Chenite (original) (raw)

A valid IMA mineral species

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About CheniteHide

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Colour:

Sky blue, pale blue

Lustre:

Adamantine, Vitreous, Resinous

Name:

Named in honor of Tzong Tzy Chen (b. 1942), mineralogist with the Canada Centre for Mineral and Energy Technology (CANMET), Ottawa, Ontario, Canada, for his contributions to mineralogy.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:987:6

f6199c6e-6537-42d9-b2ea-6eca0c8384a9

IMA Classification of CheniteHide

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IMA Formula:

CuPb4(SO4)2(OH)6

Classification of CheniteHide

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7.BC.70

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

30.1.16.1

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1

25.7.8

25 : Sulphates
7 : Sulphates of Pb

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Che IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CheniteHide

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Adamantine, Vitreous, Resinous

Transparency:

Transparent, Translucent

Colour:

Sky blue, pale blue

Cleavage:

Distinct/Good
On {100}; traces of another cleavage on {001}.

Density:

5.98(2) g/cm3 (Measured) 6.044 g/cm3 (Calculated)

Optical Data of CheniteHide

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RI values:

_n_α = 1.871 _n_β = 1.909 _n_γ = 1.927

2V:

Measured: 67° (1), Calculated: 66°

δ = 0.056

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

Very strong, r >> v.

Chemistry of CheniteHide

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Mindat Formula:

Pb4Cu(SO4)2(OH)6

Crystallography of CheniteHide

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Class (H-M):

1 - Pinacoidal

Cell Parameters:

a = 5.791(1) Å, b = 7.940(1) Å, c = 7.976(1) Å
α = 112.02(1)°, β = 97.73(1)°, γ = 100.45(1)°

Ratio:

a:b:c = 0.729 : 1 : 1.005

Unit Cell V:

326.00 ų (Calculated from Unit Cell)

Morphology:

Tabular, pointed, rich in faces. Forms include dominant {132} and {221}, less dominant {100}. Also {253}, {154}, {110}, {010}, {001}, {101}, {111}, {112}.

Twinning:

Twinning observed.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0014826 Chenite Hess H, Keller P, Riffel H (1988) The crystal structure of chenite, Pb4Cu(OH)6(SO4)2 Neues Jahrbuch fur Mineralogie, Monatshefte 1988 259-264 1988 Leadhills, Scotland 0 293
0015326 Chenite Mereiter K (2009) Chenite, Pb4Cu(SO4)2(OH)6, from Susanna mine, Leadhills, Scotland. Private communication 0 0-0 2009 Susanna mine, Leadhills, Scotland 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.55 Å (70)
4.32 Å (60)
3.97 Å (30)
3.60 Å (100)
3.41 Å (90)
3.30 Å (50)
3.00 Å (50)
2.87 Å (40)
2.80 Å (70)
2.71 Å (40)
2.53 Å (30)
2.21 Å (40)
2.07 Å (60)
1.949 Å (40)
1.914 Å (30)
1.838 Å (40)
1.778 Å (50)
1.750 Å (30)
1.704 Å (30)
1.582 Å (30)

Comments:

Data from type description.

Geological EnvironmentHide

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Type Occurrence of CheniteHide

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General Appearance of Type Material:

Crystals to 1 x 0.5 x 0.2 mm in size, and a twinned crystal 1.5 mm in length.

Place of Conservation of Type Material:

Institut für Mineralogie und Kristallchemie, Universität Stuttgart, Stuttgart, Germany, number NM 14 (holotype).
National Museum of Natural History, Washington, D.C., USA, number 160384 (cotype).
Archiv der Universität Stuttgart, Stuttgart, Germany, number TM-83.69 (part of the holotype).
Royal Ontario Museum, Toronto, Ontario, Canada.
Institut fUr Mineralogie, Kristallographie und Strukturchemie der Technischen Universitat Wien, Wien, Austria.

Geological Setting of Type Material:

Secondary mineral in a lead-copper deposit.

