Strashimirite (original) (raw)
A valid IMA mineral species
About StrashimiriteHide
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Formula:
Cu8(AsO4)4(OH)4 · 5H2O
Colour:
White, pale green, yellow-green
Specific Gravity:
3.67 (Calculated)
Crystal System:
Monoclinic
Name:
Named in honor of Strashimir Georgiev Dimitrov (Страшимир Георгиев Димитров) (22 August 1892, Sofia, Bulgaria - 26 April 1960, Sofia, Bulgaria), petrographer. He was Head of the Department of Mineralogy and Petrography and secretary of the Department of Geological, Geographical and Chemical Sciences at the Bulgarian Academy of Sciences.
An uncommon secondary Cu-arsenate. Fibrous varieties and crusts of parnauite can appear visually similar.
The crystal structure has been solved very recently (2015), leading to a revision of the formula, space group and unit cell (Kolitsch & Giester, to be published).
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:3799:6
fa1dbe29-687b-4185-a5cc-7e457dc1ec9d
IMA Classification of StrashimiriteHide
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IMA Formula:
Cu4(AsO4)2(OH)2 · 2.5H2O
Type description reference:
Classification of StrashimiriteHide
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8.DC.12
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
42.6.5.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
6 : A2(XO4)Zq·xH2O
20.1.9
20 : Arsenates (also arsenates with phosphate, but without other anions)
1 : Arsenates of Cu
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Ssh | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of StrashimiriteHide
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Colour:
White, pale green, yellow-green
Parting:
May exhibit parting ⊥ elongation.
Density:
3.67 g/cm3 (Calculated)
Optical Data of StrashimiriteHide
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RI values:
_n_α = 1.726 _n_γ = 1.747
δ = 0.021
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Optical Extinction:
Z ∧ elongation ≃ 5°.
Comments:
Y = very pale yellowish green; Z = yellowish green.
Chemistry of StrashimiriteHide
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Mindat Formula:
Cu8(AsO4)4(OH)4 · 5H2O
Crystallography of StrashimiriteHide
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Crystal System:
Monoclinic
Cell Parameters:
a = 9.71 Å, b = 18.81 Å, c = 8.94 Å
β = 97.2°
Ratio:
a:b:c = 0.516 : 1 : 0.475
Unit Cell V:
1,619.97 ų (Calculated from Unit Cell)
Comment:
Space group is P2/m, Pm or P2
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 18.74 Å | (100) |
| 2.86 Å | (100) |
| 8.97 Å | (90) |
| 3.13 Å | (90) |
| 9.46 Å | (80) |
| 4.79 Å | (80) |
| 4.21 Å | (80) |
Geological EnvironmentHide
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Type Occurrence of StrashimiriteHide
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General Appearance of Type Material:
Fine platy to fibrous aggregates in spherulites up to 0.5 mm.
Place of Conservation of Type Material:
Natural History Museum, Sofia, Bulgaria.
University of Sofia, Sofia, Bulgaria.
Geological Setting of Type Material:
Oxidation zone of a copper deposit.
Associated Minerals at Type Locality:
Reference:
Mincheva-Stefanova, I. (1968) Strashimirite, a new hydrous copper arsenate. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 97: 470-477.
Synonyms of StrashimiriteHide
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Other Language Names for StrashimiriteHide
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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| 8.DC. | Césarferreiraite | Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
|---|---|---|---|
| 8.DC. | Ferrivauxite | Fe3+Al2(PO4)2(OH)3 · 5H2O | Tric. 1 : _P_1 |
| 8.DC. | Ianbruceite | Zn2(AsO4)(OH) · 3H2O | Mon. 2/m : _P_21/b |
| 8.DC.05 | Nissonite | Cu2Mg2(PO4)2(OH)2 · 5H2O | Mon. 2/m : _B_2/b |
| 8.DC.07 | Euchroite | Cu2(AsO4)(OH) · 3H2O | Orth. 222 : _P_212121 |
| 8.DC.10 | Legrandite | Zn2(AsO4)(OH) · H2O | Mon. 2/m : _P_21/b |
| 8.DC.15 | Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DC.15 | Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DC.15 | UM2006-27-PO:FeHZn | ZnFe3+2(PO4)2(OH)2 · 4H2O | Mon. |
| 8.DC.15 | UKI-2006-(PO:AlCuFeH) | Fe2+Al3+2(PO4)2(OH)2 · 4H2O | |
| 8.DC.15 | Cobaltarthurite | CoFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DC.15 | Arthurite | CuFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DC.15 | Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DC.15 | Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DC.15 | Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DC.17 | Kleemanite | ZnAl2(PO4)2(OH)2 · 3H2O | Mon. |
| 8.DC.20 | Magnesiobermanite | MgMn3+2(PO4)2(OH)2 · 4H2O | Mon. 2 : _P_21 |
