| dbo:abstract |
Komplexy kovů s fosfiny jsou komplexní sloučeniny obsahující jeden nebo více fosfinových ligandů. Využití nacházejí v homogenní katalýze. K významným zástupcům těchto sloučenin patří Wilkinsonův katalyzátor (Rh(PPh3)3Cl), Grubbsovy katalyzátory a tetrakis(trifenylfosfin)palladium. Wilkinsonův katalyzátor, používaný ke katalýze hydrogenací (cs) A metal-phosphine complex is a In coordination complex containing one or more phosphine ligands. Almost always, the phosphine is an organophosphine of the type R3P (R = alkyl, aryl). Metal phosphine complexes are useful in homogeneous catalysis. Prominent examples of metal phosphine complexes include Wilkinson's catalyst (Rh(PPh3)3Cl), Grubbs' catalyst, and tetrakis(triphenylphosphine)palladium(0). (en) 膦配合物是指配体为膦（PR3，R为有机基团）的配位化合物，这类化合物和相应的氨配合物有差别，膦配合物的亲脂能力更强，并表现出在有机溶剂中较好的溶解度。它们可以和具有不同氧化数的金属配位，其配合物在中有所应用。常见的膦配合物包括氯化三(三苯基膦)铑(I)、格拉布试剂和四(三苯基膦)钯。 (zh) |
| dbo:thumbnail |
wiki-commons:Special:FilePath/Wilkinson's-catalyst-2D.png?width=300 |
| dbo:wikiPageID |
34732976 (xsd:integer) |
| dbo:wikiPageLength |
13374 (xsd:nonNegativeInteger) |
| dbo:wikiPageRevisionID |
1112888702 (xsd:integer) |
| dbo:wikiPageWikiLink |
dbr:Carbon_monoxide dbr:Metal_ammine_complex dbr:Bis(triphenylphosphine)iron_tricarbonyl dbr:Bis(triphenylphosphine)palladium_chloride dbr:Alkyne dbr:Hydroformylation dbr:Vaska's_complex dbr:Electronegative dbr:Noyori_asymmetric_hydrogenation dbr:(Triphenylphosphine)iron_tetracarbonyl dbr:1,1'-Bis(diphenylphosphino)ferrocene dbr:1,2-bis(diphenylphosphino)ethane dbc:Coordination_complexes dbr:Chemical_Reviews dbr:Oligomer dbr:Trans-spanning_ligand dbr:Coordination_complex dbr:Organophosphine dbr:Lipophilic dbr:Stryker's_reagent dbr:Organic_synthesis dbr:Tolman_electronic_parameter dbr:Triethyl_phosphite dbr:Trimethylphosphine dbr:Triphenylphosphine dbr:Walter_Reppe dbr:Wilkinson's_catalyst dbr:Alcohol_(chemistry) dbr:D_orbital dbr:Nickel(II)_bromide dbc:Phosphanes dbr:Heck_reaction dbr:Tetrakis(triphenylphosphine)palladium(0) dbr:Hydrocyanation dbr:Arsine dbc:Catalysis dbr:Homogeneous_catalysis dbr:Tolman_cone_angle dbr:Dichloro(1,3-bis(diphenylphosphino)propane)nickel dbr:Dichlorobis(triphenylphosphine)nickel(II) dbr:Phosphorus_trichloride dbr:Phosphorus_trifluoride dbr:Grubbs'_catalyst dbr:Tertiary_amine dbr:Kumada_coupling dbr:Asymmetric_catalysis dbr:Organic_solvent dbr:Reagent dbr:Xantphos dbr:L-type_ligand dbr:Transition_metal_hydride dbr:Spanphos dbr:Solubility dbr:Phosphinite dbr:Phosphonite dbr:Oxidative_addition dbr:Substituent dbr:Palladium_chloride dbr:Phosphorus_NMR dbr:Diphosphine dbr:Chelate_effect dbr:Pi_acidity dbr:Pincer_complex dbr:Anti-bonding_orbital dbr:Bis(triphenylphosphine)palladium(II)_chloride dbr:Carbonyl_ligand dbr:Steric dbr:Trifluorophosphine dbr:Spin_triplet dbr:File:ConeAng.png dbr:File:TPPTS.png dbr:File:Wilkinson's-catalyst-2D.png |
