Ferroalluaudite (original) (raw)

A valid IMA mineral species - grandfathered

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About FerroalluauditeHide

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Formula:

(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3

Colour:

Straw-yellow to brownish yellow, green, greenish black; yellow to yellow-green in transmitted light.

Specific Gravity:

3.4 - 3.5

Crystal System:

Monoclinic

Name:

In allusion to the composition, containing dominant iron (Latin = FERRum) and Alluaudite in allusion to its relationship to that species.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1507:9

c70aacab-2de0-4f02-9d69-1b83d2e0ea54

IMA Classification of FerroalluauditeHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

NaFe2+Fe3+2(PO4)3

Classification of FerroalluauditeHide

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8.AC.10

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations

38.2.3.5

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3

19.12.29

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Fald IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Fal The Canadian Mineralogist (2019) The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of FerroalluauditeHide

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Colour:

Straw-yellow to brownish yellow, green, greenish black; yellow to yellow-green in transmitted light.

Cleavage:

Distinct/Good
On {100} and {010}, good.

Density:

3.4 - 3.5 g/cm3 (Measured) 3.67 g/cm3 (Calculated)

Optical Data of FerroalluauditeHide

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RI values:

_n_α = 1.727 _n_γ = 1.738

δ = 0.011

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

relatively strong

Comments:

X = dull green to pale blue; Y = Z = bright green with a bluish tinge.

Chemistry of FerroalluauditeHide

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Mindat Formula:

(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3

Crystallography of FerroalluauditeHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 11.898(2) Å, b = 12.541(2) Å, c = 6.434(1) Å
β = 114.1°

Ratio:

a:b:c = 0.949 : 1 : 0.513

Unit Cell V:

876.35 ų (Calculated from Unit Cell)

Morphology:

Massive; compact granular; radiating fibrous or globular aggregates.

Comment:

space group by analogy to alluaudite

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012695 Ferroalluaudite Corbin D R, Whitney J F, Fultz W C, Stucky G D, Eddy M M, Cheetham A K (1986) Synthesis of open-framework transition-metal phosphates using organometallic precursors in acidic media. Preparation and structural characterization of Fe5P4O20H10 and NaFe3P3O12 Inorganic Chemistry 25 2279-2280 1986 0 293

CIF Raw Data - click here to close

Geological EnvironmentHide

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Type Occurrence of FerroalluauditeHide

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Place of Conservation of Type Material:

National Museum of Natural History, Washington, D.C., USA, 162558.

Synonyms of FerroalluauditeHide

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Other Language Names for FerroalluauditeHide

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Relationship of Ferroalluaudite to other SpeciesHide

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Other Members of this group:

