Mapimite (original) (raw)

A valid IMA mineral species

02759740015154296455381.jpg

02759740015154296455381.jpg

02759740015154296455381.jpg

About MapimiteHide

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Formula:

Zn2Fe3+3(AsO4)3(OH)4 · 10H2O

Colour:

Blue, blue-green, green

Crystal System:

Monoclinic

Name:

After the type locality, the Ojuela Mine, Mapimí, Mun. de Mapimí, Durango, Mexico.

This page provides mineralogical data about Mapimite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2570:2

0bcc9dc3-b1fa-43f1-abf9-6a996335af32

IMA Classification of MapimiteHide

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Type description reference:

Classification of MapimiteHide

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8.DC.55

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1

42.8.7.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
8 : (AB)5(XO4)3Zq·xH2O

20.9.15

20 : Arsenates (also arsenates with phosphate, but without other anions)
9 : Arsenates of Fe

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Mpm IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MapimiteHide

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Colour:

Blue, blue-green, green

Comment:

variable due to trichroism

Cleavage:

Distinct/Good
{001} and {010}.

Density:

2.95(3) g/cm3 (Measured) 3.02(4) g/cm3 (Calculated)

Optical Data of MapimiteHide

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RI values:

_n_α = 1.672 _n_β = 1.678 _n_γ = 1.712

2V:

Measured: 50° , Calculated: 48°

δ = 0.040

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Y = b, Z ∧ a = 13°.

Comments:

X = pale yellow; Y = greenish yellow; Z = deep Prussian blue

Chemistry of MapimiteHide

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Mindat Formula:

Zn2Fe3+3(AsO4)3(OH)4 · 10H2O

Crystallography of MapimiteHide

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Crystal System:

Monoclinic

Cell Parameters:

a = 11.415(5) Å, b = 11.259(5) Å, c = 8.661(3) Å
β = 107.74(4)°

Ratio:

a:b:c = 1.014 : 1 : 0.769

Unit Cell V:

1,060.19 ų (Calculated from Unit Cell)

Twinning:

Polysynthetic on {001} with [104] pseudoaxis.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0009743 Mapimite Ginderow D, Cesbron F (1981) Structure de la mapimite, Zn2Fe3(AsO4)3(OH)4*10H2O Acta Crystallographica B37 1040-1043 1981 Ojuela, Mapimi, Durango, Mexico 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.24 Å (100)
7.83 Å (94)
4.662 Å (61)
3.883 Å (46)
3.217 Å (41)
2.826 Å (37)
3.451 Å (36)

Geological EnvironmentHide

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Type Occurrence of MapimiteHide

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General Appearance of Type Material:

rectangular tabular crystals

Place of Conservation of Type Material:

University of Pierre and Marie Curie, Paris, France.

Associated Minerals at Type Locality:

Reference:

Cesbron, F., Romero, S.M., Williams, A.S. (1981): La mapimite et l'ojuélaïte, deux nouveaux arséniates hydratés de zinc et de fer de la mine Ojuela, Mapimi, Mexique. Bulletin de Minéralogie: 104: 582-586.

Synonyms of MapimiteHide

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Other Language Names for MapimiteHide

