Kirkiite (original) (raw)

A valid IMA mineral species

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About KirkiiteHide

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Specific Gravity:

6.82 (Calculated)

Crystal System:

Monoclinic

Name:

After the type locality at the Agios Philippos Pb-Zn deposit, Kirki (Kirka), Xánthi Prefecture, Thraki (Thrace; Thracia) Department, Greece.

This page provides mineralogical data about Kirkiite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2216:9

b466971f-ac42-45f4-98c9-bf3281614638

IMA Classification of KirkiiteHide

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Type description reference:

Moëlo, Yves, Oudin, Elisabeth, Makovicky, Emil, Karup-Møller, Sven, Pillard, François, Bornuat, Michel, Evanghelou, Evangheli (1985) La kirkiite, Pb10Bi3As3S19, une nouvelle espèce minérale homologue de la jordanite. Bulletin de Minéralogie, 108 (5) 667-677 doi:10.3406/bulmi.1985.7883

Classification of KirkiiteHide

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2.JB.30b

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb

3.4.17.1

3 : SULFOSALTS
4 : ø = 3

5.6.32

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
6 : Sulpharsenites etc. of Pb alone

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Krk IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Krk The Canadian Mineralogist (2019) The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of KirkiiteHide

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Hardness:

VHN100=150 kg/mm2 - Vickers

Hardness Data:

Could not be measured

Density:

6.82 g/cm3 (Calculated)

Optical Data of KirkiiteHide

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Reflectivity:

Wavelength R1 R2
420nm 45.3% 40.2%
460nm 45.2% 40.9%
500nm 44.5% 40.4%
540nm 43.5% 39.4%
580nm 42.6% 38.6%
620nm 42.1% 38.0%
660nm 41.5% 37.5%
700nm 40.9% 36.9%
740nm 39.9% 35.7%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 45.3%.
R1 shown in black, R2 shown in red

Colour in reflected light:

White

Chemistry of KirkiiteHide

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Mindat Formula:

Pb10Bi3As3S19

Crystallography of KirkiiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 8.700(2) Å, b = 26.237(6) Å, c = 8.774(3) Å
β = 119.653(4)°

Ratio:

a:b:c = 0.332 : 1 : 0.334

Comment:

Data from Pinto et al. (2006) for a sample with a composition very close to the endmember.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0006074 Kirkiite Makovicky E, Balic-Zunic T, Karanovic L, Poleti D (2006) The crystal structure of kirkiite, Pb10Bi3As3S19 The Canadian Mineralogist 44 177-188 2006 lead-zinc deposit of Aghios Philippos, near Kirki, in Thrace, Greece 0 293
0007156 Kirkiite Pinto D, Balic-Zunic T, Garavelli A, Garbarino C, Makovicky E, Vurro F (2006) First occurrence of close-to-ideal kirkiite at Vulcano (Aeolian Islands, Italy): chemical data and single-crystal X-ray study European Journal of Mineralogy 18 393-401 2006 La Fossa crater, Vulcano, Aeolian Islands, Italy 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.65 Å (50)
3.475 Å (60)
3.260 Å (100)
3.070 Å (70)
2.854 Å (60)
2.190 Å (50)
2.014 Å (40)
1.815 Å (50)

Geological EnvironmentHide

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Type Occurrence of KirkiiteHide

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General Appearance of Type Material:

Subhedral grains to 200 μm.

Place of Conservation of Type Material:

No designated type material.

Geological Setting of Type Material:

Associated Minerals at Type Locality:

Reference:

Moëlo, Y., Oudin, E., Makovicky, E., Karup-Møller, S., Pillard, F., Bornuat, M., Evanghelou, E. (1985) La kirkiite, Pb10Bi3As3S19, une nouvelle espèce minérale homologue de la jordanite. Bulletin de Minéralogie: 108: 667-677.

Synonyms of KirkiiteHide

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Other Language Names for KirkiiteHide

