Obradovicite-NaCu (original) (raw)
A valid IMA mineral species
Formula:
Na2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3]
Lustre:
Sub-Adamantine, Vitreous
Crystal System:
Orthorhombic
Name:
Named for its relationship to other obradovicite group minerals. The double suffix corresponds to the dominant cations in two different types of non-framework cation sites; in this case sodium and copper.
First recognized as a potential hypothetical member of the Betpakdalite group (IMA 10-E). Later in 2011, approved by IMA as a valid species. Found on the type specimen of obradovicite-KCu (formerly obradovicite) from the Chuquicamata mine, Chile.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:41948:0
07df2ac6-0673-4299-b8c5-3b5cb6a8f900
IMA Classification of Obradovicite-NaCuHide
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IMA Formula:
[Na2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3]
Type description reference:
Kampf, A. R., Mills, S. J., Rumsey, M. S., Dini, M., Birch, W. D., Spratt, J., Pluth, J. J., Steele, I. M., Jenkins, R. A., Pinch, W. W. (2012) The heteropolymolybdate family: structural relations, nomenclature scheme and new species. Mineralogical Magazine, 76 (5) 1175-1207 doi:10.1180/minmag.2012.076.5.09
Classification of Obradovicite-NaCuHide
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7.GB.45
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
G : Molybdates, Wolframates and Niobates
B : With additional anions and/or H2O
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Obr-NaCu | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Obradovicite-NaCuHide
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Pronunciation:
Play | Recorded by | Country |
---|---|---|
Sorry, your browser doesn't support HTML5 audio. | Jolyon Ralph | United Kingdom |
Physical Properties of Obradovicite-NaCuHide
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Streak:
Very pale yellowish green
Optical Data of Obradovicite-NaCuHide
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RI values:
_n_α = 1.790(3) _n_β = 1.798(3) _n_γ = 1.805
δ = 0.015
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Pleochroism:
Non-pleochroic
Chemistry of Obradovicite-NaCuHide
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Mindat Formula:
Na2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3]
Crystallography of Obradovicite-NaCuHide
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Crystal System:
Orthorhombic
Class (H-M):
m m m _(_2/_m_2/_m_2/m ) - Dipyramidal
Cell Parameters:
a = 14.872(4) Å, b = 11.091(3) Å, c = 15.032(4) Å
Ratio:
a:b:c = 1.341 : 1 : 1.355
Morphology:
Short bladed crystals, flattened on {001}, elongated parallel to [010]. Size: Up to ~0.1 mm in length. Forms observed: {001}, {110} and {101}. The {001} are showing striations paralllel to [010]. Often double terminated.
Twinning:
No twinning observed.
Comment:
Space group: Pnmb
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
10.483 Å | (43) |
8.936 Å | (100) |
7.452 Å | (21) |
3.226 Å | (25) |
2.980 Å | (25) |
2.898 Å | (29) |
2.773 Å | (22) |
2.598 Å | (23) |
Geological EnvironmentHide
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Type Occurrence of Obradovicite-NaCuHide
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General Appearance of Type Material:
Sugary aggregates intermixed with fragmented quartz crystals embedded in a porous boxwork of hematite and goethite.
Place of Conservation of Type Material:
Colorado School of Mines Geology Museum, Golden, Colorado, USA, catalogue number 86.496.
Geological Setting of Type Material:
Oxidation zone of porphyry copper deposit.
Associated Minerals at Type Locality:
Reference:
Kampf, A.R., Mills, S.J., Rumsey, M.S., Dini, M., Birch, W.D., Spratt, J., Pluth, J.J., Steele, I.M., Jenkins, R.A., Pinch, W.W. (2012): The heteropolymolybdate family: structural relations, nomenclature scheme and new species. Mineralogical Magazine, 76, 1175-1207.