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8.DC. Ianbruceite Zn2(AsO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC. Césarferreiraite Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC. Ferrivauxite Fe3+Al2(PO4)2(OH)3 · 5H2O Tric. 1 : _P_1
8.DC.05 Nissonite Cu2Mg2(PO4)2(OH)2 · 5H2O Mon. 2/m : _B_2/b
8.DC.07 Euchroite Cu2(AsO4)(OH) · 3H2O Orth. 222 : _P_212121
8.DC.10 Legrandite Zn2(AsO4)(OH) · H2O Mon. 2/m : _P_21/b
8.DC.12 Strashimirite Cu8(AsO4)4(OH)4 · 5H2O Mon.
8.DC.15 Arthurite CuFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Earlshannonite Mn2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Ojuelaite ZnFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Whitmoreite Fe2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Cobaltarthurite (Co,Mg)Fe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Bendadaite Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Kunatite CuFe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 UM2006-27-PO:FeHZn ZnFe3+2(PO4)2(OH)2 · 4H2O Mon.
8.DC.15 UKI-2006-(PO:AlCuFeH) Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.17 Kleemanite ZnAl2(PO4)2(OH)2 · 3H2O Mon.
8.DC.20 Bermanite Mn2+Mn3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_2/b
8.DC.20 Coralloite Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O Tric. 1 : _P_1
8.DC.20 Magnesiobermanite MgMn3+2(PO4)2(OH)2 · 4H2O Mon. 2 : _P_21
8.DC.22 Kovdorskite Mg2(PO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC.25 Ferristrunzite Fe3+Fe3+2(PO4)2(OH)3 · 5H2O Tric.
8.DC.25 Ferrostrunzite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric.
8.DC.25 Metavauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.25 Metavivianite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Strunzite Mn2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Zincostrunzite ZnFe3+2(PO4)2(OH)2 · 6.5H2O Tric. 1 : _P_1
8.DC.27 Beraunite Fe3+6(PO4)4O(OH)4 · 6H2O Mon. m : B b
8.DC.27 Tvrdýite Fe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2O Mon. 2/m : _B_2/b
8.DC.27 Zincoberaunite ZnFe3+5(PO4)4(OH)5 · 6H2O Mon. 2/m : _B_2/b
8.DC.30 Gordonite MgAl2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Laueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Mangangordonite Mn2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Paravauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Pseudolaueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.30 Sigloite Fe3+Al2(PO4)2(OH)3 · 7H2O Tric. 1 : _P_1
8.DC.30 Stewartite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ushkovite MgFe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ferrolaueite Fe2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Kastningite (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Maghrebite MgAl2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Nordgauite MnAl2(PO4)2(F,OH)2 · 5H2O Tric. 1 : _P_1
8.DC.30 Kayrobertsonite [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O Tric. 1 : _P_1
8.DC.30 Kummerite Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.32 Tinticite Fe3+3(PO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.32 Kamarizaite Fe3+3(AsO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.35 Vauxite Fe2+Al2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.37 Vantasselite Al4(PO4)3(OH)3 · 9H2O Orth.
8.DC.40 Cacoxenite Fe3+24AlO6(PO4)17(OH)12 · 75H2O Hex. 6/m : _P_63/m
8.DC.45 Gormanite (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric.
8.DC.45 Souzalite (Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric. 1
8.DC.47 Kingite Al3(PO4)2F2(OH) · 7H2O Tric.
8.DC.50 Wavellite Al3(PO4)2(OH,F)3 · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.50 Allanpringite Fe3+3(PO4)2(OH)3 · 5H2O Mon. 2/m : _P_21/m
8.DC.50 Fluorwavellite Al3(PO4)2(OH)2F · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.52 Kribergite Al5(PO4)3(SO4)(OH)4 · 4H2O Tric. 1 : _P_1
8.DC.57 Ogdensburgite Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m m m
8.DC.60 Nevadaite (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.60 Cloncurryite Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O Mon. 2/m : _P_21/b
8.DC.62 Kenngottite Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : _P_2/b
8.DC.67 Molinelloite Cu(H2O)(OH)V4+O(V5+O4) Tric. 1 : _P_1
8.DC.70 Whitecapsite H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O Hex. 6/m : _P_63/m
8.DC.75 Heimite PbCu2(AsO4)(OH)3 · 2H2O Mon. 2/m
8.DC.80 Lednevite Cu[PO3(OH)] · H2O Mon. 2/m : _P_21/b

Other InformationHide

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Thermal Behaviour:

Fuses readily to a brown scoria.
The DTA curve shows a sharp endothermic break at 190°C, a smaller one at 343°C, and an exothermic break at 638°C.

Notes:

Readily soluble in dilute acids.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for MapimiteHide

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Localities for MapimiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Greece
Attica East Attica Lavreotiki Lavrion mining district Agios Konstantinos (Kamariza) Mercati mines Christiana Mine
Mexico (TL)
Durango Mapimí Municipality Mapimí Ojuela Mine (TL) Cesbron et al. (1981)
Palomas Oriente Thomas P. Moore (2008)