Ferraioloite (original) (raw)

A valid IMA mineral species

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About FerraioloiteHide

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Formula:

MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20

Crystal System:

Monoclinic

Name:

The species is named in honour of the late James (Jim) Anthony Ferraiolo (May 14, 1947-February 6, 2014). The mineral is pronounced /fe..(r) i: ‘Ou lOu ait/. Jim worked as scientific assistant at the American Museum of Natural History (AMNH) from April 1978 until August 1982 and also as transaction coordinator at the Smithsonian Institution’s Museum of Natural History from September 1982 until April 1985. He was best known for his publication A Systematic Classification of Nonsilicate Minerals (Bulletin 172 of the AMNH, 1982), which was widely used in Museum collections, as a basis for collection classification and organisation (e.g. Museums Victoria, Australia). Recently, Jim was a member of the IMA CNMNC subcommittee for mineral group nomenclature and the subcommittee on unnamed minerals. Jim also spent more than a decade as a manager with mindat.org and was instrumental in publishing the description of ferrolaueite (Ferraiolo, 2012; Segeler et al., 2012).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:46878:7

8e433b53-acce-4fdb-b09a-69699c4b4cc5

IMA Classification of FerraioloiteHide

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IMA Formula:

MgMn2+4(Fe2+0.5Al0.5)4Zn4(PO4)8(OH)4(H2O)20

Type description reference:

Mills, Stuart J., Grey, Ian E., Kampf, Anthony R., MaCrae, Colin M., Smith, Jason B., Davidson, Cameron J., Glenn, A. Matt (2016) Ferraioloite, MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20, a new secondary phosphate mineral from the Foote mine, USA. European Journal of Mineralogy, 28 (3) 655-661 doi:10.1127/ejm/2016/0028-2525

Classification of FerraioloiteHide

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8.CF.

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
F : With large and medium-sized cations, RO4:H2O > 1:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Frl IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Optical Data of FerraioloiteHide

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RI values:

_n_α = 1.575 _n_β = 1.583(5) _n_γ = 1.584(5)

2V:

Measured: 40° , Calculated: 40°

δ = 0.008

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

colourless (X, Z), blue grey (Y)

Chemistry of FerraioloiteHide

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Mindat Formula:

MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20

Crystallography of FerraioloiteHide

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Crystal System:

Monoclinic

Cell Parameters:

a = 25.333(3) Å, b = 6.299(1) Å, c = 15.161(3) Å
β = 90.93(3)°

Ratio:

a:b:c = 4.022 : 1 : 2.407

Morphology:

platelets, blades

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
12.7 Å (100)
4.78 Å (4)
4.22 Å (4)
3.580 Å (4)
3.499 Å (5)
3.245 Å (7)
2.924 Å (8)
2.869 Å (5)

Geological EnvironmentHide

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Type Occurrence of FerraioloiteHide

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General Appearance of Type Material:

platelets and blades up to ca. 0.2 mm long and a few μm thick

Place of Conservation of Type Material:

Cotype material is deposited in the mineralogical collections of the Museum Victoria, Melbourne, Australia, registration numbers M53492 and M53493, and the Natural History Museum of Los Angeles County, Los Angeles, California,USA, catalogue numbers 65593

Geological Setting of Type Material:

vugs in a thin sugary fine-grained pegmatite seam

Associated Minerals at Type Locality:

Reference:

Mills, S.J., Grey, I.E., Kampf, A.R., Macrae, C.M., Smith, J.B., Davidson, C.J. and Glenn, A.M. (2016) Ferraioloite, a new secondary phosphate mineral from the Foote mine, USA. European Journal of Mineralogy, 28(3), 655‒661.

Synonyms of FerraioloiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.CF. Naalasite NaAl(AsO3OH)2 · H2O Trig. 32 : _R_32
8.CF. Falsterite Ca2MgMn2+2Fe2+2Fe3+2Zn4(PO4)8(OH)4(H2O)14 Mon. 2/m : _P_21/b
8.CF. Espadaite Na4Ca3Mg2[AsO3(OH)]2[AsO2(OH)2]10 · 7H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C c c a
8.CF. Liraite NaCa2Mn2+2[Fe3+Fe2+]Mn2+2(PO4)6(H2O)2 Orth. m _m_2
8.CF. Nafeasite Na3Fe3+3(AsO3OH)6 · 3H2O Mon. 2 : _B_2
8.CF.05 Grischunite NaCa2Mn2+5Fe3+(AsO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.CF.05 Wicksite NaCa2(Fe2+,Mn2+)4MgFe3+(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.CF.05 Bederite Ca2(Mn2+)4(Fe3+)2(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.CF.05 Tassieite (Na,◻)Ca2(Mg,Fe2+,Fe3+)2(Fe2+,Mg)2(Fe3+,Mg)2(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.CF.05 Maneckiite (Na◻)Ca2Fe2+2(Fe3+Mg)Mn2(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.CF.10 Haigerachite KFe3+3(PO3OH)2[PO2(OH)2]6 · 4H2O Mon. 2/m : _B_2/b
8.CF.10 Yazganite NaFe3+2(Mg,Mn2+)(AsO4)3 · H2O Mon. 2/m : _B_2/b
8.CF.15 Currierite Na4Ca3MgAl4(AsO3OH)12 · 9H2O Hex. 622 : _P_622
8.CF.20 Ríosecoite Ca2Mg(AsO3OH)3(H2O)2 Tric. 1 : _P_1

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for FerraioloiteHide

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Reference List:

Mills, Stuart J., Grey, Ian E., Kampf, Anthony R., MaCrae, Colin M., Smith, Jason B., Davidson, Cameron J., Glenn, A. Matt (2016) Ferraioloite, MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20, a new secondary phosphate mineral from the Foote mine, USA. European Journal of Mineralogy, 28 (3) 655-661 doi:10.1127/ejm/2016/0028-2525

Localities for FerraioloiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Portugal
Guarda Gouveia Folgosinho Sítio do Castelo Mine Ferraioloite from the Sítio do Castelo mine (Guarda, Portugal) +3 other references
USA (TL)
North Carolina Cleveland County Kings Mountain Foote Lithium Co. Mine (TL) Mills et al. (2016)