Kleemanite (original) (raw)

A valid IMA mineral species

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About KleemaniteHide

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Formula:

ZnAl2(PO4)2(OH)2 · 3H2O

Colour:

colorless to pale brownish yellow

Crystal System:

Monoclinic

Name:

Named in honor of Alfred William Kleeman (27 July 1913 - 15 December 1982), Australian petrologist and Reader in the Department of Geology, The University of Adelaide, Australia. He was "the mentor of a generation and more of students of mineralogy and petrology in that department."

This page provides mineralogical data about Kleemanite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2224:4

c3841ae5-008f-4ae0-8a9b-6b7382b1d2aa

IMA Classification of KleemaniteHide

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Type description reference:

Classification of KleemaniteHide

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8.DC.17

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1

42.11.12.2

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O

19.8.22

19 : Phosphates
8 : Phosphates of Al and other metals

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Klm IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of KleemaniteHide

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Pronunciation:

Play Recorded by Country
Sorry, your browser doesn't support HTML5 audio. Jolyon Ralph United Kingdom

Physical Properties of KleemaniteHide

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Colour:

colorless to pale brownish yellow

Density:

2.84 g/cm3 (Measured) 2.76 g/cm3 (Calculated)

Optical Data of KleemaniteHide

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RI values:

_n_α = 1.598(2) _n_γ = 1.614(2)

δ = 0.016

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of KleemaniteHide

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Mindat Formula:

ZnAl2(PO4)2(OH)2 · 3H2O

Crystallography of KleemaniteHide

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Crystal System:

Monoclinic

Cell Parameters:

a = 7.282(8) Å, b = 7.190(5) Å, c = 9.770(8) Å
β = 110.2°

Ratio:

a:b:c = 1.013 : 1 : 1.359

Unit Cell V:

480.07 ų (Calculated from Unit Cell)

Morphology:

matted coatings of very fine-bladed acicular crystals

Twinning:

Multiple twinning parallel to fiber elongation probable.

Comment:

Point Group: 2/m or 2; Space Group: P2/m, P21/m, P2, or P21.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.76 Å (10)
3.09 Å (8)
9.09 Å (6)
3.30 Å (6)
5.66 Å (5)
3.88 Å (5)
3.64 Å (5)

Geological EnvironmentHide

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Type Occurrence of KleemaniteHide

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General Appearance of Type Material:

Ochreous in appearance, but under a hand lens it is composed of a very fine, hair-like mass of crystals.

Place of Conservation of Type Material:

Museum Victoria, Melbourne, M34218; Division of Mineral Chemistry, CSIRO, Melbourne, Australia, MC637; National Museum of Natural History, Washington, D.C., USA, 145805.

Geological Setting of Type Material:

weathering zone of manganiferous iron ore.

Associated Minerals at Type Locality:

Reference:

Pilkington, E. S., Segnit, E. R., Watts, J. and Francis, G. (1979) Kleemanite, a new zinc aluminium phosphate. Mineralogical Magazine: 43: 93-95.

