Siwaqaite (original) (raw)

A valid IMA mineral species

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About SiwaqaiteHide

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Formula:

Ca6Al2(CrO4)3(OH)12 · 26H2O

Specific Gravity:

1.819 (Calculated)

Name:

Named for the Siwaqa area, Jordan, the type locality.

The Cr (chromate) analogue of ettringite. First chromate-dominant group member. First chromate mineral to combine Ca and Al.

The temperature of formation is not higher than ~70–80 °C, based on mineral association and inferred from the formation conditions of the natural and synthetic members of the ettringite group minerals, which are stable at conditions of T < 120 °C and pH = 9.5–13.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:53414:1

594aa3cb-2cee-4e8c-a7f6-a00aa900b0bf

IMA Classification of SiwaqaiteHide

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Type description reference:

Juroszek, Rafał, Krüger, Biljana, Galuskina, Irina, Krüger, Hannes, Vapnik, Yevgeny, Galuskin, Evgeny (2020) Siwaqaite, Ca6Al2(CrO4)3(OH)12·26H2O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan. American Mineralogist, 105 (3) 409-421 doi:10.2138/am-2020-7208

Classification of SiwaqaiteHide

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7.DG.15

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Siw IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of SiwaqaiteHide

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Comment:

Based on scratch tests; micro-hardness test could not be performed

Fracture:

Irregular/Uneven

Density:

1.819 g/cm3 (Calculated)

Comment:

Could not be measured

Optical Data of SiwaqaiteHide

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RI values:

_n_ω = 1.512(2) _n_ε = 1.502(2)

δ = 0.010

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Pleochroism:

Non-pleochroic

Chemistry of SiwaqaiteHide

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Mindat Formula:

Ca6Al2(CrO4)3(OH)12 · 26H2O

Crystallography of SiwaqaiteHide

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Class (H-M):

3_m_ - Ditrigonal Pyramidal

Cell Parameters:

a = 11.3640(2) Å, c = 21.4485(2) Å

Unit Cell V:

2,398.78 ų (Calculated from Unit Cell)

Morphology:

Hexagonal prisms, terminated by a pyramid or a pinacoid.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
9.841 Å (100)
5.682 Å (65)
5.021 Å (16)
4.709 Å (38)
3.900 Å (29)
3.280 Å (17)
3.279 Å (33)
2.224 Å (16)

Geological EnvironmentHide

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Type Occurrence of SiwaqaiteHide

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General Appearance of Type Material:

Grain aggregates and hexagonal prismatic crystals up to 250 mm in size

Place of Conservation of Type Material:

Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5277/1

Geological Setting of Type Material:

Thin veins and small cavities in spurrite marble

Associated Minerals at Type Locality:

Reference:

Juroszek, R., Krüger, B., Galuskina, I., Krüger, H., Vapnik, Y., Galuskin, E. (2020) Siwaqaite, Ca6Al2(CrO4)3(OH)12·26H2O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan. American Mineralogist: 105(3): 409–421.

Synonyms of SiwaqaiteHide

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Relationship of Siwaqaite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.DG. Mathesiusite K5(UO2)4(SO4)4(VO5) · 4H2O Tet. 4/m : _P_4/n
7.DG.05 Darapskite Na3(SO4)(NO3) · H2O Mon. 2/m : _P_21/m
7.DG.10 Clinoungemachite (Na, K, Fe, SO4) Mon. 2/m
7.DG.10 Humberstonite Na7K3Mg2(SO4)6(NO3)2 · 6H2O Trig. 3 : _R_3
7.DG.10 Ungemachite K3Na8Fe(SO4)6(NO3)2 · 6H2O Trig. 3 : _R_3
7.DG.15 Bentorite Ca6Cr2(SO4)3(OH)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Charlesite Ca6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Ettringite Ca6Al2(SO4)3(OH)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Jouravskite Ca3Mn4+(SO4)(CO3)(OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Sturmanite Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12 · 25H2O Trig. 3_m_ : P_31_c
7.DG.15 Thaumasite Ca3(SO4)[Si(OH)6](CO3) · 12H2O Hex. 6 : _P_63
7.DG.15 Carraraite Ca3(SO4)[Ge(OH)6](CO3) · 12H2O Hex.
7.DG.15 Buryatite Ca3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2O Trig. 3_m_ : P_31_c
7.DG.15 Birunite Ca18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?)
7.DG.15 Hielscherite Ca3Si(SO4)(SO3)(OH)6 · 11H2O Hex. 6 : _P_63
7.DG.15 Kottenheimite Ca 3Si(SO4)2(OH)6 · 12H2O Hex. 6/m : _P_63/m
7.DG.15 Imayoshiite Ca3Al(CO3)[B(OH)4](OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Tatarinovite Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Chiyokoite Ca3Si(CO3)[B(OH)4]O (OH)5 · 12H2O Hex. 6 : _P_63
7.DG.20 Rapidcreekite Ca2(SO4)(CO3) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
7.DG.25 Tatarskite Ca6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2O Orth.
7.DG.30 Nakauriite Cu8(SO4)4(CO3)(OH)6 · 48H2O Orth.
7.DG.35 Chessexite (Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2O Orth.
7.DG.40 Carlosruizite K6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DG.40 Fuenzalidaite K6(Na,K)4Na6Mg10(SO4)12(IO3)12 · 12H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DG.45 Chelyabinskite (Ca,Mg)3(SO4,CO3)2[Si(OH)6] · 9H2O (?) Orth.
7.DG.55 Ramazzoite [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36] Iso. 43_m_ : P_43_m
7.DG.60 Witzkeite Na4K4Ca(NO3)2(SO4)4 · 2H2O Mon. 2/m : _B_2/b

Other InformationHide

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IR Spectrum:

Absorption bands at 3318 and 3620 cm-1 (O-H stretching), 1629 and 1650 cm-1 (bending vibration of water), 1108 and 540 cm-1 (asymmetric stretching and bending of (SO4)2-), 540 cm-1 (Al-OH bending vibrations), and 869 cm-1 (asymmetric stretching vibrations of (CrO4)2-).

Notes:

Dissolved in 10% HCl and loses color in ethanol at room temperature.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for SiwaqaiteHide

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Reference List:

Juroszek, Rafał, Krüger, Biljana, Galuskina, Irina, Krüger, Hannes, Vapnik, Yevgeny, Galuskin, Evgeny (2020) Siwaqaite, Ca6Al2(CrO4)3(OH)12·26H2O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan. American Mineralogist, 105 (3) 409-421 doi:10.2138/am-2020-7208

Localities for SiwaqaiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Jordan (TL)
Amman Governorate Transjordan Plateau Daba-Siwaqa complex North Siwaqa complex (TL) Mineralogical Magazine: 83: 315-317. +2 other references