Chlorothionite (original) (raw)
A valid IMA mineral species - grandfathered
About ChlorothioniteHide
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Crystal System:
Orthorhombic
Name:
In allusion to the chemical composition, containing CHLORine and sulphur (THIO-).
This page provides mineralogical data about Chlorothionite.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:982:1
ab4e9930-9546-4083-bbfc-cd0d07e6ea31
IMA Classification of ChlorothioniteHide
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Approved, 'Grandfathered' (first described prior to 1959)
Type description reference:
Classification of ChlorothioniteHide
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7.BC.25
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
30.1.11.1
30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
26.6
26 : Sulphates with Halide
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Ctn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of ChlorothioniteHide
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Density:
2.67 g/cm3 (Measured)
Comment:
Measured values on artificial crystals.
Optical Data of ChlorothioniteHide
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Chemistry of ChlorothioniteHide
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Mindat Formula:
K2Cu(SO4)Cl2
Crystallography of ChlorothioniteHide
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Crystal System:
Orthorhombic
Class (H-M):
m m m _(_2/_m_2/_m_2/m ) - Dipyramidal
Cell Parameters:
a = 7.73 Å, b = 6.07 Å, c = 16.29 Å
Ratio:
a:b:c = 1.273 : 1 : 2.684
Unit Cell V:
764.34 ų (Calculated from Unit Cell)
Morphology:
Crystalline incrustations.
Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0010784 | Chlorothionite | Giacovazzo C, Scandale E, Scordari F (1976) The crystal structure of chlorotionite, CuK2Cl2SO4 Zeitschrift fur Kristallographie 144 226-237 | 1976 | 1906 eruption of Vesuvius, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.04 Å | (100) |
2.187 Å | (70) |
2.847 Å | (35) |
5.69 Å | (30) |
3.26 Å | (30) |
3.15 Å | (20) |
2.491 Å | (20) |
Geological EnvironmentHide
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Type Occurrence of ChlorothioniteHide
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General Appearance of Type Material:
Bright blue crystalline incrustations.
Place of Conservation of Type Material:
Mineralogical Museum, University of Bari, Bari, Italy.
Geological Setting of Type Material:
Active volcanic fumaroles.
Reference:
Scacchi, A. (1872) Notizie preliminari di alcune specie mineralogiche rinvenute nel Vesuvio dopo l'incendio di aprile 1872. Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 11: 210-213.
Other Language Names for ChlorothioniteHide
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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7.BC. | Adranosite-(Fe) | (NH4)4NaFe3+2(SO4)4Cl(OH)2 | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d |
---|---|---|---|
7.BC. | Adranosite | (NH4)4NaAl2(SO4)4Cl(OH)2 | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d |
7.BC. | D'Ansite-(Mn) | Na21Mn2+(SO4)10Cl3 | Iso. 43_m_ : I_43_d |
7.BC. | Agaite | Pb3CuTeO5(OH)2(CO3) | Orth. m _m_2 : P c _a_21 |
7.BC. | D'Ansite-(Fe) | Na21Fe2+(SO4)10Cl3 | Iso. 43_m_ : I_43_d |
7.BC. | Acmonidesite | (NH4,K,Pb)8NaFe2+4(SO4)5Cl8 | Orth. 222 : _C_2221 |
7.BC. | Backite | Pb2AlTeO6Cl | Trig. 32 : _P_312 |
7.BC. | Hagstromite | Pb8Cu2+(Te6+O6)2(CO3)Cl4 | Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m |
7.BC. | Wildcatite | CaFe3+Te6+O5(OH) | Trig. 3_m_ _(_32/m ) : P_31_m |
7.BC. | Franksousaite | PbCu(Se6+O4)(OH)2 | Mon. 2/m : _P_21/m |
7.BC. | Zincochenite | Pb4Zn(OH)6(SO4)2 | Tric. 1 : _P_1 |
7.BC. | Viskontite | Pb5Cu2(SO4)3(SeO3)(OH)6 | Orth. m _m_2 : P m _n_21 |
7.BC. | Chromviskontite | Pb5Cu2(CrO4)3(SeO3)(OH)6 | Orth. m _m_2 : P m _n_21 |
7.BC.05 | D'Ansite | Na21Mg(SO4)10Cl3 | Iso. 43_m_ : I_43_m |
7.BC.07 | Apatelite | Fe3(SO4)2(OH)5 · 0.5H2O | |
7.BC.07 | Unnamed (Ba-Fe Vanadate) | Ba, Fe, V, O, H | |
7.BC.10 | Alunite | KAl3(SO4)2(OH)6 | Trig. 3_m_ : R_3_m |
7.BC.10 | Ammonioalunite | (NH4)Al3(SO4)2(OH)6 | Trig. |
