Phosphovanadylite-Ba (original) (raw)

A valid IMA mineral species

Formula:

Ba[V4+4P2O8(OH)8] · 12H2O

Name:

Named as phosphovanadylite after its composition of phosphate and the vanadyl (V4+O2)2- group. Renamed by IMA in August 2012 as phosphovanadylite-Ba.

This page provides mineralogical data about Phosphovanadylite-Ba.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:7234:8

35fe6965-daad-40e0-8192-2e093fe25750

IMA Classification of Phosphovanadylite-BaHide

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IMA status notes:

Renamed by the IMA

IMA Formula:

Ba[V4+4P2O12(OH)4] · 12H2O

Approval history:

1996: Approved as phosphovanadylite (IMA1996-037)
2012: Renamed as phosphovanadylite-Ba (IMA 12-A)

Type description reference:

Classification of Phosphovanadylite-BaHide

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8.DM.20

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1

42.13.15.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
13 : Miscellaneous

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Pvd-Ba IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Phosphovanadylite-BaHide

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Comment:

Greenish black on oxidation after long exposure to air

Streak:

Very pale greenish blue

Density:

2.16(3) g/cm3 (Measured) 2.13 g/cm3 (Calculated)

Optical Data of Phosphovanadylite-BaHide

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Birefringence:

Isotropic minerals have no birefringence

Chemistry of Phosphovanadylite-BaHide

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Mindat Formula:

Ba[V4+4P2O8(OH)8] · 12H2O

Crystallography of Phosphovanadylite-BaHide

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Class (H-M):

43_m_ - Hextetrahedral

Cell Parameters:

a = 15.470(4) Å

Unit Cell V:

3,702.29 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.164 Å (100)
2.582 Å (37)
2.445 Å (36)
7.73 Å (34)
10.8 Å (29)
2.738 Å (29)
2.827 Å (28)

Geological EnvironmentHide

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Type Occurrence of Phosphovanadylite-BaHide

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General Appearance of Type Material:

Geological Setting of Type Material:

organic-rich phosphatic mudstone.

Associated Minerals at Type Locality:

Reference:

Medrano, M. D., Evans, H. T., Jr., Wenk, H.-R. and Piper, D. Z. (1998): Phosphovanadylite: A new vanadium phosphate mineral with a zeolite-type structure. American Mineralogist: 83: 889-895.

Synonyms of Phosphovanadylite-BaHide

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Other Language Names for Phosphovanadylite-BaHide

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8.DM. Betpakdalite-CaMg [Ca2(H2O)17Mg(H2O)6][Mo8As2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM. Betpakdalite-FeFe [Fe3+2 (H2O)15(OH)2Fe3+(H2O)6][Mo8As2Fe3+3O37] Mon. 2/m : _B_2/m
8.DM. Penriceite [Mg(H2O)6][Na(H2O)2Al3(PO4)2F6] · H2O Mon. 2/m : _P_21/b
8.DM. Elliottite NaMgAl3(PO4)2F6 · 9H2O Mon. 2/m : _B_2/m
8.DM. Sarrochite [Ca4(H2O)38][Mo8P2Fe3+3O37(OH)] Trig. 3_m_ _(_32/m ) : _P_3_m_1
8.DM. Tomsquarryite NaMgAl3(PO4)2(OH)6 · 8H2O Trig. 3_m_ _(_32/m ) : R_3_m
8.DM. Chinnerite [Mg(H2O)6]Na(H2O)2Al3(PO4)2F6 Mon. 2/m : _P_2/m
8.DM.05 Morinite NaCa2Al2(PO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.05 Esperanzaite NaCa2Al2(AsO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.10 Tyrolite Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O Mon. 2/m
8.DM.10 Tangdanite Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O Mon. 2/m : _B_2/b
8.DM.15 Betpakdalite-CaCa [Ca2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM.15 Melkovite [Ca2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM.15 Betpakdalite-NaCa [Na2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
8.DM.20 Phosphovanadylite-Ca Ca[V4+4P2O12(OH)4] · 12H2O Iso. 43_m_ : I_43_m
8.DM.25 Yukonite Ca3Fe3+(AsO4)2(OH)3 · 5H2O Orth. m _m_2
8.DM.30 Uduminelite Ca3Al8(PO4)2O12 · 2H2O
8.DM.35 Aldermanite [Mg(H2O)6][Na(H2O)2Al3(PO4)2(OH,F)6] · H2O Mon. 2/m : _P_21/b
8.DM.35 Azovskite Fe3+3(PO4)(OH)6 or near
8.DM.35 Delvauxite CaFe4(PO4,SO4)2(OH)8 · 4-6H2O not confirmed Amor.
8.DM.40 Santafeite (Na,Ca,Sr)12(Mn2+,Fe3+,Al,Mg)8Mn4+8(VO4)16(OH,O)20 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DM.55 Tapiaite Ca5Al2(AsO4)4(OH)4 · 12H2O Mon.
8.DM.60 Alcantarillaite [Fe3+0.5(H2O)4][CaAs3+2(Fe3+2.5W6+0.5)(AsO4)2O7] Orth. m m m _(_2/_m_2/_m_2/m ) : I m m a

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Phosphovanadylite-BaHide

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Localities for Phosphovanadylite-BaHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

USA (TL)
Idaho Caribou County Blackfoot River Mining District Enoch Valley Mine (TL) American Mineralogist