Crocobelonite (original) (raw)

A valid IMA mineral species

08051660017056126006947.jpg

08051660017056126006947.jpg

08051660017056126006947.jpg

About CrocobeloniteHide

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Colour:

saffron red to pinkish red

Specific Gravity:

3.555 (Calculated)

Crystal System:

Orthorhombic

Name:

From Greek κρόκος (saffron) and βελόνα 81 (needle), for the orange-red colour and prismatic to acicular habit of its crystals.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:54653:5

e307084a-acbf-4cf7-9542-03dca837d65c

IMA Classification of CrocobeloniteHide

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Classification of CrocobeloniteHide

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8.AC.

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ccb IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CrocobeloniteHide

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Colour:

saffron red to pinkish red

Comment:

single crystals exhibit distinct dichroism from pink-red to deep-red

Cleavage:

Perfect
In two directions for Crocobelonite-2O and one direction for Crocobelonite-1M

Density:

3.555 g/cm3 (Calculated)

Comment:

for Crocobelonite-2O

Optical Data of CrocobeloniteHide

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RI values:

_n_α = 1.885(5) _n_β = 1.885(5) _n_γ = 1.950

δ = 0.065

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

Y – pale-yellow, Z – deep brownish-orange

Comments:

From Crocobelonite-2O

Chemistry of CrocobeloniteHide

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Mindat Formula:

CaFe3+2O(PO4)2

Crystallography of CrocobeloniteHide

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Polytype:

Formula:

Crystal System:

Class (H-M)

Space Group:

Space Group Setting:

Cell Parameters:

Ratio:

Unit Cell Volume (calc):

Z:

Crocobelonite-1M Crocobelonite-2O
CaFe3+2O(PO4)2 CaFe3+2O(PO4)2
Monoclinic Orthorhombic
2/m - Prismatic m m m _(_2/_m_2/_m_2/m ) - Dipyramidal
_P_21/m P n m a
_P_21/m P n m a
a = 7.2447(2) Å, b = 6.3832(1) Å, c = 7.3993(2) Åβ = 106.401(2)° a = 14.2757(1) Å, b = 6.3832(1) Å, c = 7.3169(1) Å
a:b:c = 1.135 : 1 : 1.159 a:b:c = 2.236 : 1 : 1.146
V 328.25 ų(Calculated from Unit Cell) V 666.75 ų(Calculated from Unit Cell)
2 4

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
6.54 Å (16)
5.12 Å (26)
3.549 Å (100)
3.200 Å (50)
2.912 Å (19)
2.869 Å (40)
2.662 Å (21)
2.264 Å (20)

Comments:

From Type Description of Crocobelonite-2O.

Geological EnvironmentHide

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Type Occurrence of CrocobeloniteHide

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General Appearance of Type Material:

irregular dense segregations up to 0.5 mm

Place of Conservation of Type Material:

Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5559/1 crocobelonite-2O

Geological Setting of Type Material:

Diopside paralava and appear as nests and schlieren up to 30 cm in size situated in brown to red-colored hornfels.

Associated Minerals at Type Locality:

Synonyms of CrocobeloniteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.AC. Angarfite NaFe3+5(PO4)4(OH)4 · 4H2O Orth. 222 : _C_2221
8.AC. Wopmayite Ca6Na3◻Mn(PO4)3(PO3OH)4 Trig. 3_m_ : R_3_c
8.AC.X Dyrnaesite-(La) Na8Ce4+(La,REE)2(PO4)6 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC. Edtollite K2NaCu5Fe3+O2(AsO4)4 Tric. 1 : _P_1
8.AC. Alumoedtollite K2NaCu5AlO2(AsO4)4 Tric. 1 : _P_1
8.AC. Manganobadalovite NaNaMn(MgFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC. Beershevaite CaFe3+3(PO4)3O Mon. 2/m : _P_21/m
8.AC. Calciohatertite NaNaCa(CaFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC. Kabalovite Fe2+3Fe3+4(PO4)6 Tric. 1 : _P_1
8.AC. Nazarchukite Ca2NiFe3+2(PO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.AC. Changesite–(Y) (Ca8Y)◻Fe2+(PO4)7 Trig. 3_m_ : R_3_c
8.AC. Crocobelonite-1M CaFe3+2O(PO4)2 Mon. 2/m : _P_21/m
8.AC. Ebnerite (NH4)Zn(PO4) Hex. 6 : _P_63
8.AC. Magnesioqingheiite Na2Mg(MgAl)(PO4)3 Mon. 2/m
8.AC. Epiebnerite (NH4)Zn(PO4) Mon. 2 : _P_21
8.AC.02 Grigorievite Cu3Fe3+2Al2(VO4)6 Tric. 1 : _P_1
8.AC.02 Koksharovite CaMg2Fe3+4(VO4)6 Tric. 1 : _P_1
8.AC.02 Ziminaite Fe3+ 6 (VO4)6 Tric. 1 : _P_1
8.AC.05 Calciojohillerite NaCaMg3(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Howardevansite NaCuFe2(VO4)3 Tric. 1 : _P_1
8.AC.05 O'Danielite Na(Zn,Mg)3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 va Alluaudite-Na□ ◻4Na4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
8.AC.05 va Alluaudite-Ca□ ◻4Ca4Mn2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/b
8.AC.05 va Ferroalluaudite-NaNa Na4Na4Fe2+4Fe3+8(PO4)12 Mon. 2/m : _B_2/m
8.AC.05 Hagendorfite-NaNa NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) Mon. 2/m : _B_2/b
8.AC.05 Erikapohlite Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : _B_2/m
8.AC.05 Hatertite Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Unnamed (Na-Mg Arsenate Hydroxyarsenate) NaMg3(AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 Unnamed (Na-Zn-H Arsenate Hydrxyarsenate) Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 Mon. 2/m : _B_2/b
8.AC.05 Zincobradaczekite NaZn2Cu2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Badalovite Na2Mg2Fe(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Magnesiocanutite NaMnMg2[AsO4]2[AsO2(OH)2] Mon. 2/m : _B_2/b
8.AC.05 Magnesiohatertite (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Khrenovite Na3Fe3+2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Paraberzeliite NaCa2Mg2(AsO4)3 Mon. 2/m : _B_2/b
8.AC.05 Camanchacaite NaCaMg2[AsO4][AsO3(OH)]2 Mon. 2/m : _B_2/b
8.AC.05 Manganohatertite NaNaCa(MnFe3+)(AsO4)3 Mon. 2/m : _B_2/b
8.AC.07 Zhanghuifenite Na3Mn4Mg2Al(PO4)6 Mon. 2/m
8.AC.07 Ferrobobfergusonite Na2Fe2+5Fe3+Al(PO4)6 Mon.
8.AC.10 Alluaudite (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Arseniopleite NaCaMnMn2(AsO4)3 Mon. 2/m
8.AC.10 Caryinite (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 Mon. 2/m
8.AC.10 Ferroalluaudite (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Hagendorfite NaCaMn2+Fe2+2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Johillerite Na(Mg,Zn)3Cu(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Maghagendorfite (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 Mon. 2/m
8.AC.10 Nickenichite Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Varulite NaCaMn2+Mn2+2(PO4)3 Mon. 2/m : _B_2/b
8.AC.10 Ferrohagendorfite NaCaFe2+Fe2+2(PO4)3 Mon.
8.AC.10 Bradaczekite NaCu4(AsO4)3 Mon. 2/m : _B_2/b
8.AC.10 Groatite NaCaMn2(PO4)[PO3(OH)]2 Mon. 2/m : _B_2/b
8.AC.15 Bobfergusonite Na2Mn5FeAl(PO4)6 Mon. 2/m : _P_2/b
8.AC.15 Ferrowyllieite (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Qingheiite NaNaMn2+(MgAl)(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Rosemaryite (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 Mon. 2/m : _P_21/b