7.BC.10 | Ammoniojarosite | (NH4)Fe3+3(SO4)2(OH)6 | Trig. 3_m_ : R_3_m |
7.BC.10 | Argentojarosite | AgFe3+3(SO4)2(OH)6 | Trig. 3_m_ : R_3_m |
7.BC.10 | Beaverite-(Cu) | Pb(Fe3+2Cu)(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Dorallcharite | TlFe3+3(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Huangite | Ca0.5Al3(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Hydroniumjarosite | (H3O)Fe3+3(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Jarosite | KFe3+3(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Natroalunite-2c | (Na,Ca0.5,K)Al3(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Natroalunite | NaAl3(SO4)2(OH)6 | Trig. 3_m_ : R_3_m |
7.BC.10 | Natrojarosite | NaFe3(SO4)2(OH)6 | Trig. 3_m_ : R_3_m |
7.BC.10 | Osarizawaite | Pb(Al2Cu2+)(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Plumbojarosite | Pb0.5Fe3+3(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Schlossmacherite | (H3O)Al3(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Walthierite | Ba0.5Al3(SO4)2(OH)6 | Trig. |
7.BC.10 | Beaverite-(Zn) | Pb(Fe3+2Zn)(SO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.10 | Karlseifertite | Pb(Ga2Ge)(AsO4)2(OH)6 | Trig. 3_m_ _(_32/m ) : R_3_m |
7.BC.15 | Ye'elimite | Ca4Al6(SO4)O12 | Iso. 432 : _I_4132 |
7.BC.20 | Atlasovite | K(BiO)Cu6Fe3+(SO4)5O3Cl | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c |
7.BC.20 | Nabokoite | KCu7(SO4)5(Te4+O3)OCl | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c |
7.BC.20 | Puninite | Na2Cu3O(SO4)3 | Mon. 2/m : _B_2/b |
7.BC.30 | Euchlorine | KNaCu3(SO4)3O | Mon. 2/m |
7.BC.30 | Fedotovite | K2Cu3(SO4)3O | Mon. 2/m : _B_2/b |
7.BC.35 | Kamchatkite | KCu3(SO4)2OCl | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
7.BC.40 | Piypite | K4Cu4O2(SO4)4 · (Na,Cu)Cl | Tet. 4 : _I_4 |
7.BC.45 | Klyuchevskite | K3Cu3(Fe3+,Al)(SO4)4O2 | Mon. 2 |
7.BC.45 | Alumoklyuchevskite | K3Cu3(Al,Fe3+)(SO4)4O2 | Tric. 1 : _P_1 |
7.BC.45 | Belousovite | KZn(SO4)Cl | Mon. 2/m : _P_21/b |
7.BC.47 | Müllerite | Pb2Fe3+(Te6+O6)Cl | Trig. 32 : _P_3112 |
7.BC.50 | Caledonite | Pb5Cu2(SO4)3(CO3)(OH)6 | Orth. m _m_2 : P m _n_21 |
7.BC.50 | Elasmochloite | Na3Cu6BiO4(SO4)5 | Mon. 2/m |
7.BC.52 | Eleomelanite | (K2Pb)Cu4O2(SO4)4 | Mon. 2/m |
7.BC.55 | Wherryite | Pb7Cu2(SO4)4(SiO4)2(OH)2 | Mon. 2/m : _B_2/m |
7.BC.55 | Falgarite | K4(VO)3(SO4)5 | Mon. 2/m : _B_2/b |
7.BC.57 | Krasheninnikovite | KNa2CaMg(SO4)3F | Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m c m |
7.BC.60 | Mammothite | Pb6Cu4AlSb5+O2(OH)16Cl4(SO4)2 | Mon. 2 : _B_2 |
7.BC.60 | Wulffite | K3NaCu4O2(SO4)4 | Orth. m _m_2 |
7.BC.60 | Parawulffite | K5Na3Cu8O4(SO4)8 | Mon. 2/m : _P_2/b |
7.BC.62 | Shuvalovite | K2(Ca2Na)(SO4)3F | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
7.BC.65 | Linarite | PbCu(SO4)(OH)2 | Mon. 2/m : _P_21/m |
7.BC.65 | Schmiederite | Pb2Cu2(Se6+O4)(Se4+O3)(OH)4 | Mon. 2/m : _P_21/m |
7.BC.65 | Munakataite | Pb2Cu2(Se4+O3)(SO4)(OH)4 | Mon. 2/m : _P_21/m |
7.BC.65 | Therasiaite | (NH4)3KNa2Fe2+Fe3+(SO4)3Cl5 | Mon. m : B b |
7.BC.65 | Saccoite | Ca2Mn3+2F(OH)8 · 0.5(SO4) | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c |
7.BC.70 | Chenite | Pb4Cu(SO4)2(OH)6 | Tric. 1 : _P_1 |
7.BC.75 | Krivovichevite | Pb3Al(OH)6(SO4)(OH) | Trig. 3_m_ : R_3_c |
7.BC.80 | Anhydrokainite | KMg(SO4)Cl |
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for ChlorothioniteHide
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References for ChlorothioniteHide
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Reference List:
Localities for ChlorothioniteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Italy (TL) | |
---|---|
Campania Metropolitan City of Naples ⓘ Mount Vesuvius (TL) | [Lapis 1994:5 p.13-23 +2 other references |
ⓘ Vesuvius fumaroles | Pelloux (1927) +2 other references |
Russia | |
Kamchatka Krai Milkovsky District ⓘ Tolbachik Volcanic field | Pekov et al. (2012) |
Great Fissure eruption (Main Fracture) Northern Breakthrough (North Breach) Second scoria cone ⓘ Glavnaya Tenoritovaya fumarole (Major Tenorite) | Pekov et al. (2015) |
ⓘ Yadovitaya fumarole | Pekov et al. (2012) |