Betpakdalite-CaCa (original) (raw)

A valid IMA mineral species

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About Betpakdalite-CaCaHide

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Formula:

[Ca2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O36(OH)]

Colour:

Lemon-yellow with greenish tint

Specific Gravity:

2.98 - 3.05

Crystal System:

Monoclinic

Name:

Named betpakdalite by L.P. Ermilova and V.M. Senderova in 1961 after the Betpakdala (Bet-Pak-Dal) Desert, Kazakhstan that includes the type locality.

It was redefined in 2010 (IMA 10-E) and renamed betpakdalite-CaCa.

This page provides mineralogical data about Betpakdalite-CaCa.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:651:4

0b07f472-53fa-4ea8-a801-22d2e942cf94

IMA Classification of Betpakdalite-CaCaHide

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IMA status notes:

Renamed by the IMA

Approval history:

Renamed by IMA: 2010

Classification of Betpakdalite-CaCaHide

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8.DM.15

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1

49.4.1.1

49 : HYDRATED MOLYBDATES AND TUNGSTATES
4 : Compound Molybdates and Tungstates

22.5.8

22 : Phosphates, Arsenates or Vanadates with other Anions
5 : Phosphates, arsenates or vanadates with chromate, molybdate, niobate or tantalate

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Bpd-CaCa IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Betpakdalite-CaCaHide

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Colour:

Lemon-yellow with greenish tint

Density:

2.98 - 3.05 g/cm3 (Measured) 2.913 g/cm3 (Calculated)

Optical Data of Betpakdalite-CaCaHide

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RI values:

_n_α = 1.782 - 1.809 _n_β = 1.797 - 1.821 _n_γ = 1.850 - 1.857

2V:

Measured: 60° , Calculated: 53° to 88°

δ = 0.068

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

extreme, inclined

Optical Extinction:

Y = b; X ∧ c = 12°.

Comments:

X = pale yellow, Y = greenish yellow, Z= bluish.

Comments:

Absorption: Z > Y > X.

Chemistry of Betpakdalite-CaCaHide

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Mindat Formula:

[Ca2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O36(OH)]

Crystallography of Betpakdalite-CaCaHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 19.507(2) Å, b = 11.0768(9) Å, c = 15.2618(19) Å
β = 131.2618(5)°

Ratio:

a:b:c = 1.761 : 1 : 1.378

Comment:

Cell parameters from SCXRD (Kampf et al 2012)

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0005591 Betpakdalite-CaCa Cooper M A, Hawthorne F C (1999) The crystal structure of betpakdalite, and a new chemical formula: {Mg(H2O)6}Ca2(H2O)13[Mo8As2Fe3O36(OH)](H2O)4 The Canadian Mineralogist 37 61-66 1999 0 293
0014792 Betpakdalite-CaCa Schmetzer K, Nuber B, Tremmel G (1984) Betpakdalite from Tsumeb, Namibia: mineralogy, crystal chemistry and structure Neues Jahrbuch fur Mineralogie, Monatshefte 1984 393-403 1984 Tsumeb, Namibia 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.75 Å (100)
3.63 Å (90)
1.532 Å (80)
1.480 Å (80)
2.95 Å (70)
1.723 Å (70)
1.191 Å (70)
1.024 Å (70)

Comments:

Kara-Oba deposit, Kazakhstan. Data from Ermilova and Senderova (1961).

Geological EnvironmentHide

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Type Occurrence of Betpakdalite-CaCaHide

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General Appearance of Type Material:

Powdery finely-crystalline aggregates, individual crystals being 0.005 to 0.025 mm.

Place of Conservation of Type Material:

No designated type material.

Geological Setting of Type Material:

Oxidation zone of a wolframite deposit, that consists of early quartz-wolframite-veins and later quartz-huebnerite-pyrite-arsenopyrite veins.

Associated Minerals at Type Locality:

