Betpakdalite-CaMg (original) (raw)

A valid IMA mineral species

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About Betpakdalite-CaMgHide

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Formula:

[Ca2(H2O)17Mg(H2O)6][Mo8As2Fe3+3O36(OH)]

Lustre:

Sub-Adamantine, Vitreous

Crystal System:

Monoclinic

Name:

First recognized as a potential hypothetical member of the betpakdalite group (IMA 10-E). In 2012 it was approved by IMA as a valid species.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:41944:4

924c28b4-6a69-4ae6-85eb-76bf4404e94b

IMA Classification of Betpakdalite-CaMgHide

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IMA Formula:

[Ca2(H2O)17Mg(H2O)6][Mo6+8As5+2Fe3+3O36(OH)]

Classification of Betpakdalite-CaMgHide

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8.DM.

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Bpd-CaMg IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Betpakdalite-CaMgHide

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Streak:

Colorless to very pale yellow

Fracture:

Irregular/Uneven

Density:

2.98(4) g/cm3 (Measured) 2.944 g/cm3 (Calculated)

Optical Data of Betpakdalite-CaMgHide

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RI values:

_n_α = 1.818(3) _n_β = 1.824(3) _n_γ = 1.846(3)

2V:

Measured: 55° (2), Calculated: 55.7°

δ = 0.028

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Pleochroism:

Non-pleochroic

Chemistry of Betpakdalite-CaMgHide

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Mindat Formula:

[Ca2(H2O)17Mg(H2O)6][Mo8As2Fe3+3O36(OH)]

Crystallography of Betpakdalite-CaMgHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 19.5336(7) Å, b = 11.0637(4) Å, c = 15.2559(11) Å
β = 131.528(9)°

Ratio:

a:b:c = 1.766 : 1 : 1.379

Morphology:

Pseudo-octaedra. Forms observed: {001}, {1-10} and [20-1}.

Twinning:

Uncommon. Contact twins on (001) by rotation of 120° about [102] and as pentetration twins by rotation of 120° about [102].

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
11.568 Å (25)
8.971 Å (100)
7.341 Å (34)
3.656 Å (33)
3.143 Å (26)
2.965 Å (44)
2.817 Å (35)
2.662 Å (31)

Geological EnvironmentHide

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Type Occurrence of Betpakdalite-CaMgHide

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General Appearance of Type Material:

Yellow pseudo-octaedra (up to ~1mm) included in and on scorodite

Place of Conservation of Type Material:

Natural History Museum of Los Angeles County, Los Angeles, California, USA, catalogue numbers 63327 and 63328

Associated Minerals at Type Locality:

Synonyms of Betpakdalite-CaMgHide

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Other Language Names for Betpakdalite-CaMgHide

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Relationship of Betpakdalite-CaMg to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DM. Betpakdalite-FeFe [Fe3+2 (H2O)15(OH)2Fe3+(H2O)6][Mo8As2Fe3+3O37] Mon. 2/m : _B_2/m
8.DM. Penriceite [Mg(H2O)6][Na(H2O)2Al3(PO4)2F6] · H2O Mon. 2/m : _P_21/b
8.DM. Elliottite NaMgAl3(PO4)2F6 · 9H2O Mon. 2/m : _B_2/m
8.DM. Sarrochite [Ca4(H2O)38][Mo8P2Fe3+3O37(OH)] Trig. 3_m_ _(_32/m ) : _P_3_m_1
8.DM. Tomsquarryite NaMgAl3(PO4)2(OH)6 · 8H2O Trig. 3_m_ _(_32/m ) : R_3_m
8.DM. Chinnerite [Mg(H2O)6]Na(H2O)2Al3(PO4)2F6 Mon. 2/m : _P_2/m
8.DM.05 Morinite NaCa2Al2(PO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.05 Esperanzaite NaCa2Al2(AsO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.10 Tyrolite Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O Mon. 2/m
8.DM.10 Tangdanite Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O Mon. 2/m : _B_2/b
8.DM.15 Betpakdalite-CaCa [Ca2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM.15 Melkovite [Ca2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM.15 Betpakdalite-NaCa [Na2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
8.DM.20 Phosphovanadylite-Ba Ba[V4+4P2O8(OH)8] · 12H2O Iso. 43_m_ : I_43_m
8.DM.20 Phosphovanadylite-Ca Ca[V4+4P2O12(OH)4] · 12H2O Iso. 43_m_ : I_43_m
8.DM.25 Yukonite Ca3Fe3+(AsO4)2(OH)3 · 5H2O Orth. m _m_2
8.DM.30 Uduminelite Ca3Al8(PO4)2O12 · 2H2O
8.DM.35 Aldermanite [Mg(H2O)6][Na(H2O)2Al3(PO4)2(OH,F)6] · H2O Mon. 2/m : _P_21/b
8.DM.35 Azovskite Fe3+3(PO4)(OH)6 or near
8.DM.35 Delvauxite CaFe4(PO4,SO4)2(OH)8 · 4-6H2O not confirmed Amor.
8.DM.40 Santafeite (Na,Ca,Sr)12(Mn2+,Fe3+,Al,Mg)8Mn4+8(VO4)16(OH,O)20 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DM.55 Tapiaite Ca5Al2(AsO4)4(OH)4 · 12H2O Mon.
8.DM.60 Alcantarillaite [Fe3+0.5(H2O)4][CaAs3+2(Fe3+2.5W6+0.5)(AsO4)2O7] Orth. m m m _(_2/_m_2/_m_2/m ) : I m m a

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Betpakdalite-CaMgHide

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Reference List:

Kampf, A. R., Mills, S. J., Rumsey, M. S., Dini, M., Birch, W. D., Spratt, J., Pluth, J. J., Steele, I. M., Jenkins, R. A., Pinch, W. W. (2012) The heteropolymolybdate family: structural relations, nomenclature scheme and new species. Mineralogical Magazine, 76 (5) 1175-1207 doi:10.1180/minmag.2012.076.5.09

Localities for Betpakdalite-CaMgHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Gough Co. Elsmore Elsmore Tin Mine (Elsmore Tin lodes) Rankin et al. (2002)
France
Nouvelle-Aquitaine Haute-Vienne Bellac Vaulry Vaulry Mines Christophe Boutry collection
Germany
Saxony Sächsische Schweiz-Osterzgebirge Dippoldiswalde Sadisdorf Färber (n.d.)
Italy
Lombardy Varese Province Cuasso al Monte Cuasso al Piano Bonomi Quarry Gentile et al. (2023)
Tuscany Livorno Province Livorno Valle Benedetta Via della Sambuca U-V occurrence Marco Bonifazi collection
Namibia (TL)
Oshikoto Region Tsumeb Tsumeb Mine (Ongopolo Mine) (TL) Williams et al. (2011) +1 other reference
Russia
Zabaykalsky Krai Nerchinsky District Adun-Cholon Range Sherlova Gora Kasatkin et al. (2014)
UK
England Cumbria Eden Mungrisdale Carrock Mine Rumsey (2022)