130-137 | ![]() |
1999 | 7.51 | 293 | |
0018179 | Pseudobrookite | Pauling L (1930) The crystal structure of pseudobrookite _cod_database_code 1011342 Zeitschrift fur Kristallographie 73 97-113 | 1930 | 0 | 293 |
CIF Raw Data - click here to close
Epitaxial Relationships of PseudobrookiteHide
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Epitaxy Comments:
Pseudobrookite on hematite with pseudobrookite {121}[210] parallel to hematite {0001}[1100].
Pseudobrookite on magnetite with pseudobrookite {100}[001] parallel to magnetite {111}[110].
Oriented inclusions of rutile in pseudobrookite.
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.486 Å | (100) |
2.752 Å | (77) |
4.901 Å | (42) |
2.458 Å | (23) |
1.8657 Å | (23) |
2.407 Å | (22) |
1.9733 Å | (22) |
Comments:
Synthetic, ICDD 41-1432.
Geological EnvironmentHide
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Geological Setting:
Magmatic, post-volcanic or young volcanic rocks. Typically formed by pneumatolytic processes in titanium-rich andesite, rhyolite, basalt, etc., and by reactions with xenoliths within these; in lithophysae. Rarely in plutonic rocks.
Type Occurrence of PseudobrookiteHide
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Place of Conservation of Type Material:
No defined type material.
Associated Minerals at Type Locality:
Other Language Names for PseudobrookiteHide
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Varieties of PseudobrookiteHide
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Relationship of Pseudobrookite to other SpeciesHide
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Other Members of Pseudobrookite Group:
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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4.CB. | Magnesiohögbomite-6N12S | Mg5Al11TiO23(OH) | Trig. 3_m_ _(_32/m ) : R_3_m |
---|---|---|---|
4.CB. | Oboniobite | Mg4Nb2O9 | Trig. 3_m_ _(_32/m ) : _P_3_c_1 |
4.CB. | Ferrohögbomite-2N2S | [(Fe2+,Mg,Zn,Al)3(Al,Ti,Fe3+)8O15(OH)]2 | Hex. 6_m_ m : P_63_m c |
4.CB. | Zhenruite | (MoO3)2 · H2O | Mon. 2/m : _P_21/m |
4.CB. | Fuyuanite | Mg7Nb6O18(OH)8 | Trig. 3 : _P_3 |
4.CB. | Virgilluethite | MoO3 · H2O | Mon. 2/m : _P_21/b |
4.CB. | Pengite | (Pb8Sb3+3)Σ11Sb5+9O35 | Trig. 3_m_ _(_32/m ) : R_3_m |
4.CB.05 | Brizziite | NaSb5+O3 | Trig. 3 : _R_3 |
4.CB.05 | Tistarite | Ti3+2O3 | Trig. 3_m_ _(_32/m ) : R_3_c |
4.CB.05 | Hematite | Fe2O3 | Trig. 3_m_ _(_32/m ) : R_3_c |
4.CB.05 | Ecandrewsite | ZnTiO3 | Trig. 3 : _R_3 |
4.CB.05 | Melanostibite | Mn2+2Fe3+Sb5+O6 | Trig. 3 : _R_3 |
4.CB.05 | UM1998-11-O-AuHSb | Au+2Sb3+O2(OH) | |
4.CB.05 | Karelianite | V3+2O3 | Trig. 3_m_ _(_32/m ) : R_3_c |
4.CB.05 | Corundum | Al2O3 | Trig. 3_m_ _(_32/m ) : R_3_c |
4.CB.05 | Eskolaite | Cr2O3 | Trig. 3_m_ _(_32/m ) : R_3_c |
4.CB.05 | Geikielite | MgTiO3 | Trig. 3 : _R_3 |
4.CB.05 | Akimotoite | MgSiO3 | Trig. 3 : _R_3 |
4.CB.05 | Unnamed (Fe-Cr Oxide) | FeCrO3 | Trig. 3 : _R_3 |
4.CB.05 | Auroantimonate | AuSbO3 | |
4.CB.05 | Hemleyite | (Fe2+0.48Mg0.37Ca0.04Na0.04Mn2+0.03Al0.03Cr3+0.01)sum=1.00Si1.00O3 | Trig. 3 : _R_3 |
4.CB.05 | Ilmenite | Fe2+TiO3 | Trig. 3 : _R_3 |
4.CB.05 | Pyrophanite | Mn2+TiO3 | Trig. 3 : _R_3 |
4.CB.10 | Bixbyite-(Fe) | (Fe,Mn)2O3 | Iso. |
4.CB.10 | Bixbyite-(Mn) | Mn3+2O3 | Iso. m_3(2/m_3) : I _a_3 |
4.CB.10 | Avicennite | Tl2O3 | Iso. m_3(2/m_3) : I _a_3 |
4.CB.15 | Armalcolite | (Mg,Fe2+)Ti2O5 | Orth. m m m _(_2/_m_2/_m_2/m ) |
4.CB.15 | Ferropseudobrookite | Fe2+Ti2O5 | Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m |
4.CB.15 | Griffinite | Al2TiO5 | Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m |
4.CB.15 | Pseudobrookite Group | ||
4.CB.15 | Sassite | Ti3+2Ti4+O5 | Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m |