Alluaudite (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 Mon. 2/m : _B_2/b
Alluaudite-Ca□ ◻4Ca4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
Alluaudite-Na□ ◻4Na4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
Arseniopleite NaCaMnMn2(AsO4)3 Mon. 2/m
Badalovite Na2Mg2Fe(AsO4)3 Mon. 2/m : _B_2/b
Bradaczekite NaCu4(AsO4)3 Mon. 2/m : _B_2/b
Calciohatertite NaNaCa(CaFe3+)(AsO4)3 Mon. 2/m : _B_2/b
Calciojohillerite NaCaMg3(AsO4)3 Mon. 2/m : _B_2/b
Camanchacaite NaCaMg2[AsO4][AsO3(OH)]2 Mon. 2/m : _B_2/b
Canutite NaMn3[AsO4][AsO3(OH)]2 Mon. 2/m : _B_2/b
Caryinite (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 Mon. 2/m
Erikapohlite Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : _B_2/m
Ferroalluaudite-NaNa Na4Na4Fe2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/m
Ferrohagendorfite NaCaFe2+Fe2+2(PO4)3 Mon.
Groatite NaCaMn2(PO4)[PO3(OH)]2 Mon. 2/m : _B_2/b
Hagendorfite NaCaMn2+Fe2+2(PO4)3 Mon. 2/m : _B_2/b
Hagendorfite-NaNa NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) Mon. 2/m : _B_2/b
Hatertite Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 Mon. 2/m : _B_2/b
Johillerite Na(Mg,Zn)3Cu(AsO4)3 Mon. 2/m : _B_2/b
Keyite Cu2+3Zn4Cd2(AsO4)6 · 2H2O Mon. 2/m
Khrenovite Na3Fe3+2(AsO4)3 Mon. 2/m : _B_2/b
Maghagendorfite (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 Mon. 2/m
Magnesiocanutite NaMnMg2[AsO4]2[AsO2(OH)2] Mon. 2/m : _B_2/b
Magnesiohatertite (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 Mon. 2/m : _B_2/b
Nickenichite Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 Mon. 2/m : _B_2/b
O'Danielite Na(Zn,Mg)3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
Paraberzeliite NaCa2Mg2(AsO4)3 Mon. 2/m : _B_2/b
Unnamed (Na-Mg Arsenate Hydroxyarsenate) NaMg3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
Unnamed (Na-Zn-H Arsenate Hydroxyarsenate) Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
Varulite NaCaMn2+Mn2+2(PO4)3 Mon. 2/m : _B_2/b
Yazganite NaFe3+2(Mg,Mn2+)(AsO4)3 · H2O Mon. 2/m : _B_2/b
Zhanghuifenite Na3Mn4Mg2Al(PO4)6 Mon. 2/m
Zincobradaczekite NaZn2Cu2(AsO4)3 Mon. 2/m : _B_2/b

