Kayrobertsonite (original) (raw)

A valid IMA mineral species

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About KayrobertsoniteHide

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Formula:

[MnAl2(PO4)2(OH)2(H2O)4] · 2H2O

Name:

Named in honor of Kay Robertson (born Gabriella Katherine Loewi) (b. 23 April 1920, Venice, Italy - d. March 23, 2020, Puget Sound area) of Los Angeles, California, USA, a well known collector, especially of German localities, since the 1950s. She was a founding member of the Southern California Micromineralogists Society.

Co-Type Localities:

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
Foote Lithium Co. Mine, Kings Mountain, Cleveland County, North Carolina, USA

The OH analogue of nordgauite. Structural topology similar to that of nordgauite, but with double amount of water molecules in the [001] channels.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:46697:4

ee78beaf-06d8-48fa-a712-5dc41b90bcc5

IMA Classification of KayrobertsoniteHide

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IMA Formula:

MnAl2(PO4)2(OH)2 · 6H2O

Type description reference:

Mills, Stuart J., Grey, Ian E., Kampf, Anthony R., Birch, William D., MaCrae, Colin M., Smith, Jason B., Keck, Erich (2016) Kayrobertsonite, MnAl2(PO4)2(OH)2·6H2O, a new phosphate mineral related to nordgauite. European Journal of Mineralogy, 28 (3) 649-654 doi:10.1127/ejm/2016/0028-2524

Classification of KayrobertsoniteHide

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8.DC.30

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Kay IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KayrobertsoniteHide

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Optical Data of KayrobertsoniteHide

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RI values:

_n_α = 1.530(1) _n_β = 1.554(1) _n_γ = 1.566(1)

2V:

Measured: 70.3° (5), Calculated: 69.6°

δ = 0.036

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Pleochroism:

Non-pleochroic

Chemistry of KayrobertsoniteHide

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Mindat Formula:

[MnAl2(PO4)2(OH)2(H2O)4] · 2H2O

Crystallography of KayrobertsoniteHide

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Class (H-M):

1 - Pinacoidal

Cell Parameters:

a = 10.049(2) Å, b = 10.205(2) Å, c = 6.083(1) Å
α = 91.79(3)°, β = 99.70(3)°, γ = 98.02(3)°

Ratio:

a:b:c = 0.985 : 1 : 0.596

Morphology:

Intergrown masses offibrous needles up to 100 μm long and less than 5 μm wide

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
10.047 Å (100)
9.804 Å (8)
7.629 Å (44)
5.029 Å (12)
4.695 Å (10)
3.023 Å (12)
2.952 Å (10)
2.579 Å (10)

Geological EnvironmentHide

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Type Occurrence of KayrobertsoniteHide

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Co-Type Localities:

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
Foote Lithium Co. Mine, Kings Mountain, Cleveland County, North Carolina, USA

General Appearance of Type Material:

intergrown masses of snow-white, soft, finely fibrous needles, less than 5 μm in diameter and no more than 100 μm in length

Place of Conservation of Type Material:

Co-type material is deposited in the mineralogical collections of the Museum Victoria, Melbourne, Victoria, Australia, registered numbers M53379, M53380 and M48795, and the Natural History Museum of Los Angeles County, Los Angeles, CA 90007, USA, registr

Geological Setting of Type Material:

Reference:

Mills, S.J., Grey, I.E., Kampf, A.R., Birch, W.D., MacRae, C.M., Smith, J.B., Keck, E. (2016) Kayrobertsonite, MnAl2(PO4)2(OH)2·6H2O, a new phosphate mineral related to nordgauite. European Journal of Mineralogy: 28: 649-654.

