Pararobertsite (original) (raw)

A valid IMA mineral species

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About PararobertsiteHide

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Formula:

Ca2Mn3+3(PO4)3O2 · 3H2O

Colour:

Bronze, cinnamon brown, yellow, dark red

Lustre:

Sub-Vitreous, Resinous, Waxy, Greasy

Crystal System:

Monoclinic

Name:

Named in 1988 by Andrew C. Roberts, B. Darko Sturman, Pete J. Dunn, and Willard L. Roberts, from the Greek 'para' for near, and robertsite, for the polymorphic relationship with that mineral.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3108:6

2335f57d-e6ba-471d-b80e-3527d1e8bc53

IMA Classification of PararobertsiteHide

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Type description reference:

Roberts, A. C., Sturman, B. D., Dunn, P. J., Roberts, W. L. (1989) Pararobertsite, Ca2Mn3+3(PO4)3O2·3H2O, a New Mineral Species from the Tip Top Pegmatite, Custer County, South Dakota, and its Relationship to Robertsite. The Canadian Mineralogist, 27 (3) 451-455

Classification of PararobertsiteHide

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8.DH.30

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1

42.8.5.2

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
8 : (AB)5(XO4)3Zq·xH2O

19.12.7

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Prb IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PararobertsiteHide

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Sub-Vitreous, Resinous, Waxy, Greasy

Transparency:

Transparent, Translucent

Colour:

Bronze, cinnamon brown, yellow, dark red

Comment:

Usually dark red to cinnamon brown

Fracture:

Irregular/Uneven

Density:

3.22 g/cm3 (Measured) 3.21 g/cm3 (Calculated)

Optical Data of PararobertsiteHide

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RI values:

_n_α = 1.791(1) _n_β = 1.811(1) _n_γ = 1.831(1)

2V:

Measured: 84° , Calculated: 85° to 88°

δ = 0.040

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Z^c = 4°

Comments:

X = yellowish brown; Y = Z = reddish brown

Comments:

Absorption: Z = Y > X

Chemistry of PararobertsiteHide

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Mindat Formula:

Ca2Mn3+3(PO4)3O2 · 3H2O

Crystallography of PararobertsiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 8.825(3) Å, b = 13.258(4) Å, c = 11.087(3) Å
β = 101.19(4)°

Ratio:

a:b:c = 0.666 : 1 : 0.836

Morphology:

Triangular to pseudo-rhombohedral plates, sometimes rhombic plates.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0002513 Pararobertsite Kampf A R (2000) The crystal structure of pararobertsite and its relationship to mitridatite American Mineralogist 85 1302-1306 2000 Tip Top pegmatite, Custer County, South Dakota, USA 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.69 Å (100)
5.66 Å (60)
5.44 Å (50)
2.884 Å (60)
2.772 Å (70)
2.611 Å (60)
2.163 Å (60)

Geological EnvironmentHide

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Geological Setting:

Fracture fillings in late-stage mineralization in a phosphate-rich granite pegmatite.

Type Occurrence of PararobertsiteHide

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General Appearance of Type Material:

Thin red transparent single plates, or clusters of plates, on whitlockite.

Place of Conservation of Type Material:

Royal Ontario Museum, Toronto, Canada, M43771.
National Museum of Natural History, Washington, D.C., USA, 149606.

Geological Setting of Type Material:

In secondary seams ina complex, zoned pegmatite.

Associated Minerals at Type Locality:

Reference:

Roberts, Andrew C., Sturman, B. Darko, Dunn, P. J., and Roberts, Willard, L. (1989) Pararobertsite, Ca

2

Mn3+

3

(PO

4

)

3

)

2

.3H

2

), a New Mineral Species from the Tip Top Pegmatite, Custer County, South Dakota, and its Relationship to Robertsite. Canadian Mineralogist: 27: 451-455.

Synonyms of PararobertsiteHide

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Other Language Names for PararobertsiteHide

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Relationship of Pararobertsite to other SpeciesHide

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Structurally related to group(s):