| dbp:wikiPageUsesTemplate |
dbt:Main dbt:Mvar dbt:Nbsp dbt:Reflist dbt:See_also dbt:Coordination_complexes |
| dct:subject |
dbc:Coordination_complexes dbc:Phosphanes dbc:Catalysis |
| rdf:type |
owl:Thing |
| rdfs:comment |
Komplexy kovů s fosfiny jsou komplexní sloučeniny obsahující jeden nebo více fosfinových ligandů. Využití nacházejí v homogenní katalýze. K významným zástupcům těchto sloučenin patří Wilkinsonův katalyzátor (Rh(PPh3)3Cl), Grubbsovy katalyzátory a tetrakis(trifenylfosfin)palladium. Wilkinsonův katalyzátor, používaný ke katalýze hydrogenací (cs) A metal-phosphine complex is a In coordination complex containing one or more phosphine ligands. Almost always, the phosphine is an organophosphine of the type R3P (R = alkyl, aryl). Metal phosphine complexes are useful in homogeneous catalysis. Prominent examples of metal phosphine complexes include Wilkinson's catalyst (Rh(PPh3)3Cl), Grubbs' catalyst, and tetrakis(triphenylphosphine)palladium(0). (en) 膦配合物是指配体为膦（PR3，R为有机基团）的配位化合物，这类化合物和相应的氨配合物有差别，膦配合物的亲脂能力更强，并表现出在有机溶剂中较好的溶解度。它们可以和具有不同氧化数的金属配位，其配合物在中有所应用。常见的膦配合物包括氯化三(三苯基膦)铑(I)、格拉布试剂和四(三苯基膦)钯。 (zh) |
| rdfs:label |
Komplexy kovů s fosfiny (cs) Metal-phosphine complex (en) 膦配合物 (zh) |
| rdfs:seeAlso |
dbr:Π-backbonding |
| owl:sameAs |
wikidata:Metal-phosphine complex dbpedia-cs:Metal-phosphine complex dbpedia-zh:Metal-phosphine complex https://global.dbpedia.org/id/4rnLr |
| prov:wasDerivedFrom |
wikipedia-en:Metal-phosphine_complex?oldid=1112888702&ns=0 |
| foaf:depiction |
wiki-commons:Special:FilePath/Wilkinson's-catalyst-2D.png wiki-commons:Special:FilePath/TPPTS.png wiki-commons:Special:FilePath/Connelly-Orpen-R3P-M-pi-backbonding.png wiki-commons:Special:FilePath/Connelly-Orpen-R3P-M-sigma-bonding.png wiki-commons:Special:FilePath/ConeAng.png |
| foaf:isPrimaryTopicOf |
wikipedia-en:Metal-phosphine_complex |
| is dbo:wikiPageRedirects of |
dbr:Metal_phosphine_complexes dbr:Metal_phosphine_complex dbr:Transition_metal_phosphine_complex dbr:Transition_metal_phosphine_complexes dbr:Phos_ligand dbr:Phosphane_ligand dbr:Phosphine_ligand |
| is dbo:wikiPageWikiLink of |
dbr:Ligand_cone_angle dbr:Metal_phosphine_complexes dbr:Metal_phosphine_complex dbr:Transition_metal_phosphine_complex dbr:Transition_metal_phosphine_complexes dbr:Phos_ligand dbr:Phosphane_ligand dbr:Phosphine_ligand |
| is foaf:primaryTopic of |
wikipedia-en:Metal-phosphine_complex |