Synonyms of KayrobertsoniteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DC. Ianbruceite Zn2(AsO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC. Césarferreiraite Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC. Ferrivauxite Fe3+Al2(PO4)2(OH)3 · 5H2O Tric. 1 : _P_1
8.DC.05 Nissonite Cu2Mg2(PO4)2(OH)2 · 5H2O Mon. 2/m : _B_2/b
8.DC.07 Euchroite Cu2(AsO4)(OH) · 3H2O Orth. 222 : _P_212121
8.DC.10 Legrandite Zn2(AsO4)(OH) · H2O Mon. 2/m : _P_21/b
8.DC.12 Strashimirite Cu8(AsO4)4(OH)4 · 5H2O Mon.
8.DC.15 Arthurite CuFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Earlshannonite Mn2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Ojuelaite ZnFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Whitmoreite Fe2+Fe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Cobaltarthurite CoFe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Bendadaite Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 Kunatite CuFe3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_21/b
8.DC.15 UM2006-27-PO:FeHZn ZnFe3+2(PO4)2(OH)2 · 4H2O Mon.
8.DC.15 UKI-2006-(PO:AlCuFeH) Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.17 Kleemanite ZnAl2(PO4)2(OH)2 · 3H2O Mon.
8.DC.20 Bermanite Mn2+Mn3+2(PO4)2(OH)2 · 4H2O Mon. 2/m : _P_2/b
8.DC.20 Coralloite Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O Tric. 1 : _P_1
8.DC.20 Magnesiobermanite MgMn3+2(PO4)2(OH)2 · 4H2O Mon. 2 : _P_21
8.DC.22 Kovdorskite Mg2(PO4)(OH) · 3H2O Mon. 2/m : _P_21/b
8.DC.25 Ferristrunzite Fe3+Fe3+2(PO4)2(OH)3 · 5H2O Tric.
8.DC.25 Ferrostrunzite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric.
8.DC.25 Metavauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.25 Metavivianite Fe2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Strunzite Mn2+Fe3+2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.25 Zincostrunzite ZnFe3+2(PO4)2(OH)2 · 6.5H2O Tric. 1 : _P_1
8.DC.27 Beraunite Fe3+6(PO4)4O(OH)4 · 6H2O Mon. m : B b
8.DC.27 Tvrdýite Fe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2O Mon. 2/m : _B_2/b
8.DC.27 Zincoberaunite ZnFe3+5(PO4)4(OH)5 · 6H2O Mon. 2/m : _B_2/b
8.DC.30 Gordonite MgAl2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Laueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Mangangordonite Mn2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Paravauxite Fe2+Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Pseudolaueite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DC.30 Sigloite Fe3+Al2(PO4)2(OH)3 · 7H2O Tric. 1 : _P_1
8.DC.30 Stewartite Mn2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ushkovite MgFe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Ferrolaueite Fe2+Fe3+2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Kastningite (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Maghrebite MgAl2(AsO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.30 Nordgauite MnAl2(PO4)2(F,OH)2 · 5H2O Tric. 1 : _P_1
8.DC.30 Kummerite Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O Tric. 1 : _P_1
8.DC.32 Tinticite Fe3+3(PO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.32 Kamarizaite Fe3+3(AsO4)2(OH)3 · 3H2O Tric. 1 : _P_1
8.DC.35 Vauxite Fe2+Al2(PO4)2(OH)2 · 6H2O Tric. 1 : _P_1
8.DC.37 Vantasselite Al4(PO4)3(OH)3 · 9H2O Orth.
8.DC.40 Cacoxenite Fe3+24AlO6(PO4)17(OH)12 · 75H2O Hex. 6/m : _P_63/m
8.DC.45 Gormanite (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric.
8.DC.45 Souzalite (Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O Tric. 1
8.DC.47 Kingite Al3(PO4)2F2(OH) · 7H2O Tric.
8.DC.50 Wavellite Al3(PO4)2(OH,F)3 · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.50 Allanpringite Fe3+3(PO4)2(OH)3 · 5H2O Mon. 2/m : _P_21/m
8.DC.50 Fluorwavellite Al3(PO4)2(OH)2F · 5H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.52 Kribergite Al5(PO4)3(SO4)(OH)4 · 4H2O Tric. 1 : _P_1
8.DC.55 Mapimite Zn2Fe3+3(AsO4)3(OH)4 · 10H2O Mon. m : B m
8.DC.57 Ogdensburgite Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m m m
8.DC.60 Nevadaite (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DC.60 Cloncurryite Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O Mon. 2/m : _P_21/b
8.DC.62 Kenngottite Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : _P_2/b
8.DC.67 Molinelloite Cu(H2O)(OH)V4+O(V5+O4) Tric. 1 : _P_1
8.DC.70 Whitecapsite H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O Hex. 6/m : _P_63/m
8.DC.75 Heimite PbCu2(AsO4)(OH)3 · 2H2O Mon. 2/m
8.DC.80 Lednevite Cu[PO3(OH)] · H2O Mon. 2/m : _P_21/b

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KayrobertsoniteHide

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Reference List:

Mills, Stuart J., Grey, Ian E., Kampf, Anthony R., Birch, William D., MaCrae, Colin M., Smith, Jason B., Keck, Erich (2016) Kayrobertsonite, MnAl2(PO4)2(OH)2·6H2O, a new phosphate mineral related to nordgauite. European Journal of Mineralogy, 28 (3) 649-654 doi:10.1127/ejm/2016/0028-2524

Localities for KayrobertsoniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany (TL)
Bavaria Upper Palatinate Neustadt an der Waldnaab District Waidhaus Hagendorf Hagendorf South Pegmatite (TL) Hålenius et al. (2015) +1 other reference
Silbergrube EDS Jason B. Smith
USA (TL)
North Carolina Cleveland County Kings Mountain Foote Lithium Co. Mine (TL) Mineralogical Magazine +2 other references