Henritermierite (original) (raw)

A valid IMA mineral species

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About HenritermieriteHide

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Formula:

Ca3Mn3+2(SiO4)2[◻(OH)4]

Colour:

Clove-brown to apricot-brown; lemon-yellow to pale yellow in thin section.

Crystal System:

Tetragonal

Name:

Named in 1969 by C. Gaudefroy, M. Orliac, F. Permingeat, and A. Parfenoff, in honor of Henri François Émile Termier (13 December 1897, Lyon, France - 12 August 1989, Gif sur Yvette, France), geologist known for his studies of the stratigraphy and paleontology of North Africa and France. He was, for a time, head of the Morocco Geological Service and later, professor at the University of Algiers and the Sorbonne.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1868:1

6f9f94b7-3bdd-4f56-8316-e214e2a14bb3

IMA Classification of HenritermieriteHide

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IMA Formula:

Ca3Mn3+2(SiO4)2(OH)4

Type description reference:

Classification of HenritermieriteHide

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9.AD.25

9 : SILICATES (Germanates)
A : Nesosilicates
D : Nesosilicates without additional anions; cations in [6] and/or greater coordination

51.4.4.1

51 : NESOSILICATES Insular SiO4 Groups Only
4 : Insular SiO4 Groups Only with cations in [6] and >[6] coordination

16.16.19

16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Hri IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HenritermieriteHide

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Colour:

Clove-brown to apricot-brown; lemon-yellow to pale yellow in thin section.

Density:

3.34(2) g/cm3 (Measured) 3.40 g/cm3 (Calculated)

Optical Data of HenritermieriteHide

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RI values:

_n_ω = 1.765 _n_ε = 1.800

δ = 0.035

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

O = very pale yellow
E = lemon-yellow

Chemistry of HenritermieriteHide

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Mindat Formula:

Ca3Mn3+2(SiO4)2[◻(OH)4]

Crystallography of HenritermieriteHide

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Crystal System:

Tetragonal

Class (H-M):

4/m m m _(_4/_m_2/_m_2/m ) - Ditetragonal Dipyramidal

Cell Parameters:

a = 12.39 Å, c = 11.91 Å

Unit Cell V:

1,828.33 ų (Calculated from Unit Cell)

Morphology:

As pseudo-octahedral crystals, to 3mm, and as aggregates of small grains.

Twinning:

Common on {101} sectored

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.75 Å (very very strong)
2.516 Å (very strong)
4.37 Å (strong)
3.09 Å (strong)
2.98 Å (strong)
2.684 Å (moderately strong)
1.614 Å (moderately strong)

Comments:

Tachgagalt mine, Morocco. Data from the type description.

Geological EnvironmentHide

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Geological Setting:

Manganese deposits

Type Occurrence of HenritermieriteHide

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General Appearance of Type Material:

Aggregates of small grains up to 0.5 mm; mostly about 0.2 mm in diameter, filling interstices between crystals of marokite, hausmannite, and rare gaudefroyite.

Place of Conservation of Type Material:

Ecole Nationale Supérieure des Mines, Paris, France, numbers 51098, 51099 (holotype).
FS, Toulouse, France (cotype).
Geological Survey of Morocco, Rabat, Morocco (cotype).
Muséum Nationale d’Histoire Naturelle, Paris, France, number 175.139 (holotype).

Associated Minerals at Type Locality:

Reference:

Gaudefroy, C., Orliac, M., Permingeat, F., Parfenoff, A. (1969) L`henritermiérite, une nouvelle espèce minérale. Bulletin de la Société Française de Minéralogie et de Cristallographie: 92: 185-190.

Synonyms of HenritermieriteHide

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Other Language Names for HenritermieriteHide

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Relationship of Henritermierite to other SpeciesHide

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Other Members of this group:

Holtstamite Ca3Al2(SiO4)2[◻(OH)4] Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.AD. Adrianite Ca12(Al4Mg3Si7)O32Cl6 Iso. 43_m_ : I_43_d
9.AD.05 Larnite Ca2SiO4 Mon. 2/m
9.AD.10 Calcio-olivine Ca2SiO4 Orth. m m m _(_2/_m_2/_m_2/m )
9.AD.15 Merwinite Ca3Mg(SiO4)2 Mon. 2/m : _P_21/b
9.AD.20 Bredigite Ca7Mg(SiO4)4 Orth. m _m_2 : P n _n_2
9.AD.25 Midbarite Ca3Mg2(V2Si)O12 Iso. m_3_m _(_4/_m_32/m )
9.AD.25 Menzerite-(Y) (Y2Ca)Mg2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Uvarovite Ca3Cr2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Eltyubyuite Ca12Fe3+10Si4O32Cl6 Iso. 43_m_ : I_43_d
9.AD.25 Eringaite Ca3Sc2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 va Hydrougrandite (Ca,Mg,Fe2+)3(Fe3+,Al)2[(OH)4(SiO4)2] Iso.
9.AD.25 Calderite Mn2+3Fe3+2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Nikmelnikovite Ca12(Fe2+Fe3+3Al3◻)[SiO4]6[◻(OH)4]5◻4 Trig. 3 : _R_3
9.AD.25 Hutcheonite Ca3Ti2(SiO4)(AlO4)2 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Wadalite (Ca,Mg)6(Al,Fe3+)4((Si,Al)O4)3O4Cl3 Iso. 43_m_ : I_43_d
9.AD.25 Rubinite Ca3Ti3+2Si3O12 Iso.
9.AD.25 Kerimasite Ca3Zr2(SiO4)(Fe3+O4)2 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Holtstamite Ca3Al2(SiO4)2[◻(OH)4] Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
9.AD.25 Spessartine Mn2+3Al2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Toturite Ca3Sn2(SiO4)(Fe3+O4)2 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Kimzeyite Ca3Zr2(SiO4)(AlO4)2 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Khoharite Mg3Fe3+2(SiO4)3
9.AD.25 Irinarassite Ca3Sn2(SiO4)(AlO4)2 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Knorringite Mg3Cr2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Goldmanite Ca3V3+2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Blythite Mn2+3Mn3+2[SiO4]3
9.AD.25 Skiagite Fe2+3Fe3+2[SiO4]3
9.AD.25 UM1984-37-SiO:CrMn Mn2+3Cr3+2(SiO4)3
9.AD.25 Almandine Fe2+3Al2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 va Yamatoite (Mn2+,Ca)3(V3+,Al)2(SiO4)3 Iso.
9.AD.25 Momoiite Mn2+3V3+2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Grossular Ca3Al2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Andradite Ca3Fe3+2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Morimotoite Ca3(TiFe2+)(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Majorite Mg3(MgSi)(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Pyrope Mg3Al2(SiO4)3 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.25 Schorlomite Ca3Ti2(SiO4)(Fe3+O4)2 Iso. m_3_m _(_4/_m_32/m ) : I a_3_d
9.AD.30 Hafnon HfSiO4 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
9.AD.30 Zircon Zr(SiO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
9.AD.30 Coffinite U(SiO4) · nH2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
9.AD.30 Thorite Th(SiO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
9.AD.30 va Auerlite near Th(Si,P)O4
9.AD.30 Stetindite-(Ce) Ce(SiO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
9.AD.35 Tombarthite-(Y) Y4(Si,H4)4O12-x(OH)4+2x Mon.
9.AD.35 Huttonite ThSiO4 Mon. 2/m
9.AD.40 Eulytine Bi4(SiO4)3 Iso. 43_m_ : I_43_d
9.AD.45 Reidite ZrSiO4 Tet. 4/m : _I_41/a
9.AD.55 Jeffbenite Mg3Al2Si3O12 Tet. 42_m_ : I_42_d

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for HenritermieriteHide

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Reference List:

Armbruster, T., Kohler, T., Libowitzky, E., Friedrich, A., Miletich, R., Kunz, M., Medenbach, O., Gutzmer, J. (2001) Structure, compressibility, hydrogen bonding, and dehydration of the tetragonal Mn3+ hydrogarnet, henritermierite. American Mineralogist: 86: 147-158.

Grew, E. S., Locock, A. J., Mills, S. J., Galuskina, I. O., Galuskin, E. V., Hålenius, U. (2013) Nomenclature of the garnet supergroup. American Mineralogist, 98 (4) 785-811 doi:10.2138/am.2013.4201

Cruickshank, L.A. (2018) Crystal Chemistry and Structure of kimzeyite, Ca3Zr2[Al2Si]Σ3O12, henritermierite, Ca3Mn2[(SiO4)2(O4H4)1]Σ3, (OH,F)-spessartine, Mn2+3Al2[(SiO4)2(O4H4,F4)1]Σ3, and hausmannite, Mn3O4. Master of Science thesis, University of Calgary, Calgary, Alberta, Canada.

Localities for HenritermieriteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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