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Relationship of Kirkiite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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2.JB. Senandorite AgPbSb3S6 Orth. m _m_2 : P m _n_21
2.JB. Oscarkempffite Ag10Pb4(Sb17Bi9)S48 Orth. m _m_2
2.JB. Chukotkaite AgPb7Sb5S15 Mon. 2/m : _P_21/b
2.JB. Arsenquatrandorite Ag17.6Pb12.8Sb38.1As11.5S96 Mon. 2/m : _P_21/b
2.JB. Clino-oscarkempffite Ag15Pb6Sb21Bi18S72 Mon. 2/m : _P_21/b
2.JB. Andreadiniite CuHgAg7Pb7Sb24S48 Mon. 2/m : _P_21/b
2.JB. Ginelfite Ag2(Ag0.5Fe)TlPb23.5(Sb,As)33.5S76 Tric. 1 : _P_1
2.JB. Lazerckerite Ag3.75Pb4.50(Sb7.75Bi4)S24 Mon. 2/m
2.JB. Lasmanisite Ag12Pb13Mn11Sb44S96 Orth. 222 : _P_212121
2.JB. Montpelvouxite AgPb16Sb27As18S84 Tric. 1 : _P_1
2.JB. Selenojunoite Cu2Pb3Bi8Se16 Mon. 2/m : _B_2/m
2.JB.05 Diaphorite Ag3Pb2Sb3S8 Mon. 2/m : _P_21/b
2.JB.10 Cosalite Pb2Bi2S5 Orth. m m m _(_2/_m_2/_m_2/m )
2.JB.15 Freieslebenite AgPbSbS3 Mon. 2/m : _P_21/b
2.JB.15 Marrite AgPbAsS3 Mon. 2/m : _P_21/b
2.JB.20 Cannizzarite Pb48Bi56S132 Mon. 2/m : _P_21/m
2.JB.20 Wittite Pb9Bi12(S,Se)27 Mon.
2.JB.25a Junoite Cu2Pb3Bi8(S,Se)16 Mon. 2/m : _B_2/m
2.JB.25i Neyite Ag2Cu6Pb25Bi26S68 Mon. 2/m : _B_2/m
2.JB.25c Nordströmite CuPb3Bi7(Se4S10) Mon. 2/m : _P_21/m
2.JB.25g Nuffieldite Cu1.4Pb2.4Bi2.4Sb0.2S7 Orth. m m m _(_2/_m_2/_m_2/m )
2.JB.25d Proudite CuPb7.5Bi9.33(S,Se)22 Mon. 2/m : _B_2/m
2.JB.25h Weibullite Pb5Bi8Se7S11 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
2.JB.25b Felbertalite Cu2Pb6Bi8S19 Mon. 2/m : _B_2/m
2.JB.25j Rouxelite Cu2HgPb23Sb27S65.5 Mon. 2/m : _B_2/m
2.JB.25f Ángelaite Cu2AgPbBiS4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
2.JB.25i Cuproneyite Cu7Pb27Bi25S68 Mon. 2/m : _B_2/m
2.JB.30a Geocronite Pb14Sb6S23 Mon. 2/m : _P_21/m
2.JB.30a Jordanite Pb14As6S23 Mon. 2/m : _P_21/m
2.JB.30c Tsugaruite Pb28As15S50Cl Orth. m _m_2 : P n _n_2
2.JB.30a Marcobaldiite Pb12(Sb3As2Bi)Σ6S21 Tric. 1 : _P_1
2.JB.30a Arsenmarcobaldiite Pb12(As3.2Sb2.8)Σ6S21 Tric. 1 : _P_1
2.JB.35c Pillaite Pb9Sb10S23ClO0.5 Mon. 2/m : _B_2/m
2.JB.35a Zinkenite Pb9Sb22S42 Hex. 6 : _P_63
2.JB.35b Scainiite Pb14Sb30S54O5 Mon. 2/m : _B_2/m
2.JB.35d Pellouxite (Cu,Ag)Pb10Sb12S27O(Cl,S)0.6 Mon. 2/m : _B_2/m
2.JB.35f Tubulite Ag2Pb22Sb20S53 Mon. m : P b
2.JB.35e Chovanite Pb15-2xSb14+2xS36Ox (x ~ 0.2) Mon. 2/m : _B_2/m
2.JB.40b Aschamalmite Pb6-3xBi2+xS9 Mon. 2/m : _B_2/m
2.JB.40a Bursaite Pb5Bi4S11 (?) Orth.
2.JB.40b Eskimoite Ag7Pb10Bi15S36 Mon.
2.JB.40a Fizélyite Ag5Pb14Sb21S48 Mon. 2/m
2.JB.40a Gustavite AgPbBi3S6 Orth. m m m _(_2/_m_2/_m_2/m )
2.JB.40a Lillianite Pb3-2xAgxBi2+xS6 Orth. m m m _(_2/_m_2/_m_2/m )
2.JB.40c Ourayite Ag3Pb4Bi5S13 Orth.
2.JB.40a Ramdohrite Pb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24 Mon. 2/m
2.JB.40a Roshchinite Ag19Pb10Sb51S96 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
2.JB.40d Schirmerite PbAgBi3S6 - Pb3Ag1.5Bi3.5S9 Orth.
2.JB.40a Treasurite Ag7Pb6Bi15S32 Mon.
2.JB.40a Uchucchacuaite AgMnPb3Sb5S12 Orth. m m m _(_2/_m_2/_m_2/m ) : P m m m
2.JB.40e Ustarasite Pb(Bi,Sb)6S10 (?)
2.JB.40a Vikingite Ag5Pb8Bi13S30 Mon. 2/m : _B_2/m
2.JB.40a Xilingolite Pb3Bi2S6 Mon.
2.JB.40b Heyrovskýite Pb6Bi2S9 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
2.JB.40 UM1988-05-S:AgBiCuHgPb (Hg,Ag,Cu,Pb)5Pb5Bi11S27
2.JB.40 UM1988-06-S:AgBiCuHgPb (Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27
2.JB.40a Quatrandorite AgPbSb3S6 Mon. 2/m : _P_21/b
2.JB.40a Menchettiite AgPb2.40Mn1.60Sb3As2S12 Mon. 2/m : _P_21/b
2.JB.40a Terrywallaceite AgPb(Sb,Bi)3S6 Mon. 2/m : _P_21/b
2.JB.40a Jasrouxite Ag16Pb4(Sb24As16)S72 Tric. 1 : _P_1
2.JB.40a Erzwiesite Ag8Pb12Bi16S40 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m
2.JB.40a Staročeskéite Ag0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m
2.JB.40a Oyonite Ag3Mn2Pb4Sb7As4S24 Mon. 2/m
2.JB.40a Holubite Ag3Pb6(Sb8Bi3)S24 Mon. 2/m
2.JB.40b Baiamareite Ag4Pb12Fe4Sb20S48 Mon. 2/m
2.JB.40a Tarutinoite Ag3Pb7Bi7S19 Mon. 2/m : _B_2/m
2.JB.55 Gratonite Pb9As4S15 Trig. 3_m_ : R_3_m
2.JB.60 Marrucciite Hg3Pb16Sb18S46 Mon. 2/m : _B_2/m
2.JB.65 Vurroite Pb20Sn2(Bi,As)22S54Cl6 Mon. 2/m : _B_2/b
2.JB.65 Tazieffite Pb20Cd2(As,Bi)22S50Cl10 Mon. 2/m : _B_2/b
2.JB.70 Daliranite PbHgAs2S5 Mon.

