Chlorothionite (original) (raw)

A valid IMA mineral species - grandfathered

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About ChlorothioniteHide

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Crystal System:

Orthorhombic

Name:

In allusion to the chemical composition, containing CHLORine and sulphur (THIO-).

This page provides mineralogical data about Chlorothionite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:982:1

ab4e9930-9546-4083-bbfc-cd0d07e6ea31

IMA Classification of ChlorothioniteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of ChlorothioniteHide

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7.BC.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

30.1.11.1

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1

26.6

26 : Sulphates with Halide

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ctn IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ChlorothioniteHide

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Density:

2.67 g/cm3 (Measured)

Comment:

Measured values on artificial crystals.

Optical Data of ChlorothioniteHide

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Chemistry of ChlorothioniteHide

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Mindat Formula:

K2Cu(SO4)Cl2

Crystallography of ChlorothioniteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 7.73 Å, b = 6.07 Å, c = 16.29 Å

Ratio:

a:b:c = 1.273 : 1 : 2.684

Unit Cell V:

764.34 ų (Calculated from Unit Cell)

Morphology:

Crystalline incrustations.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0010784 Chlorothionite Giacovazzo C, Scandale E, Scordari F (1976) The crystal structure of chlorotionite, CuK2Cl2SO4 Zeitschrift fur Kristallographie 144 226-237 1976 1906 eruption of Vesuvius, Italy 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.04 Å (100)
2.187 Å (70)
2.847 Å (35)
5.69 Å (30)
3.26 Å (30)
3.15 Å (20)
2.491 Å (20)

Geological EnvironmentHide

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Type Occurrence of ChlorothioniteHide

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General Appearance of Type Material:

Bright blue crystalline incrustations.

Place of Conservation of Type Material:

Mineralogical Museum, University of Bari, Bari, Italy.

Geological Setting of Type Material:

Active volcanic fumaroles.

Reference:

Scacchi, A. (1872) Notizie preliminari di alcune specie mineralogiche rinvenute nel Vesuvio dopo l'incendio di aprile 1872. Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 11: 210-213.

