Hagendorfite-NaNa (original) (raw)

A material that is NOT an approved mineral species

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About Hagendorfite-NaNaHide

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Formula:

NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)

Crystal System:

Monoclinic

Name:

Originally published as a re-definition of hühnerkobelite (Moore, 1965). Renamed hagendorfite-NaNa by Moore and Ito (1979) for a member of the Alluaudite Group with the formula (M(2)4(M(1)4X(1)4X(2)4(PO4)-[_][_] where the dominant cation occupancies are: M(2) = Fe#2+#, M(1) = Mn#2+#, X(2) = Na, and X(1) = Na. Moore and Ito (1979) stated: "The proposed nomenclature of the alluaudites and the wyllieites was brought before the Commission on New Minerals and new Mineral Names (IMA)." Several species of the alluadite/wyllieite group have followed the proposed notation, but the proposal has not been adopted to date (2017).

Brilliant black stout crystals.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:31866:8

a5078e62-2485-4e07-a7bc-5214a3b884e1

IMA Classification of Hagendorfite-NaNaHide

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IMA status notes:

Pending approval

Approval history:

Submitted in 1979. No action to date.

Classification of Hagendorfite-NaNaHide

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8.AC.05

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations

Physical Properties of Hagendorfite-NaNaHide

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Comment:

Extremely fragile

Optical Data of Hagendorfite-NaNaHide

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RI values:

_n_α = 1.727 _n_γ = 1.738

δ = 0.011

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X = tan, Z = blue green

Chemistry of Hagendorfite-NaNaHide

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Mindat Formula:

NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)

Crystallography of Hagendorfite-NaNaHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 10.89 Å, b = 9.98 Å, c = 6.46 Å
β = 97.55°

Ratio:

a:b:c = 1.091 : 1 : 0.647

Unit Cell V:

696.00 ų (Calculated from Unit Cell)

Morphology:

c{001}, b{010}, a{100}, k{130}, j{310}, w{211}, x{321}, f{123},

Comment:

I21/a according to Moore (1965), Moore (1971); P2/n and C2/c according to Moore and Ito (1979).

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.18 Å (40)
6.24 Å (70)
5.41 Å (50)
3.465 Å (20)
3.196 Å (30)
3.085 Å (55)
3.035 Å (20)
2.938 Å (30)
2.876 Å (50)
2.841 Å (20)
2.760 Å (20)
2.703 Å (100)
2.659 Å (20)
2.601 Å (20)
2.531 Å (50)
2.481 Å (20)
2.360 Å (10)
2.192 Å (10)
2.135 Å (20)
2.102 Å (40)
2.055 Å (30)
1.978 Å (20)
1.945 Å (20)

Geological EnvironmentHide

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Geological Setting:

Late-stage granite pegmatite phosphate pods

First Recorded Occurrence of Hagendorfite-NaNaHide

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General Appearance of First Recorded Material:

Black equant crystals, also massive

Geological Setting of First Recorded Material:

Late-stage phosphate replacement unite of granite pegmatite

Associated Minerals at First Recorded Locality:

Synonyms of Hagendorfite-NaNaHide

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Relationship of Hagendorfite-NaNa to other SpeciesHide

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Other Members of this group:

Alluaudite (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 Mon. 2/m : _B_2/b
Alluaudite-Ca□ ◻4Ca4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
Alluaudite-Na□ ◻4Na4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
Arseniopleite NaCaMnMn2(AsO4)3 Mon. 2/m
Badalovite Na2Mg2Fe(AsO4)3 Mon. 2/m : _B_2/b
Bradaczekite NaCu4(AsO4)3 Mon. 2/m : _B_2/b
Calciohatertite NaNaCa(CaFe3+)(AsO4)3 Mon. 2/m : _B_2/b
Calciojohillerite NaCaMg3(AsO4)3 Mon. 2/m : _B_2/b
Camanchacaite NaCaMg2[AsO4][AsO3(OH)]2 Mon. 2/m : _B_2/b
Canutite NaMn3[AsO4][AsO3(OH)]2 Mon. 2/m : _B_2/b
Caryinite (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 Mon. 2/m
Erikapohlite Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : _B_2/m
Ferroalluaudite (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 Mon. 2/m : _B_2/b
Ferroalluaudite-NaNa Na4Na4Fe2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/m
Ferrohagendorfite NaCaFe2+Fe2+2(PO4)3 Mon.
Groatite NaCaMn2(PO4)[PO3(OH)]2 Mon. 2/m : _B_2/b
Hagendorfite NaCaMn2+Fe2+2(PO4)3 Mon. 2/m : _B_2/b
Hatertite Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 Mon. 2/m : _B_2/b
Johillerite Na(Mg,Zn)3Cu(AsO4)3 Mon. 2/m : _B_2/b
Keyite Cu2+3Zn4Cd2(AsO4)6 · 2H2O Mon. 2/m
Khrenovite Na3Fe3+2(AsO4)3 Mon. 2/m : _B_2/b
Maghagendorfite (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 Mon. 2/m
Magnesiocanutite NaMnMg2[AsO4]2[AsO2(OH)2] Mon. 2/m : _B_2/b
Magnesiohatertite (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 Mon. 2/m : _B_2/b
Nickenichite Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 Mon. 2/m : _B_2/b
O'Danielite Na(Zn,Mg)3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
Paraberzeliite NaCa2Mg2(AsO4)3 Mon. 2/m : _B_2/b
Unnamed (Na-Mg Arsenate Hydroxyarsenate) NaMg3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
Unnamed (Na-Zn-H Arsenate Hydroxyarsenate) Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
Varulite NaCaMn2+Mn2+2(PO4)3 Mon. 2/m : _B_2/b
Yazganite NaFe3+2(Mg,Mn2+)(AsO4)3 · H2O Mon. 2/m : _B_2/b
Zhanghuifenite Na3Mn4Mg2Al(PO4)6 Mon. 2/m
Zincobradaczekite NaZn2Cu2(AsO4)3 Mon. 2/m : _B_2/b

