Whitlockite (original) (raw)
A valid IMA mineral species - grandfathered
About WhitlockiteHide
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Formula:
Ca9Mg(PO4)6(PO3OH)
The given IMA formula (not editable here) for whitlockite shows the monofluorophosphate (PO3F)2- ion rather than hydroxylated phosphate (PO3OH)2- ion. The latter anionic group is correct; the former, attributed to the now-discredited whitlockite group mineral bobdownsite, was determined to be an analytical error.
Colour:
Colourless, grey-white, light pink, light yellow; colourless in transmitted light.
Lustre:
Vitreous, Resinous
Name:
Named after Herbert Percy Whitlock (31 July 1868, New York City, New York, USA - 22 February 1948), Curator of Minerals, American Museum of Natural History, New York (USA).
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:4280:8
8da5f0d5-3c9e-4ff3-9506-81529b44f250
IMA Classification of WhitlockiteHide
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Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca9Mg(PO3OH)(PO4)6
Type description reference:
Classification of WhitlockiteHide
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8.AC.45
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
38.3.4.1
38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
3 : (AB)3(XO4)2
19.4.8
19 : Phosphates
4 : Phosphates of Ca
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Wht | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Wht | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Physical Properties of WhitlockiteHide
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Transparency:
Transparent, Translucent
Colour:
Colourless, grey-white, light pink, light yellow; colourless in transmitted light.
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
3.12 g/cm3 (Measured) 3.102 g/cm3 (Calculated)
Optical Data of WhitlockiteHide
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RI values:
_n_ω = 1.629 _n_ε = 1.626
δ = 0.003
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Chemistry of WhitlockiteHide
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Mindat Formula:
Ca9Mg(PO4)6(PO3OH)
The given IMA formula (not editable here) for whitlockite shows the monofluorophosphate (PO3F)2- ion rather than hydroxylated phosphate (PO3OH)2- ion. The latter anionic group is correct; the former, attributed to the now-discredited whitlockite group mineral bobdownsite, was determined to be an analytical error.
Crystallography of WhitlockiteHide
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Class (H-M):
3_m_ - Ditrigonal Pyramidal
Cell Parameters:
a = 10.33 Å, c = 37.103(5) Å
Unit Cell V:
3,428.79 ų (Calculated from Unit Cell)
Morphology:
Crystals exhibit rhombohedral development; rarely tabular {0001}. Coarse-granular to earthy. Cave pearls.
Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000445 | Whitlockite | Calvo C, Gopal R (1975) The crystal structure of whitlockite from the Palermo quarry American Mineralogist 60 120-133 | 1975 | 0 | 293 | ||
0004622 | Whitlockite | Hughes J M, Jolliff B L, Rakovan J (2008) The crystal chemistry of whitlockite and merrillite and the dehydrogenation of whitlockite to merrillite American Mineralogist 93 1300-1305 | 2008 | Palermo Mine, North Groton, Grafton County, New Hampshire | 0 | 293 | |
0004623 | Whitlockite | Hughes J M, Jolliff B L, Rakovan J (2008) The crystal chemistry of whitlockite and merrillite and the dehydrogenation of whitlockite to merrillite American Mineralogist 93 1300-1305 | 2008 | Tip Top Pegmatite, Custer County, South Dakota | 0 | 293 | |
0004624 | Whitlockite | Hughes J M, Jolliff B L, Rakovan J (2008) The crystal chemistry of whitlockite and merrillite and the dehydrogenation of whitlockite to merrillite American Mineralogist 93 1300-1305 | 2008 | synthetic | 0 | 293 | |
0004625 | Whitlockite | Hughes J M, Jolliff B L, Rakovan J (2008) The crystal chemistry of whitlockite and merrillite and the dehydrogenation of whitlockite to merrillite American Mineralogist 93 1300-1305 | 2008 | synthetic | 0 | 293 | |
0018920 | Whitlockite | Tait K T, Barkley M C, Thompson R M, Origlieri M J, Evans S H, Prewitt C T, Yang H (2011) Bobdownsite, a new mineral species from Big Fish River, Yukon, Canada, and its structural relationship with whitlockite-type compounds The Canadian Mineralogist 49 1065-1078 | 2011 | Palermo #1 quarry, New Hampshire, USA | 0 | 293 | |
0009550 | Whitlockite | Kostiner E, Rea J R (1976) The crystal structure of manganese-whitlockite, Ca18Mn2H2(PO4)14 Acta Crystallographica B32 250-253 | 1976 | synthetic | 0 | 293 | |
