Siwaqaite (original) (raw)
A valid IMA mineral species
About SiwaqaiteHide
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Formula:
Ca6Al2(CrO4)3(OH)12 · 26H2O
Specific Gravity:
1.819 (Calculated)
Name:
Named for the Siwaqa area, Jordan, the type locality.
The Cr (chromate) analogue of ettringite. First chromate-dominant group member. First chromate mineral to combine Ca and Al.
The temperature of formation is not higher than ~70–80 °C, based on mineral association and inferred from the formation conditions of the natural and synthetic members of the ettringite group minerals, which are stable at conditions of T < 120 °C and pH = 9.5–13.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:53414:1
594aa3cb-2cee-4e8c-a7f6-a00aa900b0bf
IMA Classification of SiwaqaiteHide
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Type description reference:
Juroszek, Rafał, Krüger, Biljana, Galuskina, Irina, Krüger, Hannes, Vapnik, Yevgeny, Galuskin, Evgeny (2020) Siwaqaite, Ca6Al2(CrO4)3(OH)12·26H2O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan. American Mineralogist, 105 (3) 409-421 doi:10.2138/am-2020-7208
Classification of SiwaqaiteHide
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7.DG.15
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Siw | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of SiwaqaiteHide
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Comment:
Based on scratch tests; micro-hardness test could not be performed
Fracture:
Irregular/Uneven
Density:
1.819 g/cm3 (Calculated)
Comment:
Could not be measured
Optical Data of SiwaqaiteHide
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RI values:
_n_ω = 1.512(2) _n_ε = 1.502(2)
δ = 0.010
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Pleochroism:
Non-pleochroic
Chemistry of SiwaqaiteHide
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Mindat Formula:
Ca6Al2(CrO4)3(OH)12 · 26H2O
Crystallography of SiwaqaiteHide
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Class (H-M):
3_m_ - Ditrigonal Pyramidal
Cell Parameters:
a = 11.3640(2) Å, c = 21.4485(2) Å
Unit Cell V:
2,398.78 ų (Calculated from Unit Cell)
Morphology:
Hexagonal prisms, terminated by a pyramid or a pinacoid.
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
9.841 Å | (100) |
5.682 Å | (65) |
5.021 Å | (16) |
4.709 Å | (38) |
3.900 Å | (29) |
3.280 Å | (17) |
3.279 Å | (33) |
2.224 Å | (16) |
Geological EnvironmentHide
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Type Occurrence of SiwaqaiteHide
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General Appearance of Type Material:
Grain aggregates and hexagonal prismatic crystals up to 250 mm in size
Place of Conservation of Type Material:
Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5277/1
Geological Setting of Type Material:
Thin veins and small cavities in spurrite marble
Associated Minerals at Type Locality:
Reference:
Juroszek, R., Krüger, B., Galuskina, I., Krüger, H., Vapnik, Y., Galuskin, E. (2020) Siwaqaite, Ca6Al2(CrO4)3(OH)12·26H2O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan. American Mineralogist: 105(3): 409–421.
Synonyms of SiwaqaiteHide
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Relationship of Siwaqaite to other SpeciesHide
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Other Members of this group:
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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7.DG. | Mathesiusite | K5(UO2)4(SO4)4(VO5) · 4H2O | Tet. 4/m : _P_4/n |
---|---|---|---|
7.DG.05 | Darapskite | Na3(SO4)(NO3) · H2O | Mon. 2/m : _P_21/m |
7.DG.10 | Clinoungemachite | (Na, K, Fe, SO4) | Mon. 2/m |
7.DG.10 | Humberstonite | Na7K3Mg2(SO4)6(NO3)2 · 6H2O | Trig. 3 : _R_3 |
7.DG.10 | Ungemachite | K3Na8Fe(SO4)6(NO3)2 · 6H2O | Trig. 3 : _R_3 |
7.DG.15 | Bentorite | Ca6Cr2(SO4)3(OH)12 · 26H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Charlesite | Ca6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Ettringite | Ca6Al2(SO4)3(OH)12 · 26H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Jouravskite | Ca3Mn4+(SO4)(CO3)(OH)6 · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Sturmanite | Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12 · 25H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Thaumasite | Ca3(SO4)[Si(OH)6](CO3) · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Carraraite | Ca3(SO4)[Ge(OH)6](CO3) · 12H2O | Hex. |
7.DG.15 | Buryatite | Ca3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Birunite | Ca18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?) | |
7.DG.15 | Hielscherite | Ca3Si(SO4)(SO3)(OH)6 · 11H2O | Hex. 6 : _P_63 |
7.DG.15 | Kottenheimite | Ca 3Si(SO4)2(OH)6 · 12H2O | Hex. 6/m : _P_63/m |
7.DG.15 | Imayoshiite | Ca3Al(CO3)[B(OH)4](OH)6 · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Tatarinovite | Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Chiyokoite | Ca3Si(CO3)[B(OH)4]O (OH)5 · 12H2O | Hex. 6 : _P_63 |
7.DG.20 | Rapidcreekite | Ca2(SO4)(CO3) · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n |
7.DG.25 | Tatarskite | Ca6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2O | Orth. |
7.DG.30 | Nakauriite | Cu8(SO4)4(CO3)(OH)6 · 48H2O | Orth. |
7.DG.35 | Chessexite | (Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2O | Orth. |
7.DG.40 | Carlosruizite | K6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2O | Trig. 3_m_ _(_32/m ) : _P_3_c_1 |
7.DG.40 | Fuenzalidaite | K6(Na,K)4Na6Mg10(SO4)12(IO3)12 · 12H2O | Trig. 3_m_ _(_32/m ) : _P_3_c_1 |
7.DG.45 | Chelyabinskite | (Ca,Mg)3(SO4,CO3)2[Si(OH)6] · 9H2O (?) | Orth. |
7.DG.55 | Ramazzoite | [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36] | Iso. 43_m_ : P_43_m |
7.DG.60 | Witzkeite | Na4K4Ca(NO3)2(SO4)4 · 2H2O | Mon. 2/m : _B_2/b |
Other InformationHide
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IR Spectrum:
Absorption bands at 3318 and 3620 cm-1 (O-H stretching), 1629 and 1650 cm-1 (bending vibration of water), 1108 and 540 cm-1 (asymmetric stretching and bending of (SO4)2-), 540 cm-1 (Al-OH bending vibrations), and 869 cm-1 (asymmetric stretching vibrations of (CrO4)2-).
Notes:
Dissolved in 10% HCl and loses color in ethanol at room temperature.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for SiwaqaiteHide
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References for SiwaqaiteHide
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Reference List:
Juroszek, Rafał, Krüger, Biljana, Galuskina, Irina, Krüger, Hannes, Vapnik, Yevgeny, Galuskin, Evgeny (2020) Siwaqaite, Ca6Al2(CrO4)3(OH)12·26H2O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan. American Mineralogist, 105 (3) 409-421 doi:10.2138/am-2020-7208
Localities for SiwaqaiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Jordan (TL) | |
---|---|
Amman Governorate Transjordan Plateau Daba-Siwaqa complex ⓘ North Siwaqa complex (TL) | Mineralogical Magazine: 83: 315-317. +2 other references |