Szenicsite (original) (raw)

A valid IMA mineral species

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About SzenicsiteHide

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Lustre:

Adamantine, Pearly

Crystal System:

Orthorhombic

Name:

Named after Zoltan "Terry" (b. 1947) and Marissa (b. 1950) Szenics, American mineral collectors who discovered the mineral.

The szenicsite occurrence was an isolated area, approximately 1 cubic meter in size, wherein the szenicsite occurred in cavities in a matrix rich in molybdenite and Cu-bearing powellite. The cavities were filled with a clay-like material. Outside of the szenicsite zone, the mineralization changed from szenicsite to lindgrenite, with decreasing copper. Thereafter, moving further out, the mineralization was lacking visible copper content and consisted of powellite blebs in the ore. (pers. comm. Terry Szenics to Chet Lemanski, 2006).

Note: the type locality was originally erroneously given as "Tierra Amarilla".

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3862:7

6361b5bf-87cb-43d7-b525-bd54dd959902

IMA Classification of SzenicsiteHide

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Type description reference:

Classification of SzenicsiteHide

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7.GB.10

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
G : Molybdates, Wolframates and Niobates
B : With additional anions and/or H2O

48.3.5.1

48 : ANHYDROUS MOLYBDATES AND TUNGSTATES
3 : Basic Anhydrous Molybdates and Tungstates

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Sze IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of SzenicsiteHide

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Pronunciation:

Play Recorded by Country
Sorry, your browser doesn't support HTML5 audio. Jolyon Ralph United Kingdom

Physical Properties of SzenicsiteHide

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Transparency:

Transparent, Translucent

Cleavage:

Distinct/Good
{100} and {010}, good.

Density:

4.26(5) g/cm3 (Measured) 4.279 g/cm3 (Calculated)

Comment:

Calculated value based on the empirical formula, the ideal formula gives 4.30.

Optical Data of SzenicsiteHide

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RI values:

_n_α = 1.886 _n_β = 1.892 _n_γ = 1.903

2V:

Measured: 74° (3), Calculated: 74°

Birefringence:

Low to moderate.

δ = 0.017

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X = b; Y = a; Z = c.

Comments:

X = yellow-green; Y = Z = green.

Chemistry of SzenicsiteHide

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Mindat Formula:

Cu3(MoO4)(OH)4

Crystallography of SzenicsiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 8.5201(8) Å, b = 12.545(1) Å, c = 6.0794(6) Å

Ratio:

a:b:c = 0.679 : 1 : 0.485

Unit Cell V:

649.79 ų (Calculated from Unit Cell)

Morphology:

Bladed crystals, lamellar on {100} and elongated parallel to [001], which are intergrown as radial aggregates about [001] resulting in lustrous, curved {010} faces. The dominant form is {100} with {010} common.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0014535 Szenicsite Burns P C (1998) The crystal structure of szenicsite, Cu3MoO4(OH)4 Mineralogical Magazine 62 461-469 1998 0 293
0014897 Szenicsite Stolz J, Armbruster T (1998) X-ray single-crystal structure refinement of szenicsite, Cu3MoO4(OH)4, and its relation to the structure of antlerite, Cu3SO4(OH)4 Neues Jahrbuch fur Mineralogie, Monatshefte 1998 278-288 1998 Jardinera No. 1, Inca de Oro, Atacama, Chile 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.591 Å (vs)
5.471 Å (s)
3.754 Å (s)
3.043 Å (s)
1.519 Å (s)
4.599 Å (m)
2.759 Å (m)
2.415 Å (m)

Geological EnvironmentHide

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Type Occurrence of SzenicsiteHide

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General Appearance of Type Material:

Dark green bladed crystals, that are intergrown as radial aggregates. Crystals are typically less than 1 cm, but up to 3 x 1 x 0.1 cm. They occur both freestanding in cavities and as fracture fillings. Terminated crystals are extremely rare.

Place of Conservation of Type Material:

Harvard University, Cambridge, Massachusetts, USA, 133734, 133735, 133738, 133739.

Geological Setting of Type Material:

A secondary mineral derived from the oxidation of primary bornite and mo1ybdenite.