Other Language Names for Betpakdalite-CaCaHide

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Relationship of Betpakdalite-CaCa to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DM. Betpakdalite-CaMg [Ca2(H2O)17Mg(H2O)6][Mo8As2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM. Betpakdalite-FeFe [Fe3+2 (H2O)15(OH)2Fe3+(H2O)6][Mo8As2Fe3+3O37] Mon. 2/m : _B_2/m
8.DM. Penriceite [Mg(H2O)6][Na(H2O)2Al3(PO4)2F6] · H2O Mon. 2/m : _P_21/b
8.DM. Elliottite NaMgAl3(PO4)2F6 · 9H2O Mon. 2/m : _B_2/m
8.DM. Sarrochite [Ca4(H2O)38][Mo8P2Fe3+3O37(OH)] Trig. 3_m_ _(_32/m ) : _P_3_m_1
8.DM. Tomsquarryite NaMgAl3(PO4)2(OH)6 · 8H2O Trig. 3_m_ _(_32/m ) : R_3_m
8.DM. Chinnerite [Mg(H2O)6]Na(H2O)2Al3(PO4)2F6 Mon. 2/m : _P_2/m
8.DM.05 Morinite NaCa2Al2(PO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.05 Esperanzaite NaCa2Al2(AsO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.10 Tyrolite Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O Mon. 2/m
8.DM.10 Tangdanite Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O Mon. 2/m : _B_2/b
8.DM.15 Melkovite [Ca2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM.15 Betpakdalite-NaCa [Na2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
8.DM.20 Phosphovanadylite-Ba Ba[V4+4P2O8(OH)8] · 12H2O Iso. 43_m_ : I_43_m
8.DM.20 Phosphovanadylite-Ca Ca[V4+4P2O12(OH)4] · 12H2O Iso. 43_m_ : I_43_m
8.DM.25 Yukonite Ca3Fe3+(AsO4)2(OH)3 · 5H2O Orth. m _m_2
8.DM.30 Uduminelite Ca3Al8(PO4)2O12 · 2H2O
8.DM.35 Aldermanite [Mg(H2O)6][Na(H2O)2Al3(PO4)2(OH,F)6] · H2O Mon. 2/m : _P_21/b
8.DM.35 Azovskite Fe3+3(PO4)(OH)6 or near
8.DM.35 Delvauxite CaFe4(PO4,SO4)2(OH)8 · 4-6H2O not confirmed Amor.
8.DM.40 Santafeite (Na,Ca,Sr)12(Mn2+,Fe3+,Al,Mg)8Mn4+8(VO4)16(OH,O)20 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DM.55 Tapiaite Ca5Al2(AsO4)4(OH)4 · 12H2O Mon.
8.DM.60 Alcantarillaite [Fe3+0.5(H2O)4][CaAs3+2(Fe3+2.5W6+0.5)(AsO4)2O7] Orth. m m m _(_2/_m_2/_m_2/m ) : I m m a

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Betpakdalite-CaCaHide

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Reference List:

Schmetzer, K., Nuber, B., Tremmel, G. (1984) Betpakdalit aus Tsumeb, Namibia: Mineralogie, Kristallchemie und Struktur. [Betpakdalite from Tsumeb, Namibia: mineralogy, crystal chemistry and structure.]. Neues Jahrbuch für Mineralogie, Monatshefte, 1984. 393-403

Dunn, Pete J., Ferraiolo, James A., Fleischer, Michael, Gobel, Volker, Grice, Joel D., Langley, Richard H., Shigley, James E., Vanko, David A., Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (11-12) 1329-1335

Kampf, A. R., Mills, S. J., Rumsey, M. S., Dini, M., Birch, W. D., Spratt, J., Pluth, J. J., Steele, I. M., Jenkins, R. A., Pinch, W. W. (2012) The heteropolymolybdate family: structural relations, nomenclature scheme and new species. Mineralogical Magazine, 76 (5) 1175-1207 doi:10.1180/minmag.2012.076.5.09

Localities for Betpakdalite-CaCaHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Gough Co. Elsmore Elsmore Tin Mine (Elsmore Tin lodes) Williams et al. (2005)
Chile
Atacama Copiapó Province Tierra Amarilla Pampa Larga mining district Descubridora mine analysed with Edx (by dr. Jochen Schlüter) +1 other reference
China
Hebei Zhangjiakou Guyuan County Guyuan U-Mo deposit (U-Mo deposit No. 460) Dahlkamp (2009)
Czech Republic
Karlovy Vary Region Sokolov District Krásno Huber stock (Huber shaft; Hub stock) Sejkora et al. (2006)
Ústí nad Labem Region Teplice District Krupka Knöttel area Quartz vein outcrops Sejkora (1998)
France
Nouvelle-Aquitaine Haute-Vienne Bellac Vaulry Celtic Age Mine Tschernich et al. (1992)
Vaulry Mines La Fosse Profonde (La Poudrière) Queneau (n.d.) +1 other reference
Germany
Saxony Sächsische Schweiz-Osterzgebirge Dippoldiswalde Sadisdorf Witzke (2023)
Greece
Attica East Attica Lavreotiki Lavrion Mining District Rieck et al. (2020)
Plaka Plaka mines Plaka Porphyry Deposit ("Porphyry Hill") Rieck et al. (2020)
Italy
Lombardy Varese Province Cuasso al Monte Cuasso al Piano Bonomi Quarry Gentile et al. (2023)
Tuscany Livorno Province Livorno Valle Benedetta Via della Sambuca U-V occurrence Marco Bonifazi collection
Japan
Hiroshima Prefecture Inland Sea (Setonaikai) Ikuchi Island Minamiikuchi mine The Mineral Species of Japan (5th ed)
Kazakhstan (TL)
Jambyl Region Moiynkum District Kara-Oba W deposit (TL) Ermilova et al. (1961) +1 other reference
Jetisu Region Alakol District Bota-Burum U deposit Pavel.M. Kartashov (n.d.)
Mongolia
Khentii Province Tsenkhermandal District Bayan Tsogto Mo-W deposit Kampf et al. (2012)
Namibia
Oshikoto Region Tsumeb Tsumeb Mine (Ongopolo Mine) Schmetzer
Norway
Nordland Hamarøy Drag Nedre Kvartsen Quarry Husdal (2011) +1 other reference
USA
Utah Tooele County Gold Hill Mining District (Clifton Mining District) Rustler Mine Kampf et al. (2012)