Ammonioalunite (original) (raw)

A valid IMA mineral species

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About AmmonioaluniteHide

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Formula:

(NH4)Al3(SO4)2(OH)6

Name:

The name is derived from "alunite" since it is a member of the Alunite Sub-group. The "Ammonio" prefix designates that it is the (NH4)-dominant member of the sub-group.

This page provides mineralogical data about Ammonioalunite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:203:1

90e94022-ae90-450f-8166-d8ea1dd59c98

IMA Classification of AmmonioaluniteHide

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Type description reference:

Altaner, S.P., Fitzpatrick, J.J., Krohn, M.D., Bethke, P.M., Hayba, D.O., Goss, J.A., Brown, Z.A. (1988) Ammonium in alunites. American Mineralogist: 73: 145-152.

Classification of AmmonioaluniteHide

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7.BC.10

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

30.2.4.6

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
2 : (AB)2(XO4)Zq

25.1.10

25 : Sulphates
1 : Sulphates of the alkali metals and ammonium

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Aalu IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AmmonioaluniteHide

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Transparency:

Transparent, Translucent

Comment:

colorless in thin section.

Cleavage:

Perfect
perfect on {0001}(by analogy with the alunite group).

Density:

2.4 g/cm3 (Measured) 2.58 g/cm3 (Calculated)

Optical Data of AmmonioaluniteHide

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RI values:

_n_ω = 1.590(5) _n_ε = 1.602(5)

δ = 0.012

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of AmmonioaluniteHide

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Mindat Formula:

(NH4)Al3(SO4)2(OH)6

Crystallography of AmmonioaluniteHide

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Cell Parameters:

a = 7.01 Å, c = 17.88 Å

Unit Cell V:

760.91 ų (Calculated from Unit Cell)

Morphology:

As rhombohedral crystals, to 20 μm, forming granular masses.

Comment:

Point Group: 3 2/m or 3m; Space Group: R3m or R3m. a

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.023 Å (100)
5.04 Å (93)
2.996 Å (50)
1.917 Å (32)
2.353 Å (31)
1.753 Å (21)
3.514 Å (19)

Geological EnvironmentHide

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Type Occurrence of AmmonioaluniteHide

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General Appearance of Type Material:

As rhombohedral crystals, to 20 µm, forming granular masses.

Place of Conservation of Type Material:

National Museum of Natural History, Washington, D.C., USA, 145596.

Geological Setting of Type Material:

Formed in hot springs under very acid conditions, rich in ammonium and sulfate, poor in potassium, below 100 C.

Associated Minerals at Type Locality:

Reference:

Altaner, S.P., Fitzpatrick, J.J., Krohn, M.D., Bethke, P.M., Hayba, D.O., Goss, J.A., Brown, Z.A. (1988) Ammonium in alunites. American Mineralogist: 73: 145-152.

Synonyms of AmmonioaluniteHide

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Other Language Names for AmmonioaluniteHide