Associated Minerals at Type Locality:

Reference:

Francis, C.A., Pitman, L.C., and Lange, D.E. (1994) Szenicsite, a new mineral from Tierra Amarilla, Chile. The Mineralogical Record: 25: 76.

Synonyms of SzenicsiteHide

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Other Language Names for SzenicsiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.GB. Wangpuite K3(PO4)(Mo12O36) Iso. m_3_m _(_4/_m_32/m ) : P n_3_m
7.GB. Natromolybdite Na2MoO4 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
7.GB. Ootannite Th4+2W6+4O16 · 5H2O Mon. 2/m : _P_21/b
7.GB.05 Lindgrenite Cu3(MoO4)2(OH)2 Mon. 2/m : _P_21/m
7.GB.15 Cuprotungstite Cu2(WO4)(OH)2 Tet. 422 : _P_41212
7.GB.15 UM1999-38-WO:CrV (V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3]
7.GB.15 Huenite Cu4(MoO4)3(OH)2 Trig. 3_m_ : P_31_c
7.GB.20 Phyllotungstite (H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K) Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
7.GB.25 Rankachite Ca0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2O Mon. 2/m : _P_21/m
7.GB.30 Ferrimolybdite Fe2(MoO4)3 · nH2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
7.GB.35 Anthoinite AlWO3(OH)3 Tric. 1
7.GB.35 Mpororoite WAlO3(OH)3 · 2(H2O) Tric.
7.GB.40 Obradovicite-KCu [K2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
7.GB.45 Mendozavilite-NaFe [Na2(H2O)15Fe3+(H2O)6][Mo8P2Fe3+3O35(OH)2] Mon. 2/m : _B_2/m
7.GB.45 Paramendozavilite [KAl4(H2O)30][Mo12P6Fe3+6O60(OH)13] Mon.
7.GB.45 Obradovicite-NaCu Na2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
7.GB.45 Obradovicite-NaNa [Na2(H2O)16Na(H2O)6][Mo8As2Fe3+3O33(OH)4] Orth.
7.GB.50 Tancaite-(Ce) FeCe(MoO4)3 · 3H2O Trig. 3 : _R_3
7.GB.50 Mendozavilite-NaCu [Na2(H2O)15Cu(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
7.GB.50 Mendozavilite-KCa [K2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
7.GB.60 Peterandresenite Mn4Nb6O19 · 14H2O Mon. 2/m : _B_2/m
7.GB.60 Melcherite Ba2Na2Mg[Nb6O19] · 6H2O Trig. 3 : _R_3
7.GB.60 Hansesmarkite Ca2Mn2Nb6O19 · 20H2O Tric. 1 : _P_1
7.GB.65 Ichnusaite Th(MoO4)2 · 3H2O Mon. 2/m : _P_21/b
7.GB.70 Markascherite Cu3(MoO4)(OH)4 Mon. 2/m : _P_21/m
7.GB.75 Nuragheite Th(MoO4)2 · H2O Mon. 2/m : _P_21/b
7.GB.80 Ophirite Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2O Tric. 1 : _P_1

Fluorescence of SzenicsiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for SzenicsiteHide

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Reference List:

Ismagilova, R.M., Zhitova, E.S., Zolotarev, A.A., Krivovichev, S.V. (2019) Jahn–Teller distortion and thermal expansion anisotropy: temperature-dependent behavior of lindgrenite, Cu3(MoO4)2(OH)2, szenicsite, Cu3(MoO4)(OH)4, and cupromolybdite, Cu3O(MoO4)2. Physics and Chemistry of Minerals: 46: 437–447.

Localities for SzenicsiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Chile (TL)
Atacama Chañaral Province Diego de Almagro Jardinera No. 1 Mine (TL) Francis et al. (1994) +2 other references
Copiapó Province Tierra Amarilla Las Pintadas mining district Cerro Pintado La Farola Mine Mike Scott S102238 fm Cureton #CYN ID ...
USA
Arizona Gila County Globe-Miami Mining District Miami-Inspiration Mining District Top of the World Carlota Mine Confirmed by Raman spectroscopy at the ...