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KirkiiteHide

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Reference List:

Moëlo, Yves, Oudin, Elisabeth, Makovicky, Emil, Karup-Møller, Sven, Pillard, François, Bornuat, Michel, Evanghelou, Evangheli (1985) La kirkiite, Pb10Bi3As3S19, une nouvelle espèce minérale homologue de la jordanite. Bulletin de Minéralogie, 108 (5) 667-677 doi:10.3406/bulmi.1985.7883

**Hawthorne, Frank C., Fleischer, Michael, Grew, Edward S., Grice, Joel D., Jambor, John L., Puziewicz, J., Roberts, Andrew C., Vanko, D. A., Zilczer, J. A. (1986) New mineral names. American Mineralogist, 71. 1277-1282**pp.1278-1279

Borodaev, Yuri S., Garavelli, Anna, Kuzmina, Olga V., Mozgova, Nadezhda N., Organova, Natalia I., Trubkin, Nikolay V., Vurro, Filippo (1998) Rare sulfosalts from Vulcano, Aeolian Islands, Italy. I. Se-bearing kirkiite, Pb10(Bi,As)6(S,Se)19. The Canadian Mineralogist, 36 (4) 1105-1114

Pinto, Daniela, Balić-Žunić, Tonci, Garavelli, Anna, Garbarino, Carlo, Makovicky, Emil, Vurro, Filippo (2006) First occurrence of close-to-ideal kirkiite at Vulcano (Aeolian Islands, Italy): chemical data and single-crystal X-ray study. European Journal of Mineralogy, 18 (3) 393-401 doi:10.1127/0935-1221/2006/0018-0393

Localities for KirkiiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Greece (TL)
Eastern Macedonia and Thrace Evros Alexandroupoli Kirki Mines Agios Philippos Mine (TL) Moëlo et al. (1985) +3 other references
Italy
Sicily Metropolitan City of Messina Eolie Islands (Aeolian Islands) Lipari Vulcano Island La Fossa crater Borodaev et al. (1998)
Mexico
Chihuahua Carmargo Municipality Sierra de las Encinillas Guadalupe Mine Mike Scott S105203 from Cureton from ...
Russia
Sverdlovsk Oblast Beryozovsky Berezovsk deposit Kasatkin A.V. (2019)