Associated Minerals at Type Locality:

Synonyms of CheniteHide

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Other Language Names for CheniteHide

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Relationship of Chenite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.BC. Adranosite-(Fe) (NH4)4NaFe3+2(SO4)4Cl(OH)2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
7.BC. Adranosite (NH4)4NaAl2(SO4)4Cl(OH)2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
7.BC. D'Ansite-(Mn) Na21Mn2+(SO4)10Cl3 Iso. 43_m_ : I_43_d
7.BC. Agaite Pb3CuTeO5(OH)2(CO3) Orth. m _m_2 : P c _a_21
7.BC. D'Ansite-(Fe) Na21Fe2+(SO4)10Cl3 Iso. 43_m_ : I_43_d
7.BC. Acmonidesite (NH4,K,Pb)8NaFe2+4(SO4)5Cl8 Orth. 222 : _C_2221
7.BC. Backite Pb2AlTeO6Cl Trig. 32 : _P_312
7.BC. Hagstromite Pb8Cu2+(Te6+O6)2(CO3)Cl4 Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
7.BC. Wildcatite CaFe3+Te6+O5(OH) Trig. 3_m_ _(_32/m ) : P_31_m
7.BC. Franksousaite PbCu(Se6+O4)(OH)2 Mon. 2/m : _P_21/m
7.BC. Zincochenite Pb4Zn(OH)6(SO4)2 Tric. 1 : _P_1
7.BC. Viskontite Pb5Cu2(SO4)3(SeO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC. Chromviskontite Pb5Cu2(CrO4)3(SeO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC.05 D'Ansite Na21Mg(SO4)10Cl3 Iso. 43_m_ : I_43_m
7.BC.07 Apatelite Fe3(SO4)2(OH)5 · 0.5H2O
7.BC.07 Unnamed (Ba-Fe Vanadate) Ba, Fe, V, O, H
7.BC.10 Alunite KAl3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Ammonioalunite (NH4)Al3(SO4)2(OH)6 Trig.
7.BC.10 Ammoniojarosite (NH4)Fe3+3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Argentojarosite AgFe3+3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Beaverite-(Cu) Pb(Fe3+2Cu)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Dorallcharite TlFe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Huangite Ca0.5Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Hydroniumjarosite (H3O)Fe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Jarosite KFe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Natroalunite-2c (Na,Ca0.5,K)Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Natroalunite NaAl3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Natrojarosite NaFe3(SO4)2(OH)6 Trig. 3_m_ : R_3_m
7.BC.10 Osarizawaite Pb(Al2Cu2+)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Plumbojarosite Pb0.5Fe3+3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Schlossmacherite (H3O)Al3(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Walthierite Ba0.5Al3(SO4)2(OH)6 Trig.
7.BC.10 Beaverite-(Zn) Pb(Fe3+2Zn)(SO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.10 Karlseifertite Pb(Ga2Ge)(AsO4)2(OH)6 Trig. 3_m_ _(_32/m ) : R_3_m
7.BC.15 Ye'elimite Ca4Al6(SO4)O12 Iso. 432 : _I_4132
7.BC.20 Atlasovite K(BiO)Cu6Fe3+(SO4)5O3Cl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.20 Nabokoite KCu7(SO4)5(Te4+O3)OCl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.20 Puninite Na2Cu3O(SO4)3 Mon. 2/m : _B_2/b
7.BC.25 Chlorothionite K2Cu(SO4)Cl2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.30 Euchlorine KNaCu3(SO4)3O Mon. 2/m
7.BC.30 Fedotovite K2Cu3(SO4)3O Mon. 2/m : _B_2/b
7.BC.35 Kamchatkite KCu3(SO4)2OCl Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.40 Piypite K4Cu4O2(SO4)4 · (Na,Cu)Cl Tet. 4 : _I_4
7.BC.45 Klyuchevskite K3Cu3(Fe3+,Al)(SO4)4O2 Mon. 2
7.BC.45 Alumoklyuchevskite K3Cu3(Al,Fe3+)(SO4)4O2 Tric. 1 : _P_1
7.BC.45 Belousovite KZn(SO4)Cl Mon. 2/m : _P_21/b
7.BC.47 Müllerite Pb2Fe3+(Te6+O6)Cl Trig. 32 : _P_3112
7.BC.50 Caledonite Pb5Cu2(SO4)3(CO3)(OH)6 Orth. m _m_2 : P m _n_21
7.BC.50 Elasmochloite Na3Cu6BiO4(SO4)5 Mon. 2/m
7.BC.52 Eleomelanite (K2Pb)Cu4O2(SO4)4 Mon. 2/m
7.BC.55 Wherryite Pb7Cu2(SO4)4(SiO4)2(OH)2 Mon. 2/m : _B_2/m
7.BC.55 Falgarite K4(VO)3(SO4)5 Mon. 2/m : _B_2/b
7.BC.57 Krasheninnikovite KNa2CaMg(SO4)3F Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m c m
7.BC.60 Mammothite Pb6Cu4AlSb5+O2(OH)16Cl4(SO4)2 Mon. 2 : _B_2
7.BC.60 Wulffite K3NaCu4O2(SO4)4 Orth. m _m_2
7.BC.60 Parawulffite K5Na3Cu8O4(SO4)8 Mon. 2/m : _P_2/b
7.BC.62 Shuvalovite K2(Ca2Na)(SO4)3F Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
7.BC.65 Linarite PbCu(SO4)(OH)2 Mon. 2/m : _P_21/m
7.BC.65 Schmiederite Pb2Cu2(Se6+O4)(Se4+O3)(OH)4 Mon. 2/m : _P_21/m
7.BC.65 Munakataite Pb2Cu2(Se4+O3)(SO4)(OH)4 Mon. 2/m : _P_21/m
7.BC.65 Therasiaite (NH4)3KNa2Fe2+Fe3+(SO4)3Cl5 Mon. m : B b
7.BC.65 Saccoite Ca2Mn3+2F(OH)8 · 0.5(SO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n c c
7.BC.75 Krivovichevite Pb3Al(OH)6(SO4)(OH) Trig. 3_m_ : R_3_c
7.BC.80 Anhydrokainite KMg(SO4)Cl