0010333 | Whitlockite | Tsirlin A A, Dikarev E V, Shpanchenko R V, Antipov E V (2006) A new whitlockite, Ca8.42Na1.16V(PO4)7 Acta Crystallographica C62 i13-i15 | 2006 | synthetic | 0 | 293 | |
0012160 | Whitlockite | Gopal R, Calvo C, Ito J, Sabine W K (1974) Crystal structure of synthetic Mg-whitlockite, Ca18Mg2H2(PO4)14 Canadian Journal of Chemistry 52 1155-1164 | 1974 | synthetic | 0 | 293 | |
0013351 | Whitlockite | Schroeder L W, Dickens B, Brown W E (1977) Crystallographic studies of the role of Mg as a stabilizing impurity in beta-Ca3(PO4)2. II. Refinement of Mg-containing beta-Ca3(PO4)2 Journal of Solid State Chemistry 22 253-262 | 1977 | synthetic | 0 | 293 | |
0013352 | Whitlockite | Schroeder L W, Dickens B, Brown W E (1977) Crystallographic studies of the role of Mg as a stabilizing impurity in beta-Ca3(PO4)2. II. Refinement of Mg-containing beta-Ca3(PO4)2 Journal of Solid State Chemistry 22 253-262 | 1977 | synthetic | 0 | 293 | |
0014685 | Whitlockite | Gopal R, Calvo C (1972) Structural relationship of whitlockite and beta-Ca3(PO4)2 Nature Physical Science 237 30-32 | 1972 | Palermo Quarry | 0 | 293 | |
0014686 | Whitlockite | Gopal R, Calvo C (1972) Structural relationship of whitlockite and beta-Ca3(PO4)2 Nature Physical Science 237 30-32 | 1972 | Palermo Quarry | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder DiffractionHide
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Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.88 Å | (100) |
3.21 Å | (90) |
2.60 Å | (90) |
5.24 Å | (80) |
3.47 Å | (70) |
1.72 Å | (70) |
1.93 Å | (60) |
6.55 Å | (50) |
1.88 Å | (50) |
1.55 Å | (50) |
Comments:
North Groton, New Hampshire, USA. Data from Frondel (1943).
Geological EnvironmentHide
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Geological Setting:
Pegmatites; phosphate-rock deposits.
Type Occurrence of WhitlockiteHide
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General Appearance of Type Material:
Occurs as coarse granular masses with small open cavities lined with crystals. The crystals range in size from about 1 mm to 1.5 cm along the c-axis with an embedded crystal measuring about 3 cm. The crystals usually are simple rhombohedra.
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, 95030; National Museum of Natural History, Washington, D.C., USA, 146196.
Geological Setting of Type Material:
Associated Minerals at Type Locality:
Reference:
Frondel, C. (1941) Whitlockite: a new calcium phosphate, Ca3(PO4)2. American Mineralogist: 26: 145-152.
Synonyms of WhitlockiteHide
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Other Language Names for WhitlockiteHide
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Varieties of WhitlockiteHide
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Relationship of Whitlockite to other SpeciesHide
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Other Members of this group:
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O | Orth. 222 : _C_2221 |
---|---|---|---|
8.AC. | Wopmayite | Ca6Na3◻Mn(PO4)3(PO3OH)4 | Trig. 3_m_ : R_3_c |
8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 | Tric. 1 : _P_1 |
8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 | Tric. 1 : _P_1 |
8.AC. | Crocobelonite | CaFe3+2O(PO4)2 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC. | Beershevaite | CaFe3+3(PO4)3O | Mon. 2/m : _P_21/m |
8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 | Tric. 1 : _P_1 |
8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
8.AC. | Changesite–(Y) | (Ca8Y)◻Fe2+(PO4)7 | Trig. 3_m_ : R_3_c |
8.AC. | Crocobelonite-1M | CaFe3+2O(PO4)2 | Mon. 2/m : _P_21/m |
8.AC. | Ebnerite | (NH4)Zn(PO4) | Hex. 6 : _P_63 |
8.AC. | Magnesioqingheiite | Na2Mg(MgAl)(PO4)3 | Mon. 2/m |
8.AC. | Epiebnerite | (NH4)Zn(PO4) | Mon. 2 : _P_21 |
8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 | Tric. 1 : _P_1 |
8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 | Tric. 1 : _P_1 |
8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 | Tric. 1 : _P_1 |
8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Howardevansite | NaCuFe2(VO4)3 | Tric. 1 : _P_1 |
8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 | Mon. 2/m : _B_2/b |
8.AC.05 va | Alluaudite-Na□ | ◻4Na4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : _B_2/b |
8.AC.05 va | Alluaudite-Ca□ | ◻4Ca4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : _B_2/b |
8.AC.05 va | Ferroalluaudite-NaNa | Na4Na4Fe2+4Fe3+8(PO4)12 | Mon. 2/m : _B_2/m |