Synonyms of KleemaniteHide

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Other Language Names for KleemaniteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DC. Ianbruceite Zn2(AsO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC. Césarferreiraite Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC. Ferrivauxite Fe3+Al2(PO4)2(OH)3 · 5H2O Tric. 1 : _P_1
8.DC.05 Nissonite Cu2Mg2(PO4)2(OH)2 · 5H2O Mon. 2/m : _B_2/b
8.DC.07 Euchroite Cu2(AsO4)(OH) · 3H2O Orth. 222 : _P_212121
8.DC.10 Legrandite Zn2(AsO4)(OH) · H2O Mon. 2/m : _P_21/b
8.DC.12 Strashimirite Cu8(AsO4)4(OH)4 · 5H2O Mon.
8.DC.15 Arthurite CuFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Earlshannonite Mn2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Ojuelaite ZnFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Whitmoreite Fe2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Cobaltarthurite (Co,Mg)Fe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Bendadaite Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Kunatite CuFe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 UM2006-27-PO:FeHZn ZnFe3+2(PO4)2(OH)2 · 4H2O Mon.
8.DC.15 UKI-2006-(PO:AlCuFeH) Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.20 Bermanite Mn2+Mn3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_2/b
8.DC.20 Coralloite Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O Tric. 1 : _P_1
8.DC.20 Magnesiobermanite MgMn3+2(PO4)2(OH)2 · 4H2O Mon. 2 : _P_21
8.DC.22 Kovdorskite Mg2(PO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC.25 Ferristrunzite Fe3+Fe3+2(PO4)2(OH)3 · 5H2O Tric.
8.DC.25 Ferrostrunzite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric.
8.DC.25 Metavauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.25 Metavivianite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Strunzite Mn2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Zincostrunzite ZnFe3+2(PO4)2(OH)2 · 6.5H2O Tric. 1 : _P_1
8.DC.27 Beraunite Fe3+6(PO4)4O(OH)4 · 6H2O Mon. m : B b
8.DC.27 Tvrdýite Fe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2O Mon. 2/m : _B_2/b
8.DC.27 Zincoberaunite ZnFe3+5(PO4)4(OH)5 · 6H2O Mon. 2/m : _B_2/b
8.DC.30 Gordonite MgAl2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Laueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Mangangordonite Mn2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Paravauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Pseudolaueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.30 Sigloite Fe3+Al2(PO4)2(OH)3 · 7H2O Tric. 1 : _P_1
8.DC.30 Stewartite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ushkovite MgFe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ferrolaueite Fe2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Kastningite (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Maghrebite MgAl2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Nordgauite MnAl2(PO4)2(F,OH)2 · 5H2O Tric. 1 : _P_1
8.DC.30 Kayrobertsonite [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O Tric. 1 : _P_1
8.DC.30 Kummerite Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.32 Tinticite Fe3+3(PO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.32 Kamarizaite Fe3+3(AsO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.35 Vauxite Fe2+Al2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.37 Vantasselite Al4(PO4)3(OH)3 · 9H2O Orth.
8.DC.40 Cacoxenite Fe3+24AlO6(PO4)17(OH)12 · 75H2O Hex. 6/m : _P_63/m
8.DC.45 Gormanite (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric.
8.DC.45 Souzalite (Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric. 1
8.DC.47 Kingite Al3(PO4)2F2(OH) · 7H2O Tric.
8.DC.50 Wavellite Al3(PO4)2(OH,F)3 · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.50 Allanpringite Fe3+3(PO4)2(OH)3 · 5H2O Mon. 2/m : _P_21/m
8.DC.50 Fluorwavellite Al3(PO4)2(OH)2F · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.52 Kribergite Al5(PO4)3(SO4)(OH)4 · 4H2O Tric. 1 : _P_1
8.DC.55 Mapimite Zn2Fe3+3(AsO4)3(OH)4 · 10H2O Mon. m : B m
8.DC.57 Ogdensburgite Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m m m
8.DC.60 Nevadaite (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.60 Cloncurryite Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O Mon. 2/m : _P_21/b
8.DC.62 Kenngottite Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : _P_2/b
8.DC.67 Molinelloite Cu(H2O)(OH)V4+O(V5+O4) Tric. 1 : _P_1
8.DC.70 Whitecapsite H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O Hex. 6/m : _P_63/m
8.DC.75 Heimite PbCu2(AsO4)(OH)3 · 2H2O Mon. 2/m
8.DC.80 Lednevite Cu[PO3(OH)] · H2O Mon. 2/m : _P_21/b

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KleemaniteHide

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Reference List:

Fleischer, Michael, Burns, Roger G., Cabri, Louis J., Chao, George Y., Hogarth, D. D., Pabst, Adolf (1979) New Mineral Names. American Mineralogist, 64 (11-12) 1329-1334

Localities for KleemaniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Yancowinna Co. Broken Hill district Broken Hill Broken Hill South Mine (BHS Mine; South Mine) Kintore opencut Pring et al. (1989) +1 other reference
South Australia Pastoral Unincorporated Area Iron Knob Iron Monarch Main Pit (TL) Pilkington et al. (1979)
Bolivia
Oruro Poopó Province Poopó Torres et al. (2019)
China
Guangdong Meizhou Mei Co. Baokeng Mn deposit Lai et al. (1993)
Czech Republic
Karlovy Vary Region Sokolov District Krásno Huber stock (Huber shaft; Hub stock) Vrtiška et al. (n.d.)
Spain
Castile and Leon Salamanca Golpejas Golpejas Mining group Tita Mine Calvo Rebollar et al. (2022)