Synonyms of Obradovicite-NaCuHide
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Relationship of Obradovicite-NaCu to other SpeciesHide
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Other Members of this group:
Related Minerals - Strunz-mindat GroupingHide
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7.GB. | Wangpuite | K3(PO4)(Mo12O36) | Iso. m_3_m _(_4/_m_32/m ) : P n_3_m |
---|---|---|---|
7.GB. | Natromolybdite | Na2MoO4 · 2H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
7.GB. | Ootannite | Th4+2W6+4O16 · 5H2O | Mon. 2/m : _P_21/b |
7.GB.05 | Lindgrenite | Cu3(MoO4)2(OH)2 | Mon. 2/m : _P_21/m |
7.GB.10 | Szenicsite | Cu3(MoO4)(OH)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m |
7.GB.15 | Cuprotungstite | Cu2(WO4)(OH)2 | Tet. 422 : _P_41212 |
7.GB.15 | UM1999-38-WO:CrV | (V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3] | |
7.GB.15 | Huenite | Cu4(MoO4)3(OH)2 | Trig. 3_m_ : P_31_c |
7.GB.20 | Phyllotungstite | (H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K) | Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c |
7.GB.25 | Rankachite | Ca0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2O | Mon. 2/m : _P_21/m |
7.GB.30 | Ferrimolybdite | Fe2(MoO4)3 · nH2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n |
7.GB.35 | Anthoinite | AlWO3(OH)3 | Tric. 1 |
7.GB.35 | Mpororoite | WAlO3(OH)3 · 2(H2O) | Tric. |
7.GB.40 | Obradovicite-KCu | [K2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] | Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a |
7.GB.45 | Mendozavilite-NaFe | [Na2(H2O)15Fe3+(H2O)6][Mo8P2Fe3+3O35(OH)2] | Mon. 2/m : _B_2/m |
7.GB.45 | Paramendozavilite | [KAl4(H2O)30][Mo12P6Fe3+6O60(OH)13] | Mon. |
7.GB.45 | Obradovicite-NaNa | [Na2(H2O)16Na(H2O)6][Mo8As2Fe3+3O33(OH)4] | Orth. |
7.GB.50 | Tancaite-(Ce) | FeCe(MoO4)3 · 3H2O | Trig. 3 : _R_3 |
7.GB.50 | Mendozavilite-NaCu | [Na2(H2O)15Cu(H2O)6][Mo8P2Fe3+3O34(OH)3] | Mon. 2/m : _B_2/m |
7.GB.50 | Mendozavilite-KCa | [K2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O34(OH)3] | Mon. 2/m : _B_2/m |
7.GB.60 | Peterandresenite | Mn4Nb6O19 · 14H2O | Mon. 2/m : _B_2/m |
7.GB.60 | Melcherite | Ba2Na2Mg[Nb6O19] · 6H2O | Trig. 3 : _R_3 |
7.GB.60 | Hansesmarkite | Ca2Mn2Nb6O19 · 20H2O | Tric. 1 : _P_1 |
7.GB.65 | Ichnusaite | Th(MoO4)2 · 3H2O | Mon. 2/m : _P_21/b |
7.GB.70 | Markascherite | Cu3(MoO4)(OH)4 | Mon. 2/m : _P_21/m |
7.GB.75 | Nuragheite | Th(MoO4)2 · H2O | Mon. 2/m : _P_21/b |
7.GB.80 | Ophirite | Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2O | Tric. 1 : _P_1 |
Fluorescence of Obradovicite-NaCuHide
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Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Obradovicite-NaCuHide
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References for Obradovicite-NaCuHide
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Reference List:
Kampf, A. R., Mills, S. J., Rumsey, M. S., Dini, M., Birch, W. D., Spratt, J., Pluth, J. J., Steele, I. M., Jenkins, R. A., Pinch, W. W. (2012) The heteropolymolybdate family: structural relations, nomenclature scheme and new species. Mineralogical Magazine, 76 (5) 1175-1207 doi:10.1180/minmag.2012.076.5.09
Localities for Obradovicite-NaCuHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Chile (TL) | |
---|---|
Antofagasta El Loa Province Calama Chuquicamata District ⓘ Chuquicamata Mine (TL) | Williams et al. (2011) +1 other reference |