Huenite (original) (raw)
A valid IMA mineral species
About HueniteHide
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author's formula: Cu4Mo3O12(OH)2
Colour:
Very dark reddish-brown
Lustre:
Adamantine, Vitreous
Specific Gravity:
5.1 (Calculated)
Name:
Named in honor of Edgar Huen (b. 27 May 1947, Milan, Italy), a mineral collector and an expert in Alpine fissure minerals and worldwide systematic mineralogy. He co-discovered the mineral.
Chemically close to lindgrenite, markascherite, and szenicsite. Structure of the mineral is determined.
Reported as copper-molybdenum oxy-hydroxide mineral. Associates include an unknown pale purple phase.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:47779:4
a1a6929a-a478-4edf-b196-ee2ce96b3acb
IMA Classification of HueniteHide
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Type description reference:
Vignola, Pietro, Rotiroti, Nicola, Gatta, G. Diego, Risplendente, Andrea, Hatert, Frédéric, Bersani, Danilo, Mattioli, Vittorio (2019) Huenite, Cu4Mo3O12(OH)2, a New Copper-molybdenum Oxy-hydroxide Mineral from the San Samuel Mine, Carrera Pinto, Cachiyuyo De Llampos District, CopiapÓ Province, Atacama Region, Chile. The Canadian Mineralogist, 57 (4) 467-474 doi:10.3749/canmin.1900011
Classification of HueniteHide
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7.GB.15
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
G : Molybdates, Wolframates and Niobates
B : With additional anions and/or H2O
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Hue | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of HueniteHide
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Colour:
Very dark reddish-brown
Streak:
Pale reddish-brown to pinkish
Cleavage:
Distinct/Good
on {010}
Fracture:
Irregular/Uneven
Density:
5.1 g/cm3 (Calculated)
Chemistry of HueniteHide
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Mindat Formula:
Cu4(MoO4)3(OH)2
author's formula: Cu4Mo3O12(OH)2
Crystallography of HueniteHide
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Class (H-M):
3_m_ - Ditrigonal Pyramidal
Cell Parameters:
a = 7.653(5) Å, c = 9.411(6) Å
Morphology:
Flattened orthorhombic prisms up to 60–70 μm in size, weakly elongated along [001].
Comment:
Space group in original IMA list erroneously reported as "P31/c"; later this misprint was corrected to P31c.
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
6.786 Å | (25) |
5.372 Å | (24) |
3.810 Å | (51) |
2.974 Å | (100) |
2.702 Å | (41) |
2.497 Å | (38) |
1.712 Å | (60) |
1.450 Å | (37) |
Geological EnvironmentHide
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Type Occurrence of HueniteHide
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General Appearance of Type Material:
Flattened, orthorhombic prisms, up to 60–70 μm in diameter, and weakly elongated along [001]; these form aggregates, up to 1 mm in diameter
Place of Conservation of Type Material:
Collections of the Laboratoire de Minéralogie, University of Liège, Belgium (catalogue no. 20399)
Empirical Formula of Type Material:
(Cu3.519Fe2+0.403)Σ3.922(Mo2.907S0.090Si0.003)Σ3.000O12·(OH)2.229
Geological Setting of Type Material:
Fractures in a quartz breccia
Associated Minerals at Type Locality:
Reference:
Vignola, P., Rotiroti, N., Gatta, G.D., Risplendente, A., Hatert, F., Bersani, D., Mattioli, V. (2019): Huenite, Cu4Mo3O12(OH)2, a New Copper-molybdenum Oxy-hydroxide Mineral from the San Samuel Mine, Carrera Pinto, Cachiyuyo De Llampos District, Copiapo Province, Atacama Region, Chile. The Canadian Mineralogist: 57: 467-474.