| 8.DC.20 | Bermanite | Mn2+Mn3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : _P_2/b |
| 8.DC.20 | Coralloite | Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O | Tric. 1 : _P_1 |
| 8.DC.22 | Kovdorskite | Mg2(PO4)(OH) · 3H2O | Mon. 2/m : _P_21/b |
| 8.DC.25 | Zincostrunzite | ZnFe3+2(PO4)2(OH)2 · 6.5H2O | Tric. 1 : _P_1 |
| 8.DC.25 | Metavauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O | Mon. 2/m : _P_21/b |
| 8.DC.25 | Metavivianite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O | Tric. 1 : _P_1 |
| 8.DC.25 | Ferristrunzite | Fe3+Fe3+2(PO4)2(OH)3 · 5H2O | Tric. |
| 8.DC.25 | Strunzite | Mn2+Fe3+2(PO4)2(OH)2 · 6H2O | Tric. 1 : _P_1 |
| 8.DC.25 | Ferrostrunzite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O | Tric. |
| 8.DC.27 | Beraunite | Fe3+6(PO4)4O(OH)4 · 6H2O | Mon. m : B b |
| 8.DC.27 | Tvrdýite | Fe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2O | Mon. 2/m : _B_2/b |
| 8.DC.27 | Zincoberaunite | ZnFe3+5(PO4)4(OH)5 · 6H2O | Mon. 2/m : _B_2/b |
| 8.DC.30 | Maghrebite | MgAl2(AsO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Ferrolaueite | Fe2+Fe3+2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Ushkovite | MgFe3+2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Laueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Paravauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Sigloite | Fe3+Al2(PO4)2(OH)3 · 7H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Nordgauite | MnAl2(PO4)2(F,OH)2 · 5H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Kayrobertsonite | [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Kummerite | Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Mangangordonite | Mn2+Al2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Stewartite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Gordonite | MgAl2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Kastningite | (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O | Tric. 1 : _P_1 |
| 8.DC.30 | Pseudolaueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O | Mon. 2/m : _P_21/b |
| 8.DC.32 | Kamarizaite | Fe3+3(AsO4)2(OH)3 · 3H2O | Tric. 1 : _P_1 |
| 8.DC.32 | Tinticite | Fe3+3(PO4)2(OH)3 · 3H2O | Tric. 1 : _P_1 |
| 8.DC.35 | Vauxite | Fe2+Al2(PO4)2(OH)2 · 6H2O | Tric. 1 : _P_1 |
| 8.DC.37 | Vantasselite | Al4(PO4)3(OH)3 · 9H2O | Orth. |
| 8.DC.40 | Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O | Hex. 6/m : _P_63/m |
| 8.DC.45 | Souzalite | (Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O | Tric. 1 |
| 8.DC.45 | Gormanite | (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O | Tric. |
| 8.DC.47 | Kingite | Al3(PO4)2F2(OH) · 7H2O | Tric. |
| 8.DC.50 | Allanpringite | Fe3+3(PO4)2(OH)3 · 5H2O | Mon. 2/m : _P_21/m |
| 8.DC.50 | Fluorwavellite | Al3(PO4)2(OH)2F · 5H2O | Orth. m m m _(_2/_m_2/_m_2/m ) |
| 8.DC.50 | Wavellite | Al3(PO4)2(OH,F)3 · 5H2O | Orth. m m m _(_2/_m_2/_m_2/m ) |
| 8.DC.52 | Kribergite | Al5(PO4)3(SO4)(OH)4 · 4H2O | Tric. 1 : _P_1 |
| 8.DC.55 | Mapimite | Zn2Fe3+3(AsO4)3(OH)4 · 10H2O | Mon. m : B m |
| 8.DC.57 | Ogdensburgite | Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : C m m m |
| 8.DC.60 | Cloncurryite | Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O | Mon. 2/m : _P_21/b |
| 8.DC.60 | Nevadaite | (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O | Orth. m m m _(_2/_m_2/_m_2/m ) |
| 8.DC.62 | Kenngottite | Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 | Mon. 2/m : _P_2/b |
| 8.DC.67 | Molinelloite | Cu(H2O)(OH)V4+O(V5+O4) | Tric. 1 : _P_1 |
| 8.DC.70 | Whitecapsite | H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O | Hex. 6/m : _P_63/m |
| 8.DC.75 | Heimite | PbCu2(AsO4)(OH)3 · 2H2O | Mon. 2/m |
| 8.DC.80 | Lednevite | Cu[PO3(OH)] · H2O | Mon. 2/m : _P_21/b |
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for StrashimiriteHide
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References for StrashimiriteHide
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Reference List:
Frost, Ray L., Reddy, B. Jagannadha, Sejkora, Jiří, Čejka, Jiří, Keeffe, Eloise C. (2010) Characterisation of the Copper Arsenate Mineral Strashimirite, Cu8(AsO4)4(OH)4·4H2O, by near Infrared Spectroscopy. Journal of Near Infrared Spectroscopy, 18 (2) 157-165 doi:10.1255/jnirs.873
Majzlan, J., Števko, M., Plášil, J., Sejkora, J., Dachs, E. (2023) Thermodynamics of the Cu, Zn, and Cu-Zn phases: zincolivenite, adamite, olivenite, ludjibaite, strashimirite, and slavkovite. Journal of GEOsciences, 68 (1) 67-80 doi:10.3190/jgeosci.367
Localities for StrashimiriteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the 
symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. 
- Good crystals or important locality for species. 
- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.