Wopmayite (original) (raw)
A valid IMA mineral species
Formula:
Ca6Na3◻Mn(PO4)3(PO3OH)4
Colour:
Colorless to white to pale pink
Specific Gravity:
3.027 (Calculated)
Name:
After Wilfrid Reid “Wop” May (March 20, 1896 – June 21, 1952) who was born in Carberry, Manitoba, Canada. “Wop” May was a pioneering aviator who created the role of the bush pilot, and opened up the Canadian North to mineral exploration and mining.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:42881:3
9bb1c5db-f88b-4f7e-8fe7-74cb565eb41e
IMA Classification of WopmayiteHide
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IMA Formula:
Ca6Na3◻Mn(PO4)3(PO3OH)4
Type description reference:
Cooper, Mark A., Hawthorne, Frank C., Abdu, Yassir A., Ball, Neil A., Ramik, Robert A., Tait, Kimberly T. (2013) Wopmayite, ideally Ca6Na3Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure. The Canadian Mineralogist, 51 (1) 93-106 doi:10.3749/canmin.51.1.93
Classification of WopmayiteHide
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8.AC.
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Wop | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of WopmayiteHide
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Colour:
Colorless to white to pale pink
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
3.027 g/cm3 (Calculated)
Optical Data of WopmayiteHide
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RI values:
_n_ω = 1.617(2) _n_ε = 1.613(2)
δ = 0.004
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Chemistry of WopmayiteHide
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Mindat Formula:
Ca6Na3◻Mn(PO4)3(PO3OH)4
Crystallography of WopmayiteHide
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Class (H-M):
3_m_ - Ditrigonal Pyramidal
Cell Parameters:
a = 10.3926(2) Å, c = 37.1694(9) Å
Unit Cell V:
3,476.68 ų (Calculated from Unit Cell)
Morphology:
Rhombohedron {10-11}.
Twinning:
No visible twinning
Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0019803 | Wopmayite | Cooper M A, Hawthorne F C, Abdu Y A, Ball N A, Ramik R A, Tait K T (2013) Wopmayite, ideally Ca6Na3[]Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure The Canadian Mineralogist 51 93-106 | 2013 | the Tanco Mine, Bernic Lake, Manitoba, Canada | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
8.017 Å | (31) |
6.421 Å | (32) |
5.166 Å | (33) |
3.425 Å | (29) |
3.186 Å | (88) |
2.858 Å | (100) |
2.736 Å | (27) |
2.589 Å | (68) |
Geological EnvironmentHide
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Type Occurrence of WopmayiteHide
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General Appearance of Type Material:
Corroded rhombic crystals ~150 µm across.
Place of Conservation of Type Material:
Department of Natural History, Royal Ontario Museum, Toronto, Ontario, Canada, catalogue number M40501.
Geological Setting of Type Material:
Zoned petalite-subgroup pegmatite after dissolution of primary lithiophosphate by hydrothermal solutions.
Associated Minerals at Type Locality:
Reference:
Cooper, M.A., Hawthorne, F.C., Abdu, Y.A., Ball, N.A., Ramik, R.A., Tait, K.T. (2013) Wopmayite, ideally Ca6Na3Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure. The Canadian Mineralogist: 51: 93-106.
Synonyms of WopmayiteHide
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Relationship of Wopmayite to other SpeciesHide
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Other Members of this group:
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O | Orth. 222 : _C_2221 |
---|---|---|---|
8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 | Tric. 1 : _P_1 |
8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 | Tric. 1 : _P_1 |
8.AC. | Crocobelonite | CaFe3+2O(PO4)2 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC. | Beershevaite | CaFe3+3(PO4)3O | Mon. 2/m : _P_21/m |
8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 | Tric. 1 : _P_1 |
8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
8.AC. | Changesite–(Y) | (Ca8Y)◻Fe2+(PO4)7 | Trig. 3_m_ : R_3_c |
8.AC. | Crocobelonite-1M | CaFe3+2O(PO4)2 | Mon. 2/m : _P_21/m |
8.AC. | Ebnerite | (NH4)Zn(PO4) | Hex. 6 : _P_63 |
8.AC. | Magnesioqingheiite | Na2Mg(MgAl)(PO4)3 | Mon. 2/m |
8.AC. | Epiebnerite | (NH4)Zn(PO4) | Mon. 2 : _P_21 |
8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 | Tric. 1 : _P_1 |
8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 | Tric. 1 : _P_1 |
8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 | Tric. 1 : _P_1 |
8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Howardevansite | NaCuFe2(VO4)3 | Tric. 1 : _P_1 |
8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 | Mon. 2/m : _B_2/b |
8.AC.05 va | Alluaudite-Na□ | ◻4Na4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : _B_2/b |
8.AC.05 va | Alluaudite-Ca□ | ◻4Ca4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : _B_2/b |
8.AC.05 va | Ferroalluaudite-NaNa | Na4Na4Fe2+4Fe3+8(PO4)12 | Mon. 2/m : _B_2/m |
8.AC.05 | Hagendorfite-NaNa | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) | Mon. 2/m : _B_2/b |