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.AC. Angarfite NaFe3+5(PO4)4(OH)4 · 4H2O Orth. 222 : _C_2221
8.AC. Wopmayite Ca6Na3◻Mn(PO4)3(PO3OH)4 Trig. 3_m_ : R_3_c
8.AC.X Dyrnaesite-(La) Na8Ce4+(La,REE)2(PO4)6 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC. Edtollite K2NaCu5Fe3+O2(AsO4)4 Tric. 1 : _P_1
8.AC. Alumoedtollite K2NaCu5AlO2(AsO4)4 Tric. 1 : _P_1
8.AC. Crocobelonite CaFe3+2O(PO4)2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC. Manganobadalovite NaNaMn(MgFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC. Beershevaite CaFe3+3(PO4)3O Mon. 2/m : _P_21/m
8.AC. Calciohatertite NaNaCa(CaFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC. Kabalovite Fe2+3Fe3+4(PO4)6 Tric. 1 : _P_1
8.AC. Nazarchukite Ca2NiFe3+2(PO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.AC. Changesite–(Y) (Ca8Y)◻Fe2+(PO4)7 Trig. 3_m_ : R_3_c
8.AC. Crocobelonite-1M CaFe3+2O(PO4)2 Mon. 2/m : _P_21/m
8.AC. Ebnerite (NH4)Zn(PO4) Hex. 6 : _P_63
8.AC. Magnesioqingheiite Na2Mg(MgAl)(PO4)3 Mon. 2/m
8.AC. Epiebnerite (NH4)Zn(PO4) Mon. 2 : _P_21
8.AC.02 Grigorievite Cu3Fe3+2Al2(VO4)6 Tric. 1 : _P_1
8.AC.02 Koksharovite CaMg2Fe3+4(VO4)6 Tric. 1 : _P_1
8.AC.02 Ziminaite Fe3+ 6 (VO4)6 Tric. 1 : _P_1
8.AC.05 Calciojohillerite NaCaMg3(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Howardevansite NaCuFe2(VO4)3 Tric. 1 : _P_1
8.AC.05 O'Danielite Na(Zn,Mg)3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 va Alluaudite-Na□ ◻4Na4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
8.AC.05 va Alluaudite-Ca□ ◻4Ca4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
8.AC.05 va Ferroalluaudite-NaNa Na4Na4Fe2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/m
8.AC.05 Hagendorfite-NaNa NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) Mon. 2/m : _B_2/b
8.AC.05 Erikapohlite Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : _B_2/m
8.AC.05 Hatertite Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Unnamed (Na-Mg Arsenate Hydroxyarsenate) NaMg3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 Unnamed (Na-Zn-H Arsenate Hydroxyarsenate) Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 Zincobradaczekite NaZn2Cu2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Badalovite Na2Mg2Fe(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Magnesiocanutite NaMnMg2[AsO4]2[AsO2(OH)2] Mon. 2/m : _B_2/b
8.AC.05 Magnesiohatertite (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Khrenovite Na3Fe3+2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Paraberzeliite NaCa2Mg2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Camanchacaite NaCaMg2[AsO4][AsO3(OH)]2 Mon. 2/m : _B_2/b
8.AC.05 Manganohatertite NaNaCa(MnFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC.07 Zhanghuifenite Na3Mn4Mg2Al(PO4)6 Mon. 2/m
8.AC.07 Ferrobobfergusonite Na2Fe2+5Fe3+Al(PO4)6 Mon.
8.AC.10 Alluaudite (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Arseniopleite NaCaMnMn2(AsO4)3 Mon. 2/m
8.AC.10 Caryinite (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 Mon. 2/m
8.AC.10 Hagendorfite NaCaMn2+Fe2+2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Johillerite Na(Mg,Zn)3Cu(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Maghagendorfite (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 Mon. 2/m
8.AC.10 Nickenichite Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Varulite NaCaMn2+Mn2+2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Ferrohagendorfite NaCaFe2+Fe2+2(PO4)3 Mon.
8.AC.10 Bradaczekite NaCu4(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Groatite NaCaMn2(PO4)[PO3(OH)]2 Mon. 2/m : _B_2/b
8.AC.15 Bobfergusonite Na2Mn5FeAl(PO4)6 Mon. 2/m : _P_2/b
8.AC.15 Ferrowyllieite (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Qingheiite NaNaMn2+(MgAl)(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Rosemaryite (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Wyllieite (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 Mon. 2/m
8.AC.15 Ferrorosemaryite ◻NaFe2+Fe3+Al(PO4)3 Mon. 2/m
8.AC.15 Ferroqingheiite NaNaFe2+(MgAl)(PO4)3 Mon. 2/m : _P_21/m
8.AC.17 Czochralskiite Na4Ca3Mg(PO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC.18 Manitobaite Na16Mn2+ 25Al8(PO4)30 Mon. m : P b
8.AC.20 Marićite NaFe2+(PO4) Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
8.AC.25 Berzeliite (NaCa2)Mg2(AsO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Manganberzeliite (NaCa2)Mn2+2(AsO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Palenzonaite (NaCa2)Mn2+2(VO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Schäferite (NaCa2)Mg2(VO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Hedegaardite (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.25 Matyhite Ca18(Ca,◻)2Fe2+2(PO4)14 Trig. 3_m_ : R_3_c
8.AC.30 Brianite Na2CaMg(PO4)2 Mon. 2/m : _P_21/b
8.AC.35 Vitusite-(Ce) Na3(Ce,La,Nd)(PO4)2 Orth. m _m_2 : P c _a_21
8.AC.40 Olgite (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 Trig. 3_m_ _(_32/m ) : _P_3_m_1
8.AC.40 Bario-olgite (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : _P_3
8.AC.45 Strontiowhitlockite Sr9Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.45 Whitlockite Ca9Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.45 Merrillite Ca9NaMg(PO4)7 Trig. 3_m_ : R_3_m
8.AC.45 Tuite Ca3(PO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.AC.45 Ferromerrillite Ca9NaFe2+(PO4)7 Trig. 3_m_ : R_3_c
8.AC.47 Iwateite Na2BaMn(PO4)2 Trig. 3 : _P_3
8.AC.47 Yurmarinite Na7(Fe3+,Mg,Cu)4(AsO4)6 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.47 Ozerovaite Na2KAl3(AsO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
8.AC.47 Anatolyite Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.47 Pansnerite K3Na3(Fe3+,Al)6(AsO4)8 Orth. m m m _(_2/_m_2/_m_2/m )
8.AC.50 Chladniite Na3CaMg11(PO4)9 Trig. 3 : _R_3
8.AC.50 Fillowite Na3CaMn2+11(PO4)9 Trig. 3 : _R_3
8.AC.50 Johnsomervilleite Na3CaFe11(PO4)9 Trig. 3 : _R_3
8.AC.50 Galileiite Na3Fe2+Fe2+11(PO4)9 Trig. 3 : _R_3
8.AC.50 Xenophyllite Na4Fe2+7(PO4)6 Tric. 1 : _P_1
8.AC.50 Udinaite NaMg4(VO4)3 Tet. 42_m_ : I_42_d
8.AC.50 Arsenudinaite NaMg4(AsO4)3 Tet. 42_m_ : I_42_d
8.AC.52 Lasnierite (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.AC.55 Pharmazincite KZnAsO4 Hex. 6 : _P_63
8.AC.57 Zubkovaite Ca3Cu3(AsO4)4 Mon. 2 : _B_2
8.AC.60 Kosnarite KZr2(PO4)3 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.65 Panethite (Na,Ca)2(Mg,Fe2+)2(PO4)2 Mon. 2/m : _P_21/b
8.AC.70 Stanfieldite Ca4Mg5(PO4)6 Mon.
8.AC.75 Ronneburgite K2MnV4O12 Mon. 2/m
8.AC.80 Tillmannsite Ag3Hg[(V,As)O4] Tet. 4 : _I_4
8.AC.85 Filatovite K(Al,Zn)2(As,Si)2O8 Mon. 2/m

