Vestaite (original) (raw)

A valid IMA mineral species

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Formula:

(Ti4+Fe2+)Ti4+3O9

Crystal System:

Monoclinic

Name:

Named after asteroid 4 Vesta. Vestaite was found in a meteorite of the howardite-eucrite-diogenite (HED) clan, all thought to have originated from the crust of the asteroid Vesta.

The Ti4+-Fe2+ analogue of schreyerite. A shock-generated mineral first found in a meteorite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:52576:3

6400e948-3d3f-4a6d-b575-a0c75b69276c

IMA Classification of VestaiteHide

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Type description reference:

Pang, R.-L., Harries, D., Pollok, K., Zhang, Ai-C., Langenhorst, F. (2018) Vestaite, (Ti4+Fe2+)Ti34+O9, a new mineral in the shocked eucrite Northwest Africa 8003. American Mineralogist: 103: 1502–1511.

Classification of VestaiteHide

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4.CB.35

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Vst IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Chemistry of VestaiteHide

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Mindat Formula:

(Ti4+Fe2+)Ti4+3O9

Crystallography of VestaiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 17.03(2) Å, b = 4.98(1) Å, c = 7.08(1) Å
β = 106.3(2)°

Ratio:

a:b:c = 3.42 : 1 : 1.422

Unit Cell V:

576.32 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.084 Å (44)
3.398 Å (60)
2.880 Å (77)
2.732 Å (100)
2.425 Å (42)
1.705 Å (38)
1.694 Å (50)
1.643 Å (48)

Comments:

From Type Description.

Geological EnvironmentHide

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Type Occurrence of VestaiteHide

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General Appearance of Type Material:

Euhedral to subhedral crystals, ~0.2–0.5 µm in width and up to ~2.5 µm in length with normally columnar to platy habit.

Place of Conservation of Type Material:

Type material is deposited in the mineralogical collections of the Friedrich Schiller University Jena, Sellierstrasse 6, 07745 Jena, Germany, catalogue numbers 42073 and 42074.

Empirical Formula of Type Material:

(Ti4+0.73Fe2+0.63Al0.60Mn0.03Mg0.02Cr0.01)Ti4+3O9

Geological Setting of Type Material:

In shock melt pockets of eucrite meteorite

Associated Minerals at Type Locality:

Reference:

Pang, R.-L., Harries, D., Pollok, K., Zhang, Ai-C., Langenhorst, F. (2018) Vestaite, (Ti4+Fe2+)Ti34+O9, a new mineral in the shocked eucrite Northwest Africa 8003. American Mineralogist: 103: 1502–1511.