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Relationship of Ammonioalunite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.BC. Adranosite-(Fe) (NH4)4NaFe3+2(SO4)4Cl(OH)2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
7.BC. Adranosite (NH4)4NaAl2(SO4)4Cl(OH)2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
7.BC. D'Ansite-(Mn) Na21Mn2+(SO4)10Cl3 Iso. 43_m_ : I_43_d
7.BC. Agaite Pb3CuTeO5(OH)2(CO3) Orth. m _m_2 : P c _a_21
7.BC. D'Ansite-(Fe) Na21Fe2+(SO4)10Cl3 Iso. 43_m_ : I_43_d
7.BC. Acmonidesite (NH4,K,Pb)8NaFe2+4(SO4)5Cl8 Orth. 222 : _C_2221
7.BC. Backite Pb2AlTeO6Cl Trig. 32 : _P_312
7.BC. Hagstromite Pb8Cu2+(Te6+O6)2(CO3)Cl4 Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
7.BC. Wildcatite CaFe3+Te6+O5(OH) Trig. 3_m_ _(_32/m ) : P_31_m
7.BC. Franksousaite PbCu(Se6+O4)(OH)2 Mon. 2/m : _P_21/m
7.BC. Zincochenite Pb4Zn(OH)6(SO4)2 Tric. 1 : _P_1
7.BC. Viskontite Pb5Cu2(SO4)3(SeO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC. Chromviskontite Pb5Cu2(CrO4)3(SeO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC.05 D'Ansite Na21Mg(SO4)10Cl3 Iso. 43_m_ : I_43_m
7.BC.07 Apatelite Fe3(SO4)2(OH)5 · 0.5H2O
7.BC.07 Unnamed (Ba-Fe Vanadate) Ba, Fe, V, O, H
7.BC.10 Alunite KAl3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Ammoniojarosite (NH4)Fe3+3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Argentojarosite AgFe3+3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Beaverite-(Cu) Pb(Fe3+2Cu)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Dorallcharite TlFe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Huangite Ca0.5Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Hydroniumjarosite (H3O)Fe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Jarosite KFe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Natroalunite-2c (Na,Ca0.5,K)Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Natroalunite NaAl3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Natrojarosite NaFe3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Osarizawaite Pb(Al2Cu2+)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Plumbojarosite Pb0.5Fe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Schlossmacherite (H3O)Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Walthierite Ba0.5Al3(SO4)2(OH)6 Trig.
7.BC.10 Beaverite-(Zn) Pb(Fe3+2Zn)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Karlseifertite Pb(Ga2Ge)(AsO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.15 Ye'elimite Ca4Al6(SO4)O12 Iso. 432 : _I_4132
7.BC.20 Atlasovite K(BiO)Cu6Fe3+(SO4)5O3Cl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.20 Nabokoite KCu7(SO4)5(Te4+O3)OCl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.20 Puninite Na2Cu3O(SO4)3 Mon. 2/m : _B_2/b
7.BC.25 Chlorothionite K2Cu(SO4)Cl2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.30 Euchlorine KNaCu3(SO4)3O Mon. 2/m
7.BC.30 Fedotovite K2Cu3(SO4)3O Mon. 2/m : _B_2/b
7.BC.35 Kamchatkite KCu3(SO4)2OCl Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.40 Piypite K4Cu4O2(SO4)4 · (Na,Cu)Cl Tet. 4 : _I_4
7.BC.45 Klyuchevskite K3Cu3(Fe3+,Al)(SO4)4O2 Mon. 2
7.BC.45 Alumoklyuchevskite K3Cu3(Al,Fe3+)(SO4)4O2 Tric. 1 : _P_1
7.BC.45 Belousovite KZn(SO4)Cl Mon. 2/m : _P_21/b
7.BC.47 Müllerite Pb2Fe3+(Te6+O6)Cl Trig. 32 : _P_3112
7.BC.50 Caledonite Pb5Cu2(SO4)3(CO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC.50 Elasmochloite Na3Cu6BiO4(SO4)5 Mon. 2/m
7.BC.52 Eleomelanite (K2Pb)Cu4O2(SO4)4 Mon. 2/m
7.BC.55 Wherryite Pb7Cu2(SO4)4(SiO4)2(OH)2 Mon. 2/m : _B_2/m
7.BC.55 Falgarite K4(VO)3(SO4)5 Mon. 2/m : _B_2/b
7.BC.57 Krasheninnikovite KNa2CaMg(SO4)3F Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m c m
7.BC.60 Mammothite Pb6Cu4AlSb5+O2(OH)16Cl4(SO4)2 Mon. 2 : _B_2
7.BC.60 Wulffite K3NaCu4O2(SO4)4 Orth. m _m_2
7.BC.60 Parawulffite K5Na3Cu8O4(SO4)8 Mon. 2/m : _P_2/b
7.BC.62 Shuvalovite K2(Ca2Na)(SO4)3F Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.65 Linarite PbCu(SO4)(OH)2 Mon. 2/m : _P_21/m
7.BC.65 Schmiederite Pb2Cu2(Se6+O4)(Se4+O3)(OH)4 Mon. 2/m : _P_21/m
7.BC.65 Munakataite Pb2Cu2(Se4+O3)(SO4)(OH)4 Mon. 2/m : _P_21/m
7.BC.65 Therasiaite (NH4)3KNa2Fe2+Fe3+(SO4)3Cl5 Mon. m : B b
7.BC.65 Saccoite Ca2Mn3+2F(OH)8 · 0.5(SO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.70 Chenite Pb4Cu(SO4)2(OH)6 Tric. 1 : _P_1
7.BC.75 Krivovichevite Pb3Al(OH)6(SO4)(OH) Trig. 3_m_ : R_3_c
7.BC.80 Anhydrokainite KMg(SO4)Cl

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for AmmonioaluniteHide

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Reference List:

Altaner, S.P., Fitzpatrick, J.J., Krohn, M.D., Bethke, P.M., Hayba, D.O., Goss, J.A., Brown, Z.A. (1988) Ammonium in alunites. American Mineralogist: 73: 145-152.

Localities for AmmonioaluniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Czech Republic
Central Bohemian Region Kladno District Zacek et al. (1995)
Libušin Tony Nikischer
Kladno mine Zacek et al. (2019)
Hradec Králové Region Trutnov District Radvanice Kateřina Coal Mine Jirásek (2001)
Germany
North Rhine-Westphalia Cologne Aachen Alsdorf Anna mine Witzke et al. (2015)
Thuringia Greiz District Kauern Lichtenberg Absetzer dump T. Witzke & F. Rüger: Lapis 1998 (7/8)
Hungary
Baranya County Pécs District Pécs-Vasas 2015 May 16-19 +2 other references
Lebanon
South Governorate Jezzine District Bhanine Valley ? Łukasz (2019)
Poland
Silesian Voivodeship Rybnik Chwałowice Starzykowiec coal-mining dump Ciesielczuk et al. (2014)
Rybnik County Gmina Czerwionka-Leszczyny Dębieńsko Mine heap Parafiniuk et al. (2009)
Wodzisław County Radlin Marcel mine heap Kruszewski et al. (2019)
USA
California Napa County Knoxville Mining District Knoxville McLaughlin Mine (Manhattan Mine) Journal of Volcanology & Geothermal ...
Sonoma County West Mayacmas Mining District The Geysers (TL) Altaner et al. (1988) +1 other reference
Nevada Elko County Ivanhoe Mining District Jour.Volcanology & Geothermal Res. ... +1 other reference
Washoe County Nightingale Mining District Unnamed prospect Castor et al. (2004)