Ferrivauxite (original) (raw)

A valid IMA mineral species

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About FerrivauxiteHide

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Formula:

Fe3+Al2(PO4)2(OH)3 · 5H2O

Specific Gravity:

2.39 (Calculated)

Name:

After vauxite and the ferric content of the mineral.

An oxidized equivalent of vauxite. Also the lower hydrate equivalent of sigloite (the heptahydrate). Forms oxidation pseudomorphs after vauxite. Chemically similar to yet another Fe3+-Al phosphate, cacoxenite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:45990:1

7476b836-1635-4a78-a1c7-0000a1c994a2

IMA Classification of FerrivauxiteHide

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Classification of FerrivauxiteHide

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8.DC.

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Fvx IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FerrivauxiteHide

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Transparency:

Transparent, Translucent

Comment:

Estimated to be ∼3½ by comparison with vauxite

Cleavage:

None Observed
Shows no cleavage.

Fracture:

Irregular/Uneven

Density:

2.39 g/cm3 (Calculated)

Optical Data of FerrivauxiteHide

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RI values:

_n_α = 1.589(1) _n_β =
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(1) _n_γ = 1.596(1)
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δ = 0.007

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of FerrivauxiteHide

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Mindat Formula:

Fe3+Al2(PO4)2(OH)3 · 5H2O

Crystallography of FerrivauxiteHide

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Class (H-M):

1 - Pinacoidal

Cell Parameters:

a = 9.198(2) Å, b = 11.607(3) Å, c = 6.112(2) Å
α = 98.237(9)°, β = 91.90(1)°, γ = 108.658(9)°

Ratio:

a:b:c = 0.792 : 1 : 0.527

Unit Cell V:

609.68 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
10.834 Å (100)
8.682 Å (24)
8.242 Å (65)
6.018 Å (28)
5.918 Å (23)
5.491 Å (29)
4.338 Å (26)
2.898 Å (32)

Comments:

From Type Description.

Geological EnvironmentHide

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Type Occurrence of FerrivauxiteHide

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General Appearance of Type Material:

As oxidation pseudomorphs after vauxite

Place of Conservation of Type Material:

Collections of the Natural History Museum, University of Oslo, Norway, catalogue number 43576 and the Canadian Museum of Nature, Ottawa, Ontario, Canada

Associated Minerals at Type Locality:

Synonyms of FerrivauxiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DC. Ianbruceite Zn2(AsO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC. Césarferreiraite Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.05 Nissonite Cu2Mg2(PO4)2(OH)2 · 5H2O Mon. 2/m : _B_2/b
8.DC.07 Euchroite Cu2(AsO4)(OH) · 3H2O Orth. 222 : _P_212121
8.DC.10 Legrandite Zn2(AsO4)(OH) · H2O Mon. 2/m : _P_21/b
8.DC.12 Strashimirite Cu8(AsO4)4(OH)4 · 5H2O Mon.
8.DC.15 Arthurite CuFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Earlshannonite Mn2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Ojuelaite ZnFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Whitmoreite Fe2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Cobaltarthurite CoFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Bendadaite Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Kunatite CuFe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 UM2006-27-PO:FeHZn ZnFe3+2(PO4)2(OH)2 · 4H2O Mon.
8.DC.15 UKI-2006-(PO:AlCuFeH) Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.17 Kleemanite ZnAl2(PO4)2(OH)2 · 3H2O Mon.
8.DC.20 Bermanite Mn2+Mn3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_2/b
8.DC.20 Coralloite Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O Tric. 1 : _P_1
8.DC.20 Magnesiobermanite MgMn3+2(PO4)2(OH)2 · 4H2O Mon. 2 : _P_21
8.DC.22 Kovdorskite Mg2(PO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC.25 Ferristrunzite Fe3+Fe3+2(PO4)2(OH)3 · 5H2O Tric.
8.DC.25 Ferrostrunzite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric.
8.DC.25 Metavauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.25 Metavivianite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Strunzite Mn2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Zincostrunzite ZnFe3+2(PO4)2(OH)2 · 6.5H2O Tric. 1 : _P_1
8.DC.27 Beraunite Fe3+6(PO4)4O(OH)4 · 6H2O Mon. m : B b
8.DC.27 Tvrdýite Fe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2O Mon. 2/m : _B_2/b
8.DC.27 Zincoberaunite ZnFe3+5(PO4)4(OH)5 · 6H2O Mon. 2/m : _B_2/b
8.DC.30 Gordonite MgAl2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Laueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Mangangordonite Mn2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Paravauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Pseudolaueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.30 Sigloite Fe3+Al2(PO4)2(OH)3 · 7H2O Tric. 1 : _P_1
8.DC.30 Stewartite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ushkovite MgFe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ferrolaueite Fe2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Kastningite (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Maghrebite MgAl2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Nordgauite MnAl2(PO4)2(F,OH)2 · 5H2O Tric. 1 : _P_1
8.DC.30 Kayrobertsonite [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O Tric. 1 : _P_1
8.DC.30 Kummerite Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.32 Tinticite Fe3+3(PO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.32 Kamarizaite Fe3+3(AsO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.35 Vauxite Fe2+Al2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.37 Vantasselite Al4(PO4)3(OH)3 · 9H2O Orth.
8.DC.40 Cacoxenite Fe3+24AlO6(PO4)17(OH)12 · 75H2O Hex. 6/m : _P_63/m
8.DC.45 Gormanite (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric.
8.DC.45 Souzalite (Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric. 1
8.DC.47 Kingite Al3(PO4)2F2(OH) · 7H2O Tric.
8.DC.50 Wavellite Al3(PO4)2(OH,F)3 · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.50 Allanpringite Fe3+3(PO4)2(OH)3 · 5H2O Mon. 2/m : _P_21/m
8.DC.50 Fluorwavellite Al3(PO4)2(OH)2F · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.52 Kribergite Al5(PO4)3(SO4)(OH)4 · 4H2O Tric. 1 : _P_1
8.DC.55 Mapimite Zn2Fe3+3(AsO4)3(OH)4 · 10H2O Mon. m : B m
8.DC.57 Ogdensburgite Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m m m
8.DC.60 Nevadaite (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.60 Cloncurryite Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O Mon. 2/m : _P_21/b
8.DC.62 Kenngottite Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : _P_2/b
8.DC.67 Molinelloite Cu(H2O)(OH)V4+O(V5+O4) Tric. 1 : _P_1
8.DC.70 Whitecapsite H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O Hex. 6/m : _P_63/m
8.DC.75 Heimite PbCu2(AsO4)(OH)3 · 2H2O Mon. 2/m
8.DC.80 Lednevite Cu[PO3(OH)] · H2O Mon. 2/m : _P_21/b

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for FerrivauxiteHide

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Localities for FerrivauxiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Bolivia (TL)
Potosí Rafael Bustillo Province Llallagua Siglo Veinte Mine (TL) Williams et al. (2014) +2 other references