8.AC.15 Wyllieite (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 Mon. 2/m
8.AC.15 Ferrorosemaryite ◻NaFe2+Fe3+Al(PO4)3 Mon. 2/m
8.AC.15 Ferroqingheiite NaNaFe2+(MgAl)(PO4)3 Mon. 2/m : _P_21/m
8.AC.17 Czochralskiite Na4Ca3Mg(PO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.AC.18 Manitobaite Na16Mn2+ 25Al8(PO4)30 Mon. m : P b
8.AC.20 Marićite NaFe2+(PO4) Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
8.AC.25 Berzeliite (NaCa2)Mg2(AsO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Manganberzeliite (NaCa2)Mn2+2(AsO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Palenzonaite (NaCa2)Mn2+2(VO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Schäferite (NaCa2)Mg2(VO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
8.AC.25 Hedegaardite (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.25 Matyhite Ca18(Ca,◻)2Fe2+2(PO4)14 Trig. 3_m_ : R_3_c
8.AC.30 Brianite Na2CaMg(PO4)2 Mon. 2/m : _P_21/b
8.AC.35 Vitusite-(Ce) Na3(Ce,La,Nd)(PO4)2 Orth. m _m_2 : P c _a_21
8.AC.40 Olgite (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 Trig. 3_m_ _(_32/m ) : _P_3_m_1
8.AC.40 Bario-olgite (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : _P_3
8.AC.45 Strontiowhitlockite Sr9Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.45 Whitlockite Ca9Mg(PO4)6(PO3OH) Trig. 3_m_ : R_3_c
8.AC.45 Merrillite Ca9NaMg(PO4)7 Trig. 3_m_ : R_3_m
8.AC.45 Tuite Ca3(PO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.AC.45 Ferromerrillite Ca9NaFe2+(PO4)7 Trig. 3_m_ : R_3_c
8.AC.47 Iwateite Na2BaMn(PO4)2 Trig. 3 : _P_3
8.AC.47 Yurmarinite Na7(Fe3+,Mg,Cu)4(AsO4)6 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.47 Ozerovaite Na2KAl3(AsO4)4 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
8.AC.47 Anatolyite Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.47 Pansnerite K3Na3(Fe3+,Al)6(AsO4)8 Orth. m m m _(_2/_m_2/_m_2/m )
8.AC.50 Chladniite Na3CaMg11(PO4)9 Trig. 3 : _R_3
8.AC.50 Fillowite Na3CaMn2+11(PO4)9 Trig. 3 : _R_3
8.AC.50 Johnsomervilleite Na3CaFe11(PO4)9 Trig. 3 : _R_3
8.AC.50 Galileiite Na3Fe2+Fe2+11(PO4)9 Trig. 3 : _R_3
8.AC.50 Xenophyllite Na4Fe2+7(PO4)6 Tric. 1 : _P_1
8.AC.50 Udinaite NaMg4(VO4)3 Tet. 42_m_ : I_42_d
8.AC.50 Arsenudinaite NaMg4(AsO4)3 Tet. 42_m_ : I_42_d
8.AC.52 Lasnierite (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.AC.55 Pharmazincite KZnAsO4 Hex. 6 : _P_63
8.AC.57 Zubkovaite Ca3Cu3(AsO4)4 Mon. 2 : _B_2
8.AC.60 Kosnarite KZr2(PO4)3 Trig. 3_m_ _(_32/m ) : R_3_c
8.AC.65 Panethite (Na,Ca)2(Mg,Fe2+)2(PO4)2 Mon. 2/m : _P_21/b
8.AC.70 Stanfieldite Ca4Mg5(PO4)6 Mon.
8.AC.75 Ronneburgite K2MnV4O12 Mon. 2/m
8.AC.80 Tillmannsite Ag3Hg[(V,As)O4] Tet. 4 : _I_4
8.AC.85 Filatovite K(Al,Zn)2(As,Si)2O8 Mon. 2/m

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for CrocobeloniteHide

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Reference List:

Britvin, Sergey N., Murashko, Mikhail N., Krzhizhanovskaya, Maria G., Vlasenko, Natalia S., Vereshchagin, Oleg S., Vapnik, Yevgeny, Bocharov, Vladimir N. (2023) Crocobelonite, CaFe3+2(PO4)2O, a new oxyphosphate mineral, the product of pyrolytic oxidation of natural phosphides. American Mineralogist, 108 (10) 1973-1983 doi:10.2138/am-2022-8757

Localities for CrocobeloniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Israel
Southern District (HaDarom District) Tamar Regional Council Hatrurim Basin Halamish wadi (Ẕuq Tamrur) [Crocobelonite-1M] Britvin et al. (2023)
Jordan
Amman Governorate Transjordan Plateau Daba-Siwaqa complex Deynekoite type locality Galuskin et al. (2023) +1 other reference
Unnamed phosphorite quarry (TL) Miyawaki et al. (2020) +1 other reference