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DH. Ferroberaunite Fe2+Fe3+5(PO4)4(OH)5 · 6H2O Mon. 2/m : _B_2/b
8.DH. Rowleyite [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] Iso.
8.DH. Ammoniotinsleyite (NH4)Al2(PO4)2(OH) · 2H2O Mon. 2/m : _P_21/m
8.DH. Thebaite-(NH4) (NH4)3Al(C2O4)(PO3OH)2(H2O) Mon. 2/m : _P_21/b
8.DH. Dendoraite-(NH4) (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 Mon. 2/m
8.DH. Whiteite-(MnMnMn) Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH. Whiteite-(CaMnFe) CaMnFe2Al2(PO4)4(OH)2 · 8H2O Mon. 2/m
8.DH. Hochleitnerite Mn2Ti3(PO4)4O2(H2O)2 · 14H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH. Regerite KFe6(PO4)4(OH)7(H2O)6 · 4H2O Mon. 2/m : _P_21/b
8.DH.05 Minyulite KAl2(PO4)2F · 4H2O Orth. m _m_2 : P b _a_2
8.DH.10 Leucophosphite KFe3+2(PO4)2(OH) · 2H2O Mon. 2/m : _P_21/b
8.DH.10 Spheniscidite (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O Mon. 2/m
8.DH.10 Tinsleyite KAl2(PO4)2(OH) · 2H2O Mon.
8.DH.15 Jahnsite-(CaMnFe) {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMnMg) {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMnMn) {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Keckite CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O Mon. 2/m : _P_2/b
8.DH.15 Rittmannite {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Whiteite-(CaFeMg) {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DH.15 Whiteite-(CaMnMg) {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m
8.DH.15 Whiteite-(MnFeMg) {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DH.15 Jahnsite-(MnMnMn) {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DH.15 Kaluginite (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O Orth.
8.DH.15 Jahnsite-(CaFeFe) {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon.
8.DH.15 Jahnsite-(NaFeMg) NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(NaMnMg) {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMgMg) {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O
8.DH.15 Whiteite-(CaMnMn) {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Whiteite-(MnMnMg) MnMnMg2Al2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(MnMnMg) Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaFeMg) CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(MnMnFe) Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Whiteite-(CaMgMg) CaMg3Al2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(MnMnZn) Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(NaMnMn) NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMnZn) CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.20 Lun'okite (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Manganosegelerite (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Overite CaMgAl(PO4)2(OH) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Segelerite Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P c c a
8.DH.20 Wilhelmvierlingite CaMnFe3+(PO4)2(OH) · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Juonniite CaMgSc(PO4)2(OH) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.25 Calcioferrite Ca2Fe3+2(PO4)3(OH) · 7H2O Mon. 2/m : _B_2/b
8.DH.25 Kingsmountite Ca3MnFeAl4(PO4)6(OH)4 · 12H2O Tric. 1 : _P_1
8.DH.25 Montgomeryite Ca4MgAl4(PO4)6(OH)4 · 12H2O Mon. 2 : _B_2
8.DH.25 Zodacite Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O Mon.
8.DH.25 Fanfaniite Ca4MnAl4(PO4)6(OH)4 · 12H2O Mon. 2/m : _B_2/b
8.DH.30 Arseniosiderite Ca2Fe3+3(AsO4)3O2 · 3H2O Mon. 2/m : _B_2/b
8.DH.30 Kolfanite Ca2Fe3+3O2(AsO4)3 · 2H2O Mon.
8.DH.30 Mitridatite Ca2Fe3+3(PO4)3O2 · 3H2O Mon. 2/m : _B_2/b
8.DH.30 Robertsite Ca2Mn3+3(PO4)3O2 · 3H2O Mon. m : B b
8.DH.30 Sailaufite (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O Mon. m : B m
8.DH.35 Mantienneite KMg2Al2Ti(PO4)4(OH)3 · 15H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.35 Paulkerrite K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O Mon. m
8.DH.35 Benyacarite (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.35 Hydroxylbenyacarite (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.35 Macraeite K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O Mon. 2/m : _P_21/b
8.DH.35 Sperlingite (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)] · 4H2O Mon. 2/m : _P_21/b
8.DH.40 Xanthoxenite Ca4Fe3+2(PO4)4(OH)2 · 3H2O Tric. 1 : _P_1
8.DH.45 Mahnertite NaCu3(AsO4)2Cl · 5H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
8.DH.50 Andyrobertsite KCdCu5(AsO4)4(H2AsO4) · 2H2O Mon. 2/m : _P_21/m
8.DH.50 Calcioandyrobertsite KCaCu5(AsO4)4(H2AsO4) · 2H2O Mon. 2/m : _P_21/m
8.DH.55 Englishite K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O Mon. 2/m
8.DH.60 Bouazzerite Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O Mon. 2/m
8.DH.65 Galliskiite Ca4Al2(PO4)2F8 · 5H2O Tric. 1 : _P_1
8.DH.70 Joteite Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O Tric. 1 : _P_1
8.DH.75 Kampelite Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.DH.80 Kapundaite NaCaFe4(PO4)4(OH)3 · 5H2O Tric. 1 : _P_1
8.DH.85 Vaniniite Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O Mon. 2/m : _P_21/b

Fluorescence of PararobertsiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for PararobertsiteHide

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Reference List:

Roberts, A. C., Sturman, B. D., Dunn, P. J., Roberts, W. L. (1989) Pararobertsite, Ca2Mn3+3(PO4)3O2·3H2O, a New Mineral Species from the Tip Top Pegmatite, Custer County, South Dakota, and its Relationship to Robertsite. The Canadian Mineralogist, 27 (3) 451-455

Localities for PararobertsiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Poland
Lower Silesian Voivodeship Dzierżoniów County Piława Górna DSS Piława Górna Quarry Julianna pegmatite ? Pieczka et al. (2015) +1 other reference
Ząbkowice Śląskie County Gmina Ząbkowice Śląskie Szklary Mt. Szklana Mine (Szklary pegmatite) ? Pieczka et al. (2015) +1 other reference
USA (TL)
South Dakota Custer County Custer Mining District Fourmile Tip Top Mine (TL) Roberts et al. (1989) +1 other reference