Alcantarillaite (original) (raw)

A valid IMA mineral species

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About AlcantarillaiteHide

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Formula:

[Fe3+0.5(H2O)4][CaAs3+2(Fe3+2.5W6+0.5)(AsO4)2O7]

Specific Gravity:

3.06 (Calculated)

Crystal System:

Orthorhombic

Name:

Named after the Alcantarilla mine, Spain, the type locality.

Structurally related to walentaite. Unique combination of elements.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:54031:9

75aeab39-b7c9-47ba-bd35-e572670bdd53

IMA Classification of AlcantarillaiteHide

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IMA Formula:

[Fe3+0.5(H2O)4][CaAs3+2(Fe3+2.5W6+0.5)(AsO4)2O7]

Type description reference:

Grey, I.E., Hochleitner, R., Rewitzer, C., Riboldi-Tunnicliffe, A., Kampf, A.R., MacRae, C.M., Mumme, W.G., Kaliwoda, M., Friis, H., Martin, C.U. (2020) The walentaite group and the description of a new member, alcantarillaite, from the Alcantarilla mine, Belalcázar, Córdoba, Andalusia, Spain. Mineralogical Magazine: 84: 412-419.

Classification of AlcantarillaiteHide

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8.DM.60

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Alc IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AlcantarillaiteHide

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Fracture:

Irregular/Uneven

Density:

3.06 g/cm3 (Calculated)

Comment:

Calculated based on the empirical formula and single-crystal X-ray diffraction

Optical Data of AlcantarillaiteHide

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RI values:

_n_α = 1.703 _n_β = 1.800(5) _n_γ = 1.850(5)

δ = 0.147

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

r > v, moderate

Comments:

α calculated
X = a, Y = c and Z = b

Chemistry of AlcantarillaiteHide

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Mindat Formula:

[Fe3+0.5(H2O)4][CaAs3+2(Fe3+2.5W6+0.5)(AsO4)2O7]

Crystallography of AlcantarillaiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 24.038(8) Å, b = 7.444(3) Å, c = 10.387(3) Å

Ratio:

a:b:c = 3.229 : 1 : 1.395

Unit Cell V:

1,858.64 ų (Calculated from Unit Cell)

Morphology:

Ultrathin elongated blades, with lengths up to 0.1 mm and thicknesses of only 1–2 μm. The crystals are generally curved and show sub-parallel
lamellae.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
12.02 Å (100)
6.343 Å (23)
6.025 Å (27)
4.257 Å (17)
3.148 Å (12)
3.016 Å (38)
2.927 Å (11)

Geological EnvironmentHide

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Type Occurrence of AlcantarillaiteHide

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General Appearance of Type Material:

lemon-yellow fillings together with massive scorodite in fissures and cracks in quartz adjacent to löllingite. It is also found as tiny yellow rosettes lining vugs and as spheroids of ultrathin blades.

Place of Conservation of Type Material:

collections of the (1) Mineralogical State Collection, Theresienstrasse 41, 80333 München, Germany, collection number MSM37182 (holotype); (2) Natural History Museum, University of Oslo, PO Box 1172, Blindern, 0318 Oslo, Norway, collection number KNR44147 (holotype); (3) Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue number 73568 (cotype)

Associated Minerals at Type Locality:

Reference:

Grey, I.E., Hochleitner, R., Rewitzer, C., Riboldi-Tunnicliffe, A., Kampf, A.R., MacRae, C.M., Mumme, W.G., Kaliwoda, M., Friis, H., Martin, C.U. (2020) The walentaite group and the description of a new member, alcantarillaite, from the Alcantarilla mine, Belalcázar, Córdoba, Andalusia, Spain. Mineralogical Magazine: 84: 412-419.

Other Language Names for AlcantarillaiteHide

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8.DM. Betpakdalite-CaMg [Ca2(H2O)17Mg(H2O)6][Mo8As2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM. Betpakdalite-FeFe [Fe3+2 (H2O)15(OH)2Fe3+(H2O)6][Mo8As2Fe3+3O37] Mon. 2/m : _B_2/m
8.DM. Penriceite [Mg(H2O)6][Na(H2O)2Al3(PO4)2F6] · H2O Mon. 2/m : _P_21/b
8.DM. Elliottite NaMgAl3(PO4)2F6 · 9H2O Mon. 2/m : _B_2/m
8.DM. Sarrochite [Ca4(H2O)38][Mo8P2Fe3+3O37(OH)] Trig. 3_m_ _(_32/m ) : _P_3_m_1
8.DM. Tomsquarryite NaMgAl3(PO4)2(OH)6 · 8H2O Trig. 3_m_ _(_32/m ) : R_3_m
8.DM. Chinnerite [Mg(H2O)6]Na(H2O)2Al3(PO4)2F6 Mon. 2/m : _P_2/m
8.DM.05 Morinite NaCa2Al2(PO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.05 Esperanzaite NaCa2Al2(AsO4)2(OH)F4 · 2H2O Mon. 2/m : _P_21/m
8.DM.10 Tyrolite Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O Mon. 2/m
8.DM.10 Tangdanite Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O Mon. 2/m : _B_2/b
8.DM.15 Betpakdalite-CaCa [Ca2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM.15 Melkovite [Ca2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O36(OH)] Mon. 2/m : _B_2/m
8.DM.15 Betpakdalite-NaCa [Na2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
8.DM.20 Phosphovanadylite-Ba Ba[V4+4P2O8(OH)8] · 12H2O Iso. 43_m_ : I_43_m
8.DM.20 Phosphovanadylite-Ca Ca[V4+4P2O12(OH)4] · 12H2O Iso. 43_m_ : I_43_m
8.DM.25 Yukonite Ca3Fe3+(AsO4)2(OH)3 · 5H2O Orth. m _m_2
8.DM.30 Uduminelite Ca3Al8(PO4)2O12 · 2H2O
8.DM.35 Aldermanite [Mg(H2O)6][Na(H2O)2Al3(PO4)2(OH,F)6] · H2O Mon. 2/m : _P_21/b
8.DM.35 Azovskite Fe3+3(PO4)(OH)6 or near
8.DM.35 Delvauxite CaFe4(PO4,SO4)2(OH)8 · 4-6H2O not confirmed Amor.
8.DM.40 Santafeite (Na,Ca,Sr)12(Mn2+,Fe3+,Al,Mg)8Mn4+8(VO4)16(OH,O)20 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DM.55 Tapiaite Ca5Al2(AsO4)4(OH)4 · 12H2O Mon.

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for AlcantarillaiteHide

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Reference List:

Grey, I.E., Hochleitner, R., Rewitzer, C., Riboldi-Tunnicliffe, A., Kampf, A.R., MacRae, C.M., Mumme, W.G., Kaliwoda, M., Friis, H., Utrera Martin, C. (2020) The walentaite group and the description of a new member, alcantarillaite, from the Alcantarilla mine, Belalcázar, Córdoba, Andalusia, Spain. Mineralogical Magazine: 84: 412-419.

Grey, I.E., Hochleitner, R., Rewitzer, C., Riboldi-Tunnicliffe, A., Kampf, A.R., MacRae, C.M., Mumme, W.G., Kaliwoda, M., Friis, H., Martin, C.U. (2020) The walentaite group and the description of a new member, alcantarillaite, from the Alcantarilla mine, Belalcázar, Córdoba, Andalusia, Spain. Mineralogical Magazine: 84: 412-419.

Localities for AlcantarillaiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Spain (TL)
Andalusia Córdoba Belalcázar Alcantarilla mine (TL) Miyawaki et al. (2019) +2 other references