Other Language Names for ChlorothioniteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.BC. Adranosite-(Fe) (NH4)4NaFe3+2(SO4)4Cl(OH)2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
7.BC. Adranosite (NH4)4NaAl2(SO4)4Cl(OH)2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
7.BC. D'Ansite-(Mn) Na21Mn2+(SO4)10Cl3 Iso. 43_m_ : I_43_d
7.BC. Agaite Pb3CuTeO5(OH)2(CO3) Orth. m _m_2 : P c _a_21
7.BC. D'Ansite-(Fe) Na21Fe2+(SO4)10Cl3 Iso. 43_m_ : I_43_d
7.BC. Acmonidesite (NH4,K,Pb)8NaFe2+4(SO4)5Cl8 Orth. 222 : _C_2221
7.BC. Backite Pb2AlTeO6Cl Trig. 32 : _P_312
7.BC. Hagstromite Pb8Cu2+(Te6+O6)2(CO3)Cl4 Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
7.BC. Wildcatite CaFe3+Te6+O5(OH) Trig. 3_m_ _(_32/m ) : P_31_m
7.BC. Franksousaite PbCu(Se6+O4)(OH)2 Mon. 2/m : _P_21/m
7.BC. Zincochenite Pb4Zn(OH)6(SO4)2 Tric. 1 : _P_1
7.BC. Viskontite Pb5Cu2(SO4)3(SeO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC. Chromviskontite Pb5Cu2(CrO4)3(SeO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC.05 D'Ansite Na21Mg(SO4)10Cl3 Iso. 43_m_ : I_43_m
7.BC.07 Apatelite Fe3(SO4)2(OH)5 · 0.5H2O
7.BC.07 Unnamed (Ba-Fe Vanadate) Ba, Fe, V, O, H
7.BC.10 Alunite KAl3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Ammonioalunite (NH4)Al3(SO4)2(OH)6 Trig.
7.BC.10 Ammoniojarosite (NH4)Fe3+3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Argentojarosite AgFe3+3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Beaverite-(Cu) Pb(Fe3+2Cu)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Dorallcharite TlFe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Huangite Ca0.5Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Hydroniumjarosite (H3O)Fe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Jarosite KFe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Natroalunite-2c (Na,Ca0.5,K)Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Natroalunite NaAl3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Natrojarosite NaFe3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Osarizawaite Pb(Al2Cu2+)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Plumbojarosite Pb0.5Fe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Schlossmacherite (H3O)Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Walthierite Ba0.5Al3(SO4)2(OH)6 Trig.
7.BC.10 Beaverite-(Zn) Pb(Fe3+2Zn)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Karlseifertite Pb(Ga2Ge)(AsO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.15 Ye'elimite Ca4Al6(SO4)O12 Iso. 432 : _I_4132
7.BC.20 Atlasovite K(BiO)Cu6Fe3+(SO4)5O3Cl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.20 Nabokoite KCu7(SO4)5(Te4+O3)OCl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.20 Puninite Na2Cu3O(SO4)3 Mon. 2/m : _B_2/b
7.BC.30 Euchlorine KNaCu3(SO4)3O Mon. 2/m
7.BC.30 Fedotovite K2Cu3(SO4)3O Mon. 2/m : _B_2/b
7.BC.35 Kamchatkite KCu3(SO4)2OCl Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.40 Piypite K4Cu4O2(SO4)4 · (Na,Cu)Cl Tet. 4 : _I_4
7.BC.45 Klyuchevskite K3Cu3(Fe3+,Al)(SO4)4O2 Mon. 2
7.BC.45 Alumoklyuchevskite K3Cu3(Al,Fe3+)(SO4)4O2 Tric. 1 : _P_1
7.BC.45 Belousovite KZn(SO4)Cl Mon. 2/m : _P_21/b
7.BC.47 Müllerite Pb2Fe3+(Te6+O6)Cl Trig. 32 : _P_3112
7.BC.50 Caledonite Pb5Cu2(SO4)3(CO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC.50 Elasmochloite Na3Cu6BiO4(SO4)5 Mon. 2/m
7.BC.52 Eleomelanite (K2Pb)Cu4O2(SO4)4 Mon. 2/m
7.BC.55 Wherryite Pb7Cu2(SO4)4(SiO4)2(OH)2 Mon. 2/m : _B_2/m
7.BC.55 Falgarite K4(VO)3(SO4)5 Mon. 2/m : _B_2/b
7.BC.57 Krasheninnikovite KNa2CaMg(SO4)3F Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m c m
7.BC.60 Mammothite Pb6Cu4AlSb5+O2(OH)16Cl4(SO4)2 Mon. 2 : _B_2
7.BC.60 Wulffite K3NaCu4O2(SO4)4 Orth. m _m_2
7.BC.60 Parawulffite K5Na3Cu8O4(SO4)8 Mon. 2/m : _P_2/b
7.BC.62 Shuvalovite K2(Ca2Na)(SO4)3F Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.65 Linarite PbCu(SO4)(OH)2 Mon. 2/m : _P_21/m
7.BC.65 Schmiederite Pb2Cu2(Se6+O4)(Se4+O3)(OH)4 Mon. 2/m : _P_21/m
7.BC.65 Munakataite Pb2Cu2(Se4+O3)(SO4)(OH)4 Mon. 2/m : _P_21/m
7.BC.65 Therasiaite (NH4)3KNa2Fe2+Fe3+(SO4)3Cl5 Mon. m : B b
7.BC.65 Saccoite Ca2Mn3+2F(OH)8 · 0.5(SO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.70 Chenite Pb4Cu(SO4)2(OH)6 Tric. 1 : _P_1
7.BC.75 Krivovichevite Pb3Al(OH)6(SO4)(OH) Trig. 3_m_ : R_3_c
7.BC.80 Anhydrokainite KMg(SO4)Cl

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for ChlorothioniteHide

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Reference List:

Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.

Localities for ChlorothioniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Italy (TL)
Campania Metropolitan City of Naples Mount Vesuvius (TL) [Lapis 1994:5 p.13-23 +2 other references
Vesuvius fumaroles Pelloux (1927) +2 other references
Russia
Kamchatka Krai Milkovsky District Tolbachik Volcanic field Pekov et al. (2012)
Great Fissure eruption (Main Fracture) Northern Breakthrough (North Breach) Second scoria cone Glavnaya Tenoritovaya fumarole (Major Tenorite) Pekov et al. (2015)
Yadovitaya fumarole Pekov et al. (2012)