Fluorescence of CheniteHide

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Other InformationHide

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Notes:

Does NOT effervesce in dilute hydrochloric acid, allowing it to be distinguished from caledonite.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for CheniteHide

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Reference List:

Paar, W. H., Mereiter, Kurt, Braithwaite, R. S. W., Keller, Paul, Dunn, P. J. (1986) Chenite, Pb4Cu(SO4)2(OH)6, a new mineral, from Leadhills, Scotland. Mineralogical Magazine, 50 (355) 129-135 doi:10.1180/minmag.1986.050.355.17

Hawthorne, F.C., Bladh, K.W., Burke, E.A.J, Grew, E.S., Langley, R.H., Puciewicz, J., Roberts, A.C., Schedler, R.A., Shigley, J.E., Vanko, D.A. (1987) New mineral names. American Mineralogist: 72: 222-230.

Localities for CheniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Argentina
Río Negro Province Valcheta Department San Martin pluton San Martín Mine Herrmann et al. (2007)
Austria
Carinthia Sankt Veit an der Glan District Guttaring Waitschach Slag localities Kolitsch et al. (2013)
Hüttenberg Sankt Martin am Silberberg Slag localities Blaß et al. (1997)
Styria Liezen District Öblarn Walchen Slag dumps 50. +1 other reference
Belgium
Flanders Limburg Dilsen-Stokkem Rotem Rotem slag locality ?
Wallonia Namur Andenne Seilles Sclaigneaux slag locality
China
Anhui Hefei Lujiang Co. Huangzhuyuan deposit LIU et al. (2021)
France
Auvergne-Rhône-Alpes Loire Roanne Le Crozet Les Rats Mine slag dumps Vernay (1997) +1 other reference
Rhône Villefranche-sur-Saône Poule-les-Écharmeaux Longefay mine ? Chollet Pascal Collection
Brittany Finistère Châteaulin Poullaouen La Fonderie slag locality Germain C. et al. (1990)
Occitanie Aude Narbonne Padern Tistoulet mine Favreau et al. (2003)
Aveyron Villefranche-de-Rouergue Asprières Bréziès Lesénéchal.T. & Desor (04/21)
Lozère Florac Vialas Vialas smelter slag locality Georges Favreau collection
Germany
Baden-Württemberg Freiburg Region Breisgau-Hochschwarzwald Badenweiler Badenweiler Pb mining district Sehringen Haus Baden Mine Weiß (1990)
Müllheim Altemann cliff Schlomann et al. (1990)
Emmendingen Freiamt Steckwald Walenta (1992)
Waldshut St Blasien Steinenbächle Walenta (1992)
Lower Saxony Goslar District Clausthal-Zellerfeld Oberschulenberg Glücksrad Mine Schnorrer-Köhler (1991)
Silberbach slag locality "Lithothek" collection of the ...
Silver smelter slag locality inCollection Gerhard Niceus
Goslar Kleines Drecktal slag locality - (n.d.)
Langelsheim Astfeld Herzog Julius smelter slag locality
Lautenthal Lautenthal smelter slag locality