8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O | Mon. 2/m : _B_2/m |
8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Unnamed (Na-Mg Arsenate Hydroxyarsenate) | NaMg3(AsO4)(AsO3OH)2 | Mon. 2/m : _B_2/b |
8.AC.05 | Unnamed (Na-Zn-H Arsenate Hydroxyarsenate) | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 | Mon. 2/m : _B_2/b |
8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] | Mon. 2/m : _B_2/b |
8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 | Mon. 2/m : _B_2/b |
8.AC.05 | Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 | Mon. 2/m |
8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 | Mon. |
8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 | Mon. 2/m |
8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 | Mon. 2/m |
8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 | Mon. 2/m |
8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Ferrohagendorfite | NaCaFe2+Fe2+2(PO4)3 | Mon. |
8.AC.10 | Bradaczekite | NaCu4(AsO4)3 | Mon. 2/m : _B_2/b |
8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 | Mon. 2/m : _B_2/b |
8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 | Mon. 2/m : _P_2/b |
8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 | Mon. 2/m : _P_21/b |
8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 | Mon. 2/m : _P_21/b |
8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 | Mon. 2/m : _P_21/b |
8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 | Mon. 2/m : _P_21/m |
8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 | Mon. m : P b |
8.AC.20 | Marićite | NaFe2+(PO4) | Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a |
8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 | Iso. m_3_m _(_4/_m_32/m ) : I a_3_d |
8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) | Trig. 3_m_ : R_3_c |
8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 | Trig. 3_m_ : R_3_c |
8.AC.30 | Brianite | Na2CaMg(PO4)2 | Mon. 2/m : _P_21/b |
8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 | Orth. m _m_2 : P c _a_21 |
8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 | Trig. 3_m_ _(_32/m ) : _P_3_m_1 |
8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · | Trig. 3 : _P_3 |
8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) | Trig. 3_m_ : R_3_c |
8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) | Trig. 3_m_ : R_3_c |
8.AC.45 | Merrillite | Ca9NaMg(PO4)7 | Trig. 3_m_ : R_3_m |
8.AC.45 | Tuite | Ca3(PO4)2 | Trig. 3_m_ _(_32/m ) : R_3_m |
8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 | Trig. 3_m_ : R_3_c |
8.AC.47 | Iwateite | Na2BaMn(PO4)2 | Trig. 3 : _P_3 |
8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 | Trig. 3_m_ _(_32/m ) : R_3_c |
8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 | Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a |
8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 | Trig. 3_m_ _(_32/m ) : R_3_c |
8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 | Orth. m m m _(_2/_m_2/_m_2/m ) |
8.AC.50 | Chladniite | Na3CaMg11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 | Trig. 3 : _R_3 |
8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 | Tric. 1 : _P_1 |
8.AC.50 | Udinaite | NaMg4(VO4)3 | Tet. 42_m_ : I_42_d |
8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 | Tet. 42_m_ : I_42_d |
8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n |
8.AC.55 | Pharmazincite | KZnAsO4 | Hex. 6 : _P_63 |
8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 | Mon. 2 : _B_2 |
8.AC.60 | Kosnarite | KZr2(PO4)3 | Trig. 3_m_ _(_32/m ) : R_3_c |
8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 | Mon. 2/m : _P_21/b |
8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 | Mon. |
8.AC.75 | Ronneburgite | K2MnV4O12 | Mon. 2/m |
8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] | Tet. 4 : _I_4 |
8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 | Mon. 2/m |
Fluorescence of WopmayiteHide
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Other InformationHide
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IR Spectrum:
IR absorption bands (cm–1, s = strong, m = medium, w = weak) 2830s and 2395s (O−H stretching), 1720m and 1651m (combinations), 1345s (P−O−H bending vibration), 1185s, 1090s, 994w, and 947w (various stretching bands of the PO4 group), 870w (P–OH stretching).
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for WopmayiteHide
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References for WopmayiteHide
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Reference List:
Cooper, Mark A., Hawthorne, Frank C., Abdu, Yassir A., Ball, Neil A., Ramik, Robert A., Tait, Kimberly T. (2013) Wopmayite, ideally Ca6Na3Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure. The Canadian Mineralogist, 51 (1) 93-106 doi:10.3749/canmin.51.1.93
Localities for WopmayiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Canada (TL) | |
---|---|
Manitoba Lac-du-Bonnet area Bernic Lake ⓘ Tanco Mine (TL) | Williams et al. (2012) +1 other reference |