Haigerachite (original) (raw)

A valid IMA mineral species

Formula:

KFe3+3(PO3OH)2[PO2(OH)2]6 · 4H2O

Crystal System:

Monoclinic

Name:

Named for the village and valley near the locality.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:6985:0

24b3e966-c05d-4715-b53a-164f40ca0fd2

IMA Classification of HaigerachiteHide

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IMA Formula:

KFe3+3(H2PO4)6(HPO4)2 · 4H2O

Type description reference:

Classification of HaigerachiteHide

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8.CF.10

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
F : With large and medium-sized cations, RO4:H2O > 1:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Hga IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HaigerachiteHide

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Transparency:

Transparent, Translucent

Cleavage:

Distinct/Good
{001}

Fracture:

Irregular/Uneven

Density:

2.44(1) g/cm3 (Measured) 2.445 g/cm3 (Calculated)

Optical Data of HaigerachiteHide

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RI values:

_n_α = 1.557(2) _n_β = 1.598(2) _n_γ = 1.602(2)

2V:

Measured: 32° (2), Calculated: 34°

δ = 0.045

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

relatively weak

Comments:

X perpendicular to (001)

Chemistry of HaigerachiteHide

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Mindat Formula:

KFe3+3(PO3OH)2[PO2(OH)2]6 · 4H2O

Crystallography of HaigerachiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 16.95(3) Å, b = 9.59(2) Å, c = 17.57(3) Å
β = 90.85°

Ratio:

a:b:c = 1.767 : 1 : 1.832

Unit Cell V:

2,855.70 ų (Calculated from Unit Cell)

Morphology:

Thin tabular, pseudohexagonal crystals flattened (001), showing {100} and {110}.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.83 Å (100)
3.75 Å (100)
3.23 Å (50)
3.02 Å (90)

Geological EnvironmentHide

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Type Occurrence of HaigerachiteHide

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General Appearance of Type Material:

White spherules, to 0.2 mm across, consisting of scaly crystals to 0.05 mm; rarely as well-developed, thin tabular, pseudohexagonal crystals.

Place of Conservation of Type Material:

  1. Institute of Mineralogy and Crystal Chemistry, University of Stuttgart, Germany.
  2. Staatlichen Museum für Naturkunde, Stuttgart, Germany.

Geological Setting of Type Material:

Secondary phosphate formed on dump material.

Associated Minerals at Type Locality:

Reference:

Walenta, K., Theye, Th. (1999) Haigerachit, ein neues Phosphatmineral von der Grube Silberbrünnle bei Gengenbach im mittleren Schwarzwald. Aufschluss: 50: 1-7.

Synonyms of HaigerachiteHide

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Other Language Names for HaigerachiteHide

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8.CF. Naalasite NaAl(AsO3OH)2 · H2O Trig. 32 : _R_32
8.CF. Falsterite Ca2MgMn2+2Fe2+2Fe3+2Zn4(PO4)8(OH)4(H2O)14 Mon. 2/m : _P_21/b
8.CF. Ferraioloite MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20 Mon.
8.CF. Espadaite Na4Ca3Mg2[AsO3(OH)]2[AsO2(OH)2]10 · 7H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C c c a
8.CF. Liraite NaCa2Mn2+2[Fe3+Fe2+]Mn2+2(PO4)6(H2O)2 Orth. m _m_2
8.CF. Nafeasite Na3Fe3+3(AsO3OH)6 · 3H2O Mon. 2 : _B_2
8.CF.05 Grischunite NaCa2Mn2+5Fe3+(AsO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.CF.05 Wicksite NaCa2(Fe2+,Mn2+)4MgFe3+(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.CF.05 Bederite Ca2(Mn2+)4(Fe3+)2(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.CF.05 Tassieite (Na,◻)Ca2(Mg,Fe2+,Fe3+)2(Fe2+,Mg)2(Fe3+,Mg)2(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.CF.05 Maneckiite (Na◻)Ca2Fe2+2(Fe3+Mg)Mn2(PO4)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.CF.10 Yazganite NaFe3+2(Mg,Mn2+)(AsO4)3 · H2O Mon. 2/m : _B_2/b
8.CF.15 Currierite Na4Ca3MgAl4(AsO3OH)12 · 9H2O Hex. 622 : _P_622
8.CF.20 Ríosecoite Ca2Mg(AsO3OH)3(H2O)2 Tric. 1 : _P_1

Other InformationHide

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Notes:

Soluble in dilute HCl or HNO3.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for HaigerachiteHide

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Localities for HaigerachiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany (TL)
Baden-Württemberg Freiburg Region Ortenaukreis Gengenbach Gengenbach Silberbrünnle Mine (TL) [Wittern (1995) +1 other reference