North Rhine-Westphalia Arnsberg Hochsauerlandkreis Meschede Alexander Mine Weiss: "Mineralienfundstellen et al. (Munich)
Sundern Bönkhausen Churfürst Ernst Mine Wittern (2001)
Cologne Euskirchen Kall Copper smelter slag locality Blaß et al. (1995)
Rhineland-Palatinate Neuwied Unkel Rheinbreitbach Virneberg Mine Krause (1991)
Greece
Attica East Attica Lavreotiki Lavrion mining district Lophos Agrileza mines Maria Mine 90. +1 other reference
Italy
Tuscany Grosseto Province Massa Marittima Valpiana - Castello della Marsiliana area slag sites Marsiliana slag locality Jansen et al. (1998)
Livorno Province Campiglia Marittima Madonna di Fucinaia (Madonna della Fucinaia) slag heaps Jansen et al. (1998)
Piombino Baratti slag locality Jansen et al. (1998)
Sassetta Canina Valley Podere del Cancellino (Podere dei Cancellini) slag locality Jansen et al. (1998)
Japan
Shimane Prefecture Ōda City Iwami mine (Iwami-ginzan) Akasaka (2007)
Spain
Andalusia Jaén Linares La Cruz La Cruz lead smelter slag locality Calvo Rebollar et al. (2022)
Catalonia Tarragona Baix Camp Alforja Alforja Mine Joan Abella i Creus (Joanabellacreus@gmail.com)
Thailand
Phang Nga Province Thai Mueang Lam Phi Chang Non Quartz vein ? Patrice Queneau Collection
UK
England Cornwall Porthleven Wheal Rose (Wheal Lomax) ? G.Curtis collection.
County Durham Healeyfield Castleside Smelting Mill slag locality Norman Wilson collection +1 other reference
Cumbria Allerdale Caldbeck Deer Hills Short Grain Green et al. (2008)
Driggith Mine (Driggeth Mine) Green et al. (1996) +1 other reference
Roughton Gill Higher Roughton Gill (Balliway Rigg) Green et al. (2008)
Red Gill Mine Green et al. (2008)
Eden Mungrisdale Saddleback Old Mine Briscoe et al. (2008)
Scotland Dumfries and Galloway Wanlockhead Meadowfoot Smelter slag locality Green (1987) +2 other references
Pates Knowes Smelter slag locality S. Rust collection.
Whytes Cleuch S Rust collection
Cove Vein S.Rust Collection
South Lanarkshire Leadhills Horners Vein (Jeffrey's Vein; Carse's Vein) Day (1999)
Susanna Mine (Glennery Scar vein; Susanna vein [Scar vein]; Portobello vein; Humby vein; Lead vein) (TL) Paar et al. (1986)
Wanlock Dod Hopeful Vein Steve Rust collection
Scar Vein S.Rust Collection
Wales Ceredigion Ceulanymaesmawr Tal-y-bont Bwlch Glas Mine ? S Rust
Esgair Hir & Esgair Fraith mines (Cambrian Mine; Cardigan Consolidated Mine; Welsh Potosi Mine; Kylon Potosi Mine) Rust (1997)
Trefeirig Pen-bont Rhydybeddau Llechwedd Helyg Mine (Willow Bank Mine) Rust (1994)
USA
North Carolina Haywood County Waterville Lake Redmond Mine A. Kampf or C. Emproto PXRD and/EDS ... +1 other reference