4.CB.20 | Zincovelesite-6N6S | Zn3(Fe3+,Mn3+,Al,Ti)8O15(OH) | Trig. 3_m_ _(_32/m ) : _P_3_m_1 |
4.CB.20 | Magnesiohögbomite-2N4S | (Mg8.43Fe2+1.57)sum=10Al22Ti4+2O46(OH)2 | Hex. 6_m_ m : P_63_m c |
4.CB.20 | Magnesiobeltrandoite-2N3S | (Mg6Al2)(Al18Fe3+2)O38(OH)2 | Trig. 3_m_ : _P_3_m_1 |
4.CB.20 | Zincohögbomite-2N6S | [(Zn,Mg)7(Al,Fe3+,Ti)16O31(OH)]2 | Hex. 6_m_ m : P_63_m c |
4.CB.20 | Magnesiohögbomite-6N6S | [(Mg,Fe2+)3(Al,Ti,Fe3+)8O15(OH)]6 | Trig. 3_m_ _(_32/m ) : R_3_m |
4.CB.20 | Magnesiohögbomite-2N3S | [(Mg,Fe2+,Zn)4(Al,Ti,Fe3+)10O19(OH)]2 | Trig. 3_m_ _(_32/m ) : P_31_m |
4.CB.20 | Magnesiohögbomite-2N2S | [(Mg,Fe2+)3[Al7(Ti,Fe3+)]O15(OH)]2 | Hex. 6_m_ m : P_63_m c |
4.CB.20 | Ferrohögbomite-6N12S | [(Fe2+,Mg,Zn)5(Al,Ti,Fe3+)12O23(OH)]6 | Trig. 3_m_ _(_32/m ) : R_3_m |
4.CB.20 | Zincohögbomite-2N2S | [(Zn,Al,Fe2+)3(Al,Fe3+,Ti)8O15(OH)]2 | Hex. 6_m_ m : P_63_m c |
4.CB.25 | Kleberite | FeTi6O11(OH)5 | Mon. 2/m : _P_21/b |
4.CB.25 | Pseudorutile | Fe2Ti3O9 | Hex. 622 : _P_6322 |
4.CB.30 | Oxyvanite | V3+2V4+O5 | Mon. 2/m : _B_2/b |
4.CB.30 | Berdesinskiite | V3+2TiO5 | Mon. |
4.CB.30 | Kaitianite | Ti3+2Ti4+O5 | Mon. 2/m : _B_2/b |
4.CB.35 | Machiite | Al2Ti3O9 | Mon. 2/m : _B_2/b |
4.CB.35 | Vestaite | (Ti4+Fe2+)Ti4+3O9 | Mon. 2/m : _B_2/b |
4.CB.35 | Olkhonskite | (Cr,V)2Ti3O9 | Mon. |
4.CB.35 | Schreyerite | V3+2Ti4+3O9 | Mon. 2/m : _B_2/b |
4.CB.40 | Zincorinmanite-(Zn) | Zn2Sb2(Fe3+4Zn2)O14(OH)2 | Hex. 6_m_ m : P_63_m c |
4.CB.40 | Majindeite | Mg2Mo3O8 | Hex. 6_m_ m : P_63_m c |
4.CB.40 | Kamiokite | Fe2Mo3O8 | Hex. 6_m_ m : P_63_m c |
4.CB.40 | Nolanite | V3+8Fe3+2O14(OH)2 | Hex. 6_m_ m : P_63_m c |
4.CB.40 | Iseite | Mn2Mo3O8 | Hex. 6_m_ m : P_63_m c |
4.CB.40 | Rinmanite | Zn2Sb2Mg2Fe4O14(OH)2 | Hex. 6 : _P_63 |
4.CB.45 | Stibioclaudetite | AsSbO3 | Mon. 2/m : _P_21/m |
4.CB.45 | Claudetite | As2O3 | Mon. 2/m |
4.CB.50 | Senarmontite | Sb2O3 | Iso. m_3_m _(_4/_m_32/m ) : F d_3_m |
4.CB.50 | Arsenolite | As2O3 | Iso. m_3_m _(_4/_m_32/m ) : F d_3_m |
4.CB.55 | Valentinite | Sb2O3 | Orth. m m m _(_2/_m_2/_m_2/m ) : P c c n |
4.CB.60 | Bismite | Bi2O3 | Mon. 2/m : _P_21/b |
4.CB.65 | Sphaerobismoite | Bi2O3 | Tet. |
4.CB.70 | Sillénite | Bi12SiO20 | Iso. 23 : _I_23 |
4.CB.75 | Kyzylkumite | V3+Ti2O5(OH) | Mon. 2/m : _P_21/b |
4.CB.80 | Tietaiyangite | Fe3+4Fe2+TiO9 | Hex. |
4.CB.85 | Liuite | FeTiO3 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
4.CB.90 | Luogufengite | Fe2O3 | Orth. m _m_2 : P n _a_21 |
4.CB.95 | Wangdaodeite | FeTiO3 | Trig. 3_m_ : R_3_c |
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for PseudobrookiteHide
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References for PseudobrookiteHide
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Reference List:
Åsbrink, Gudrun, Magnéli, Arne, Porok, J., Levstek, I., Eržen, V., Blinc, R., Paušak, S., Ehrenberg, L., Dumanović, J. (1967) X-Ray Studies on Some Mixed Oxide Systems of the Pseudobrookite Structure. Acta Chemica Scandinavica, 21. 1977 doi:10.3891/acta.chem.scand.21-1977
Teller, Raymond G., Antonio, Mark R., Grau, Alphonso E., Gueguin, Michel, Kostiner, Edward (1990) Structural analysis of metastable pseudobrookite ferrous titanium oxides with neutron diffraction and Mossbauer spectroscopy. Journal of Solid State Chemistry, 88. 334-350 doi:10.1016/0022-4596(90)90229-q
Teller, Raymond G., Antonio, Mark R., Grau, Alphonso E., Gueguin, Michel, Kostiner, Edward (1990) The chemistry of the thermal decomposition of pseudobrookite ferrous titanium oxides. Journal of Solid State Chemistry, 88. 351-367 doi:10.1016/0022-4596(90)90230-u
Localities for PseudobrookiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The
symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed.
- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.