Transition-Metal Oxides Research Papers - Academia.edu (original) (raw)

Swelling mica exhibits unique characteristics for purification of drinking water contaminated by heavy metals and for selective removal of Sr2+ and Ba2+ ions from nuclear waste solution. As a new approach to recycle fly ash, conversion of... more

Swelling mica exhibits unique characteristics for purification of drinking water contaminated by heavy metals and for selective removal of Sr2+ and Ba2+ ions from nuclear waste solution. As a new approach to recycle fly ash, conversion of fly ash to swelling mica has been attempted and ion-exchange properties of fly ash-derived swelling mica (referred to hereinafter as FA-swelling mica) were

The synthesis and characterization of some new terphenyl ligands, modified by meta alkyl substitution on the central ring are described. The new ligands were designed for potential applications in the stabilization of novel low valent... more

The synthesis and characterization of some new terphenyl ligands, modified by meta alkyl substitution on the central ring are described. The new ligands were designed for potential applications in the stabilization of novel low valent main group species or transition metal heteronuclear multiply bonded compounds. Compounds 1-I-C6H1-2,6-Ph2-3,5-Pr2i (1), 1-I-C6H1-2,6-Mes2-3,5-Pr2i (3) (Mes=2,4,6-trimethylphenyl), 1-I-C6H1-2,6-Trip2-3,5-Pr2i (5) (Trip=2,4,6-triisopropylphenyl) and 1-I-C6H1-2,6-Dipp2-3,5-Pr2i (6) (Dipp=2,6-diisopropylphenyl) were obtained

The synthesis and characterization of some dioxouranium(VI) complexes containing potential ONS donor ligands derived from benzoyl,o-chloro-,o-methyl-,P-chloro-,p-nitro-,p-methoxy-,p-aminobenzoylhydrazines and isonicotinylhydrazine with... more

The synthesis and characterization of some dioxouranium(VI) complexes containing potential ONS donor ligands derived from benzoyl,o-chloro-,o-methyl-,P-chloro-,p-nitro-,p-methoxy-,p-aminobenzoylhydrazines and isonicotinylhydrazine with phenyl isothiocyanate are reported. Two types of complexes with general formulae [UO2(HL)2(X)2] and [[UO2(HL)2] have been identified and characterized. All the uranyl complexes are of the [UO2(HL)2(X)2] type (HL=bidentate monoanionic ligand, X=H2O and/or EtOH) and X bridges the uranyl ion and the thioketo groupvia hydrogen bonding. Upon heating to 140 °C, the complexes lose X giving a new complex of formula [UO2(HL)2] (HL=tridentate monoanionic ligand) in which the thioketo-group participates in bonding. The latter complexes take up X again on exposure to water and/or ethanol vapour.

Exposure of superalloy surfaces to jet fuel at elevated temperatures leads to the formation of carbonaceous deposits and metal sulfides. The formation of stable oxide layers on alloy surfaces can reduce the activity of the constituent... more

Exposure of superalloy surfaces to jet fuel at elevated temperatures leads to the formation of carbonaceous deposits and metal sulfides. The formation of stable oxide layers on alloy surfaces can reduce the activity of the constituent transition metals that catalyze the dehydrogenation of hydrocarbons and the subsequent carbon deposit growth. The metals Ni, Cr, Fe, Mn, Al, Ti and Nb + Ta

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full... more

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

RESUMEN El óxido y el hidróxido del escandio son compuestos de escaso interés desde el punto de vista de las enseñanzas medias. El Sc (III) no posee electrones d, por lo que sus compuestos son de color blanco,algo decepcionante si lo... more

RESUMEN El óxido y el hidróxido del escandio son compuestos de escaso interés desde el punto de vista de las enseñanzas medias. El Sc (III) no posee electrones d, por lo que sus compuestos son de color blanco,algo decepcionante si lo comparamos con los del resto de los derivados de los metales de transición A pesar de ello, veremos cómo podemos encontrar algunas reacciones de atractivo académico para el alumnado, como el carácter anfótero de los compuestos o la particular estructura gelatinosa del hidróxido. Palabras clave: Óxido de escandio; Hidróxido de escandio. ABSTRACT Scandium oxide and hydroxide are not interesting compounds regarding middle school views. Sc (III) is the only ion, and it hasn't d-electrons, so its compounds are white, a disappointing fact if compared with any of the transition metals ones. Instead of this, we'll show that scandium oxide and hydroxide present some reactions of pedagogic significance, such as the amphoteric character or the gelatinous structure of the hydroxide.

Sodium borate glasses containing iron and molybdenum ions with the total concentration of transition ions constant and gradual substitution of sodium oxide (network modifier) by borate oxide (network former) was prepared. Densities, molar... more

Sodium borate glasses containing iron and molybdenum ions with the total concentration of transition ions constant and gradual substitution of sodium oxide (network modifier) by borate oxide (network former) was prepared. Densities, molar volume, DC and AC conductivities are measured. The trends of these properties are attributed to changes in the glass network structure. Their DC and AC conductivity increased with increasing NaO concentration. The increase of AC conductivity of sodium borate glasses is attributed to the chemical composition and the hopping mechanism of conduction. Measurements of the dielectric constant (ε) and dielectric loss (tan δ) as a function of frequency (50 Hz–100 kHz) and temperature (RT—600 K) indicate that the increase in dielectric constant and loss (ε and tan δ) values with increasing sodium ion content could be attributed to the assumption that Fe and Mo ions tend to assume network-forming position in the glass compositions studied.The variation of the value of frequency exponent s for all glass samples as the function of temperature at a definite frequency indicates that the value of s decreases with increasing the temperature which agrees with the correlated barrier-hopping (CBH) model.