Dynamic Mechanical Analysis Research Papers (original) (raw)
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The viscoelastic response of commercial Al–Zn–Mg and Al–Cu–Mg alloys was measured with a dynamic-mechanical analyzer (DMA) as a function of the temperature (from 30 to 425°C) and the loading frequency (from 0.01 to 150 Hz). The... more
The viscoelastic response of commercial Al–Zn–Mg and Al–Cu–Mg alloys was measured with a dynamic-mechanical analyzer (DMA) as a function of the temperature (from 30 to 425°C) and the loading frequency (from 0.01 to 150 Hz). The time-temperature superposition (TTS) principle has proven to be useful in studying mechanical relaxations and obtaining master curves for amorphous materials. In this work, the TTS principle is applied to the measured viscoelastic data (i.e., the storage and loss moduli) to obtain the corresponding master curves and to analyze the mechanical relaxations responsible for the viscoelastic behavior of the studied alloys. For the storage modulus it was possible to identify a master curve for a low-temperature region (from room temperature to 150°C) and, for the storage and loss moduli, another master curve for a high-temperature region (from 320 to 375°C). These temperature regions are coincidental with the stable intervals where no phase transformations occur. Th...
The effect of the thickness on the mechanical properties of injection-molded specimens of pure polyamide-6 (PA6) and polyamide-6 clay nanocomposites (PA6-NC) with 5wt% of layered silicates was investigated. Plates of 0.5, 0.75, 1 and 2mm... more
The effect of the thickness on the mechanical properties of injection-molded specimens of pure polyamide-6 (PA6) and polyamide-6 clay nanocomposites (PA6-NC) with 5wt% of layered silicates was investigated. Plates of 0.5, 0.75, 1 and 2mm thickness were characterized in the injection direction using Dynamic Mechanical Analysis under torsion and tension respectively, and tensile tests. The fracture surfaces were analyzed by
- by Nara Altmann and +1
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- Engineering, Polymer science, TIME, Polymer
The thermal lag associated with the temperature ramping experiment in a dynamic mechanical analysis is demonstrated on carbon black filled vulcanised rubber samples by using a DMTA MkIII from Rheometric Scientific. The importance of... more
The thermal lag associated with the temperature ramping experiment in a dynamic mechanical analysis is demonstrated on carbon black filled vulcanised rubber samples by using a DMTA MkIII from Rheometric Scientific. The importance of achieving thermal equilibrium on the sample before starting the measurement is emphasised. By running a combination of isothermal and ramping steps, the impact of thermal lag
- by Giancarlo Galli and +1
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- Engineering, X Rays, Polymer, Transport Properties
In this study the use of dynamic mechanical analysis (DMA) for the mechanical characterisation of pharmaceutical hydrogels was evaluated. DMA was used in two different modes, the "controlled force" and the... more
In this study the use of dynamic mechanical analysis (DMA) for the mechanical characterisation of pharmaceutical hydrogels was evaluated. DMA was used in two different modes, the "controlled force" and the "multi-strain" (MS). The results obtained on dextran methacrylate hydrogels of various compositions were compared to those obtained using an oscillatory shear rheometer. The best agreement was found between the MS-DMA and the rheometer results. The moduli measured in MS-DMA were extrapolated towards zero compression to obtain the modulus of the hydrogels. This procedure resulted in good agreement with the data obtained with the rheometer. Hydrogels were analysed after swelling to equilibrium with both methods, DMA and rheology. A scaling between the elastic modulus (G') and the equilibrium swollen polymer volume fraction (v(2,s)) could be found, although the best correlation between G' and v(2,s) was obtained with the rheometer.
Composite films of Polyamide-6,6 (PA66) and multi-walled carbon nanotubes (MWCNTs) were prepared by a combination of solution casting followed by compression molding techniques. Both unfunctionalized (u-MWCNTs) and functionalized... more
Composite films of Polyamide-6,6 (PA66) and multi-walled carbon nanotubes (MWCNTs) were prepared by a combination of solution casting followed by compression molding techniques. Both unfunctionalized (u-MWCNTs) and functionalized nanotubes (f-MWCNTs) were used in this study. The functionalization involved direct solvent-free amination of MWCNTs with hexamethylenediamine. Thermogravimetric analysis was used to observe the changes in the nanotubes upon functionalization and morphological features of the resulting composite films were studied using scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. The crystallinity changes by incorporation of the u-MWCNTs and f-MWCNTs in the PA66 matrix were studied by wide angle X-ray scattering and differential scanning calorimetry. The f-MWCNT/PA66 film showed an improvement of ∼43% in maximum tensile stress (MTS) and ∼32% in Young’s modulus over pristine PA66 film, while at a similar loading of 0.5 wt%, the f-MWCNT/PA66 film showed ∼15% increase in MTS and ∼16% increase in modulus over the u-MWCNT/PA66 film. Dynamic mechanical analysis indicated significant difference in the small-strain mechanical properties between the MWCNT-filled and unfilled PA66 at the very low MWNT loadings that were tested and supported the tensile results. The water absorption trend of the composite films showed dramatic improvement over the neat film.