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for FerroalluauditeHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.674-675 - as Alluaudite

Localities for FerroalluauditeHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Canada
Yukon Dawson mining district Big Fish River Robinson et al. (1992)
Rapid Creek Robinson et al. (1992)
Czech Republic
Central Bohemian Region Kutná Hora District Vlkaneč Přibyslavice Povondra et al. (eds.) +1 other reference
Finland
Kanta-Häme Tammela Sukula Pegmatites ? Palache et al. (1951)
Southwest Finland Kimitoön (Kemiönsaari) Ilkka Mikkola Collection XRD+ ...
Kimitoön Island Smörklinten Pavel M. Kartashov analytical data 2019
France (TL)
Nouvelle-Aquitaine Haute-Vienne Bellac Razès Chanteloube (TL) Palache et al. (1951)
Germany
North Rhine-Westphalia Arnsberg Märkischer Kreis Iserlohn Letmathe Helmke quarry nature reserve Genna zinc smelter slag locality Blaß et al. (1994) +1 other reference
Morocco
Drâa-Tafilalet Region Ouarzazate Province Amerzgane Cercle Ouisselsate Caïdat Angarf-South pegmatite Pavel.M. Kartashov (n.d.) +1 other reference
Poland
Lower Silesian Voivodeship Świdnica County Gmina Świdnica Michałkowa pegmatites Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts)
Rwanda
Western Province Kiluli Anthony et al. (2016)
Spain
Castile and Leon Salamanca Pereña de la Ribera Puentemocha pegmatite Roda-Robles et al. (2012)
Galicia Pontevedra Forcarei Santa mariña de Presqueiras pegmatite Calvo Rebollar (2015)
Sweden
Stockholm County Haninge Norrö Norrö Mica Quarry Gustafson (1989) +1 other reference
Sigtuna Arlanda Norrskogen Swedish Museum of Natural History (Naturarv database)
Turkey
Muğla Province Milâs District Ilbirdagı diasporic metabauxite deposit Hikmet Kinaci et al. (2023)