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8.AC. Angarfite NaFe3+5(PO4)4(OH)4 · 4H2O Orth. 222 : _C_2221
8.AC. Wopmayite Ca6Na3◻Mn(PO4)3(PO3OH)4 Trig. 3_m_ : R_3_c
8.AC.X Dyrnaesite-(La) Na8Ce4+(La,REE)2(PO4)6 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC. Edtollite K2NaCu5Fe3+O2(AsO4)4 Tric. 1 : _P_1
8.AC. Alumoedtollite K2NaCu5AlO2(AsO4)4 Tric. 1 : _P_1
8.AC. Crocobelonite CaFe3+2O(PO4)2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC. Manganobadalovite NaNaMn(MgFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC. Beershevaite CaFe3+3(PO4)3O Mon. 2/m : _P_21/m
8.AC. Calciohatertite NaNaCa(CaFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC. Kabalovite Fe2+3Fe3+4(PO4)6 Tric. 1 : _P_1
8.AC. Nazarchukite Ca2NiFe3+2(PO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.AC. Changesite–(Y) (Ca8Y)◻Fe2+(PO4)7 Trig. 3_m_ : R_3_c
8.AC. Crocobelonite-1M CaFe3+2O(PO4)2 Mon. 2/m : _P_21/m
8.AC. Ebnerite (NH4)Zn(PO4) Hex. 6 : _P_63
8.AC. Magnesioqingheiite Na2Mg(MgAl)(PO4)3 Mon. 2/m
8.AC. Epiebnerite (NH4)Zn(PO4) Mon. 2 : _P_21
8.AC.02 Grigorievite Cu3Fe3+2Al2(VO4)6 Tric. 1 : _P_1
8.AC.02 Koksharovite CaMg2Fe3+4(VO4)6 Tric. 1 : _P_1
8.AC.02 Ziminaite Fe3+ 6 (VO4)6 Tric. 1 : _P_1
8.AC.05 Calciojohillerite NaCaMg3(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Howardevansite NaCuFe2(VO4)3 Tric. 1 : _P_1
8.AC.05 O'Danielite Na(Zn,Mg)3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 va Alluaudite-Na□ ◻4Na4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
8.AC.05 va Alluaudite-Ca□ ◻4Ca4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
8.AC.05 va Ferroalluaudite-NaNa Na4Na4Fe2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/m
8.AC.05 Erikapohlite Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : _B_2/m
8.AC.05 Hatertite Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Unnamed (Na-Mg Arsenate Hydroxyarsenate) NaMg3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 Unnamed (Na-Zn-H Arsenate Hydroxyarsenate) Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 Zincobradaczekite NaZn2Cu2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Badalovite Na2Mg2Fe(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Magnesiocanutite NaMnMg2[AsO4]2[AsO2(OH)2] Mon. 2/m : _B_2/b
8.AC.05 Magnesiohatertite (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Khrenovite Na3Fe3+2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Paraberzeliite NaCa2Mg2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Camanchacaite NaCaMg2[AsO4][AsO3(OH)]2 Mon. 2/m : _B_2/b
8.AC.05 Manganohatertite NaNaCa(MnFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC.07 Zhanghuifenite Na3Mn4Mg2Al(PO4)6 Mon. 2/m
8.AC.07 Ferrobobfergusonite Na2Fe2+5Fe3+Al(PO4)6 Mon.
8.AC.10 Alluaudite (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Arseniopleite NaCaMnMn2(AsO4)3 Mon. 2/m
8.AC.10 Caryinite (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 Mon. 2/m
8.AC.10 Ferroalluaudite (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Hagendorfite NaCaMn2+Fe2+2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Johillerite Na(Mg,Zn)3Cu(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Maghagendorfite (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 Mon. 2/m
8.AC.10 Nickenichite Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Varulite NaCaMn2+Mn2+2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Ferrohagendorfite NaCaFe2+Fe2+2(PO4)3 Mon.
8.AC.10 Bradaczekite NaCu4(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Groatite NaCaMn2(PO4)[PO3(OH)]2 Mon. 2/m : _B_2/b