Synonyms of VestaiteHide

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4.CB. Ferrohögbomite-2N2S [(Fe2+,Mg,Zn,Al)3(Al,Ti,Fe3+)8O15(OH)]2 Hex. 6_m_ m : P_63_m c
4.CB. Magnesiohögbomite-6N12S Mg5Al11TiO23(OH) Trig. 3_m_ _(_32/m ) : R_3_m
4.CB. Zhenruite (MoO3)2 · H2O Mon. 2/m : _P_21/m
4.CB. Pengite (Pb8Sb3+3)Σ11Sb5+9O35 Trig. 3_m_ _(_32/m ) : R_3_m
4.CB. Virgilluethite MoO3 · H2O Mon. 2/m : _P_21/b
4.CB.05 Brizziite NaSb5+O3 Trig. 3 : _R_3
4.CB.05 Corundum Al2O3 Trig. 3_m_ _(_32/m ) : R_3_c
4.CB.05 Ecandrewsite (Zn,Fe2+,Mn2+)TiO3 Trig. 3 : _R_3
4.CB.05 Eskolaite Cr2O3 Trig. 3_m_ _(_32/m ) : R_3_c
4.CB.05 Geikielite MgTiO3 Trig. 3 : _R_3
4.CB.05 Hematite Fe2O3 Trig. 3_m_ _(_32/m ) : R_3_c
4.CB.05 Ilmenite Fe2+TiO3 Trig. 3 : _R_3
4.CB.05 Karelianite V3+2O3 Trig. 3_m_ _(_32/m ) : R_3_c
4.CB.05 Melanostibite Mn2+2Fe3+Sb5+O6 Trig. 3 : _R_3
4.CB.05 Pyrophanite Mn2+TiO3 Trig. 3 : _R_3
4.CB.05 Akimotoite (Mg,Fe2+)SiO3 Trig. 3 : _R_3
4.CB.05 Auroantimonate AuSbO3
4.CB.05 UM1998-11-O-AuHSb Au+2Sb3+O2(OH)
4.CB.05 Tistarite Ti3+2O3 Trig. 3_m_ _(_32/m ) : R_3_c
4.CB.05 Unnamed (Fe-Cr Oxide) FeCrO3 Trig. 3 : _R_3
4.CB.05 Hemleyite (Fe2+0.48Mg0.37Ca0.04Na0.04Mn2+0.03Al0.03Cr3+0.01)sum=1.00Si1.00O3 Trig. 3 : _R_3
4.CB.10 Avicennite Tl2O3 Iso. m_3(2/m_3) : I _a_3
4.CB.10 Bixbyite-(Mn) Mn3+2O3 Iso. m_3(2/m_3) : I _a_3
4.CB.10 Bixbyite-(Fe) (Fe,Mn)2O3 Iso.
4.CB.15 Armalcolite (Mg,Fe2+)Ti2O5 Orth. m m m _(_2/_m_2/_m_2/m )
4.CB.15 Sassite Ti3+2Ti4+O5 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m
4.CB.15 Pseudobrookite Fe2TiO5 Orth. m m m _(_2/_m_2/_m_2/m )
4.CB.15 Ferropseudobrookite Fe2+Ti2O5 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m
4.CB.15 Griffinite Al2TiO5 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m
4.CB.15 Pseudobrookite Group
4.CB.20 Zincohögbomite-2N2S [(Zn,Al,Fe2+)3(Al,Fe3+,Ti)8O15(OH)]2 Hex. 6_m_ m : P_63_m c
4.CB.20 Zincohögbomite-2N6S [(Zn,Mg)7(Al,Fe3+,Ti)16O31(OH)]2 Hex. 6_m_ m : P_63_m c
4.CB.20 Magnesiohögbomite-6N6S [(Mg,Fe2+)3(Al,Ti,Fe3+)8O15(OH)]6 Trig. 3_m_ _(_32/m ) : R_3_m
4.CB.20 Magnesiohögbomite-2N3S [(Mg,Fe2+,Zn)4(Al,Ti,Fe3+)10O19(OH)]2 Trig. 3_m_ _(_32/m ) : P_31_m
4.CB.20 Magnesiohögbomite-2N2S [(Mg,Fe2+)3[Al7(Ti,Fe3+)]O15(OH)]2 Hex. 6_m_ m : P_63_m c
4.CB.20 Ferrohögbomite-6N12S [(Fe2+,Mg,Zn)5(Al,Ti,Fe3+)12O23(OH)]6 Trig. 3_m_ _(_32/m ) : R_3_m
4.CB.20 Magnesiohögbomite-2N4S (Mg8.43Fe2+1.57)sum=10Al22Ti4+2O46(OH)2 Hex. 6_m_ m : P_63_m c
4.CB.20 Magnesiobeltrandoite-2N3S (Mg6Al2)(Al18Fe3+2)O38(OH)2 Trig. 3_m_ : _P_3_m_1
4.CB.20 Zincovelesite-6N6S Zn3(Fe3+,Mn3+,Al,Ti)8O15(OH) Trig. 3_m_ _(_32/m ) : _P_3_m_1
4.CB.25 Pseudorutile Fe2Ti3O9 Hex. 622 : _P_6322
4.CB.25 Kleberite FeTi6O11(OH)5 Mon. 2/m : _P_21/b
4.CB.30 Berdesinskiite V3+2TiO5 Mon.
4.CB.30 Oxyvanite V3+2V4+O5 Mon. 2/m : _B_2/b
4.CB.30 Kaitianite Ti3+2Ti4+O5 Mon. 2/m : _B_2/b
4.CB.35 Olkhonskite (Cr,V)2Ti3O9 Mon.
4.CB.35 Schreyerite V3+2Ti3O9 Mon. 2/m : _B_2/b
4.CB.35 Machiite Al2Ti3O9 Mon. 2/m : _B_2/b
4.CB.40 Kamiokite Fe2Mo3O8 Hex. 6_m_ m : P_63_m c
4.CB.40 Nolanite V3+8Fe3+2O14(OH)2 Hex. 6_m_ m : P_63_m c
4.CB.40 Rinmanite Zn2Sb2Mg2Fe4O14(OH)2 Hex. 6 : _P_63
4.CB.40 Iseite Mn2Mo3O8 Hex. 6_m_ m : P_63_m c
4.CB.40 Majindeite Mg2Mo3O8 Hex. 6_m_ m : P_63_m c
4.CB.45 Claudetite As2O3 Mon. 2/m
4.CB.45 Stibioclaudetite AsSbO3 Mon. 2/m : _P_21/m
4.CB.50 Arsenolite As2O3 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.CB.50 Senarmontite Sb2O3 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.CB.55 Valentinite Sb2O3 Orth. m m m _(_2/_m_2/_m_2/m ) : P c c n
4.CB.60 Bismite Bi2O3 Mon. 2/m : _P_21/b
4.CB.65 Sphaerobismoite Bi2O3 Tet.
4.CB.70 Sillénite Bi12SiO20 Iso. 23 : _I_23
4.CB.75 Kyzylkumite V3+Ti2O5(OH) Mon. 2/m : _P_21/b
4.CB.80 Tietaiyangite Fe3+4Fe2+TiO9 Hex.
4.CB.85 Liuite FeTiO3 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
4.CB.90 Luogufengite Fe2O3 Orth. m _m_2 : P n _a_21
4.CB.95 Wangdaodeite FeTiO3 Trig. 3_m_ : R_3_c

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for VestaiteHide

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Reference List:

Pang, R.-L., Harries, D., Pollok, K., Zhang, Ai-C., Langenhorst, F. (2018) Vestaite, (Ti4+Fe2+)Ti34+O9, a new mineral in the shocked eucrite Northwest Africa 8003. American Mineralogist: 103: 1502–1511.

Localities for VestaiteHide

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ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.