8.AC.05 | Hagendorfite-NaNa | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) | Mon. 2/m : _B_2/b |
8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O | Mon. 2/m : _B_2/m |
8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Unnamed (Na-Mg Arsenate Hydroxyarsenate) | NaMg3(AsO4)(AsO3OH)2 | Mon. 2/m : _B_2/b |
8.AC.05 | Unnamed (Na-Zn-H Arsenate Hydroxyarsenate) | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 | Mon. 2/m : _B_2/b |
8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] | Mon. 2/m : _B_2/b |
8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 | Mon. 2/m : _B_2/b |
8.AC.05 | Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 | Mon. 2/m |
8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 | Mon. |
8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 | Mon. 2/m |
8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 | Mon. 2/m |
8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 | Mon. 2/m |
8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Ferrohagendorfite | NaCaFe2+Fe2+2(PO4)3 | Mon. |
8.AC.10 | Bradaczekite | NaCu4(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 | Mon. 2/m : _B_2/b |
8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 | Mon. 2/m : _P_2/b |
8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 | Mon. 2/m : _P_21/b |
8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 | Mon. 2/m : _P_21/b |
8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 | Mon. 2/m : _P_21/b |
8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 | Mon. 2/m : _P_21/m |
8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 | Mon. m : P b |
8.AC.20 | Marićite | NaFe2+(PO4) | Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a |
8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) | Trig. 3_m_ : R_3_c |
8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 | Trig. 3_m_ : R_3_c |
8.AC.30 | Brianite | Na2CaMg(PO4)2 | Mon. 2/m : _P_21/b |
8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 | Orth. m _m_2 : P c _a_21 |
8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 | Trig. 3_m_ _(_32/m ) : _P_3_m_1 |
8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · | Trig. 3 : _P_3 |
8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) | Trig. 3_m_ : R_3_c |
8.AC.45 | Merrillite | Ca9NaMg(PO4)7 | Trig. 3_m_ : R_3_m |
8.AC.45 | Tuite | Ca3(PO4)2 | Trig. 3_m_ _(_32/m ) : R_3_m |
8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 | Trig. 3_m_ : R_3_c |
8.AC.47 | Iwateite | Na2BaMn(PO4)2 | Trig. 3 : _P_3 |
8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 | Trig. 3_m_ _(_32/m ) : R_3_c |
8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a |
8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 | Trig. 3_m_ _(_32/m ) : R_3_c |
8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 | Orth. m m m _(_2/_m_2/_m_2/m ) |
8.AC.50 | Chladniite | Na3CaMg11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 | Tric. 1 : _P_1 |
8.AC.50 | Udinaite | NaMg4(VO4)3 | Tet. 42_m_ : I_42_d |
8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 | Tet. 42_m_ : I_42_d |
8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n |
8.AC.55 | Pharmazincite | KZnAsO4 | Hex. 6 : _P_63 |
8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 | Mon. 2 : _B_2 |
8.AC.60 | Kosnarite | KZr2(PO4)3 | Trig. 3_m_ _(_32/m ) : R_3_c |
8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 | Mon. 2/m : _P_21/b |
8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 | Mon. |
8.AC.75 | Ronneburgite | K2MnV4O12 | Mon. 2/m |
8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] | Tet. 4 : _I_4 |
8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 | Mon. 2/m |
Fluorescence of WhitlockiteHide
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Other InformationHide
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IR Spectrum:
Spectrum very similar to that of synthetic tricalcium phosphate.
Electrical:
Piezoelectric, pyroelectric.
Notes:
Readily soluble in dilute acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for WhitlockiteHide
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References for WhitlockiteHide
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Reference List:
Tait, K. T., Barkley, M. C., Thompson, R. M., Origlieri, M. J., Evans, S. H., Prewitt, C. T., Yang, H. (2011) Bobdownsite, a new mineral species from Big FIsh River, Yukon, Canada, and its structural relationship with whitlockite-type compounds. The Canadian Mineralogist, 49 (4) 1065-1078 doi:10.3749/canmin.49.4.1065
Localities for WhitlockiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.