8.AC.15 Bobfergusonite Na2Mn5FeAl(PO4)6 Mon. 2/m : _P_2/b
8.AC.15 Ferrowyllieite (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Qingheiite NaNaMn2+(MgAl)(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Rosemaryite (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Wyllieite (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 Mon. 2/m
8.AC.15 Ferrorosemaryite ◻NaFe2+Fe3+Al(PO4)3 Mon. 2/m
8.AC.15 Ferroqingheiite NaNaFe2+(MgAl)(PO4)3 Mon. 2/m : _P_21/m
8.AC.17 Czochralskiite Na4Ca3Mg(PO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC.18 Manitobaite Na16Mn2+ 25Al8(PO4)30 Mon. m : P b
8.AC.20 Marićite NaFe2+(PO4) Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
8.AC.25 Berzeliite (NaCa2)Mg2(AsO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Manganberzeliite (NaCa2)Mn2+2(AsO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Palenzonaite (NaCa2)Mn2+2(VO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Schäferite (NaCa2)Mg2(VO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Hedegaardite (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.25 Matyhite Ca18(Ca,◻)2Fe2+2(PO4)14 Trig. 3_m_ : R_3_c
8.AC.30 Brianite Na2CaMg(PO4)2 Mon. 2/m : _P_21/b
8.AC.35 Vitusite-(Ce) Na3(Ce,La,Nd)(PO4)2 Orth. m _m_2 : P c _a_21
8.AC.40 Olgite (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 Trig. 3_m_ _(_32/m ) : _P_3_m_1
8.AC.40 Bario-olgite (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : _P_3
8.AC.45 Strontiowhitlockite Sr9Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.45 Whitlockite Ca9Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.45 Merrillite Ca9NaMg(PO4)7 Trig. 3_m_ : R_3_m
8.AC.45 Tuite Ca3(PO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.AC.45 Ferromerrillite Ca9NaFe2+(PO4)7 Trig. 3_m_ : R_3_c
8.AC.47 Iwateite Na2BaMn(PO4)2 Trig. 3 : _P_3
8.AC.47 Yurmarinite Na7(Fe3+,Mg,Cu)4(AsO4)6 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.47 Ozerovaite Na2KAl3(AsO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
8.AC.47 Anatolyite Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.47 Pansnerite K3Na3(Fe3+,Al)6(AsO4)8 Orth. m m m _(_2/_m_2/_m_2/m )
8.AC.50 Chladniite Na3CaMg11(PO4)9 Trig. 3 : _R_3
8.AC.50 Fillowite Na3CaMn2+11(PO4)9 Trig. 3 : _R_3
8.AC.50 Johnsomervilleite Na3CaFe11(PO4)9 Trig. 3 : _R_3
8.AC.50 Galileiite Na3Fe2+Fe2+11(PO4)9 Trig. 3 : _R_3
8.AC.50 Xenophyllite Na4Fe2+7(PO4)6 Tric. 1 : _P_1
8.AC.50 Udinaite NaMg4(VO4)3 Tet. 42_m_ : I_42_d
8.AC.50 Arsenudinaite NaMg4(AsO4)3 Tet. 42_m_ : I_42_d
8.AC.52 Lasnierite (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.AC.55 Pharmazincite KZnAsO4 Hex. 6 : _P_63
8.AC.57 Zubkovaite Ca3Cu3(AsO4)4 Mon. 2 : _B_2
8.AC.60 Kosnarite KZr2(PO4)3 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.65 Panethite (Na,Ca)2(Mg,Fe2+)2(PO4)2 Mon. 2/m : _P_21/b
8.AC.70 Stanfieldite Ca4Mg5(PO4)6 Mon.
8.AC.75 Ronneburgite K2MnV4O12 Mon. 2/m
8.AC.80 Tillmannsite Ag3Hg[(V,As)O4] Tet. 4 : _I_4
8.AC.85 Filatovite K(Al,Zn)2(As,Si)2O8 Mon. 2/m

Fluorescence of Hagendorfite-NaNaHide

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Not fluorescent in Ultraviolet light

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Hagendorfite-NaNaHide

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Localities for Hagendorfite-NaNaHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

USA (FRL)
New Hampshire Grafton County Groton Palermo No. 1 Mine (FRL) Moore (1965) +1 other reference