Synonyms of HueniteHide
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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7.GB. | Wangpuite | K3(PO4)(Mo12O36) | Iso. m_3_m _(_4/_m_32/m ) : P n_3_m |
---|---|---|---|
7.GB. | Natromolybdite | Na2MoO4 · 2H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
7.GB. | Ootannite | Th4+2W6+4O16 · 5H2O | Mon. 2/m : _P_21/b |
7.GB.05 | Lindgrenite | Cu3(MoO4)2(OH)2 | Mon. 2/m : _P_21/m |
7.GB.10 | Szenicsite | Cu3(MoO4)(OH)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m |
7.GB.15 | Cuprotungstite | Cu2(WO4)(OH)2 | Tet. 422 : _P_41212 |
7.GB.15 | UM1999-38-WO:CrV | (V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3] | |
7.GB.20 | Phyllotungstite | (H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K) | Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c |
7.GB.25 | Rankachite | Ca0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2O | Mon. 2/m : _P_21/m |
7.GB.30 | Ferrimolybdite | Fe2(MoO4)3 · nH2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n |
7.GB.35 | Anthoinite | AlWO3(OH)3 | Tric. 1 |
7.GB.35 | Mpororoite | WAlO3(OH)3 · 2(H2O) | Tric. |
7.GB.40 | Obradovicite-KCu | [K2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] | Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a |
7.GB.45 | Mendozavilite-NaFe | [Na2(H2O)15Fe3+(H2O)6][Mo8P2Fe3+3O35(OH)2] | Mon. 2/m : _B_2/m |
7.GB.45 | Paramendozavilite | [KAl4(H2O)30][Mo12P6Fe3+6O60(OH)13] | Mon. |
7.GB.45 | Obradovicite-NaCu | Na2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] | Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a |
7.GB.45 | Obradovicite-NaNa | [Na2(H2O)16Na(H2O)6][Mo8As2Fe3+3O33(OH)4] | Orth. |
7.GB.50 | Tancaite-(Ce) | FeCe(MoO4)3 · 3H2O | Trig. 3 : _R_3 |
7.GB.50 | Mendozavilite-NaCu | [Na2(H2O)15Cu(H2O)6][Mo8P2Fe3+3O34(OH)3] | Mon. 2/m : _B_2/m |
7.GB.50 | Mendozavilite-KCa | [K2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O34(OH)3] | Mon. 2/m : _B_2/m |
7.GB.60 | Peterandresenite | Mn4Nb6O19 · 14H2O | Mon. 2/m : _B_2/m |
7.GB.60 | Melcherite | Ba2Na2Mg[Nb6O19] · 6H2O | Trig. 3 : _R_3 |
7.GB.60 | Hansesmarkite | Ca2Mn2Nb6O19 · 20H2O | Tric. 1 : _P_1 |
7.GB.65 | Ichnusaite | Th(MoO4)2 · 3H2O | Mon. 2/m : _P_21/b |
7.GB.70 | Markascherite | Cu3(MoO4)(OH)4 | Mon. 2/m : _P_21/m |
7.GB.75 | Nuragheite | Th(MoO4)2 · H2O | Mon. 2/m : _P_21/b |
7.GB.80 | Ophirite | Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2O | Tric. 1 : _P_1 |
Fluorescence of HueniteHide
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Non-fluorescent (SWUV & LWUV)
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for HueniteHide
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References for HueniteHide
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Reference List:
Vignola, Pietro, Rotiroti, Nicola, Gatta, G. Diego, Risplendente, Andrea, Hatert, Frédéric, Bersani, Danilo, Mattioli, Vittorio (2019) Huenite, Cu4Mo3O12(OH)2, a New Copper-molybdenum Oxy-hydroxide Mineral from the San Samuel Mine, Carrera Pinto, Cachiyuyo De Llampos District, CopiapÓ Province, Atacama Region, Chile. The Canadian Mineralogist, 57 (4) 467-474 doi:10.3749/canmin.1900011
Localities for HueniteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Chile | |
---|---|
Antofagasta El Loa Province Calama Chuquicamata District ⓘ Chuquicamata Mine | Andreas Schloth specimen & SEM-EDS. |
Atacama Copiapó Province Copiapó Cachiyuyo de Llampos mining district Carrera Pinto ⓘ San Samuel Mine ("San Manuel Mine") (TL) | Mineralogical Magazine +2 other references |