Kanatzidisite (original) (raw)

A valid IMA mineral species

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Specific Gravity:

5.481 (Calculated)

Crystal System:

Monoclinic

Name:

After the chemist Professor Mercouri G. Kanatzidis (1957-), in honour of his achievements and innovations in chalcogenide chemistry.

New structure type: a unique van der Waals heterolayered structure based on alternating BiSbS3 double van der Waals layers and distorted [Te] square nets comprising an array of parallel, zigzag Te chains.

Probably a Dirac semimetal.

Unique combination of elements (at the upload time).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:470783:3

a3fcdcfd-dae4-4e03-ba79-979cdc40e083

IMA Classification of KanatzidisiteHide

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Approval history:

IMA no. 2023-014

Classification of KanatzidisiteHide

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2.EB.

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
B : M:S = 1:2, with Fe, Co, Ni, PGE, etc.

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ktz IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KanatzidisiteHide

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Density:

5.481 g/cm3 (Calculated)

Optical Data of KanatzidisiteHide

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Comments:

weakly pleochroic from gray to a greenish gray

Chemistry of KanatzidisiteHide

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Mindat Formula:

(SbBiS3)2Te2

Crystallography of KanatzidisiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 4.0021(5) Å, b = 3.9963(5) Å, c = 21.1009(10) Å
β = 95.392(3)°

Ratio:

a:b:c = 1.001 : 1 : 5.28

Unit Cell V:

335.99 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.850 Å (55)
3.740 Å (75)
3.498 Å (100)
3.178 Å (45)
2.824 Å (85)
2.770 Å (80)
2.270 Å (50)
2.197 Å (30)

Type Occurrence of KanatzidisiteHide

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General Appearance of Type Material:

maximum grain size is about 20 μm

Place of Conservation of Type Material:

collections of the Museo di Storia Naturale, Università di Firenze, Via La Pira 4, 50121, Florence, Italy, catalogue number 3237/I

Geological Setting of Type Material:

stockwork in a propylitized dacite breccia pipe.

Associated Minerals at Type Locality:

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2.EB. Selenolaurite RuSe2 Iso. m_3(2/m_3) : P _a_3
2.EB. Andrieslombaardite RhSbS Iso. 23 : _P_213
2.EB. Iridarsenite (Ir,Ru)As2 Mon. 2/m : _P_21/b
2.EB.05a Vaesite NiS2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Hauerite MnS2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Laurite RuS2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Gaotaiite Ir3Te8 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Penroseite (Ni,Co,Cu)Se2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Fukuchilite Cu3FeS8 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Villamanínite (Cu,Ni,Co,Fe)S2 Tric.
2.EB.05a Erlichmanite OsS2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Sperrylite PtAs2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Geversite PtSb2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Cattierite CoS2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Aurostibite AuSb2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Trogtalite CoSe2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a v Cayeuxite
2.EB.05a Kruťaite CuSe2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Pyrite FeS2 Iso. m_3(2/m_3) : P _a_3
2.EB.05a Insizwaite Pt(Bi,Sb)2 Iso. m_3(2/m_3) : P _a_3
2.EB.05b Bambollaite Cu(Se,Te)2 Tet.
2.EB.05a Dzharkenite FeSe2 Iso. m_3(2/m_3) : P _a_3
2.EB.10a Marcasite FeS2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.10e Paracostibite CoSbS Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
2.EB.10f Oenite CoSbAs Orth.
2.EB.10e Pararammelsbergite NiAs2 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
2.EB.10a Mattagamite CoTe2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.10a Frohbergite FeTe2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.10d Costibite CoSbS Orth. m _m_2 : P m _n_21
2.EB.10b Alloclasite Co1-xFexAsS Mon. 2 : _P_21
2.EB.10c Glaucodot (Co0.50Fe0.50)AsS Orth. m _m_2 : P m _n_21
2.EB.10a Petříčekite CuSe2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.10a Kullerudite NiSe2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.10a Ferroselite FeSe2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.15b Seinäjokite FeSb2 Orth.
2.EB.15a Rammelsbergite NiAs2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.15a Clinosafflorite CoAs2 Mon. 2/m : _P_21/m
2.EB.15c Paxite CuAs2 Mon. 2/m : _P_21/b
2.EB.15a Nisbite NiSb2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.15a Löllingite FeAs2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.15a Safflorite (Co,Ni,Fe)As2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
2.EB.15a Omeiite (Os,Ru)As2 Orth.
2.EB.15a Anduoite (Ru,Os)As2 Orth.
2.EB.20 Arsenopyrite FeAsS Mon. 2/m : _P_21/b
2.EB.20 Ruarsite (Ru,Os)AsS Mon.
2.EB.20 Osarsite (Os,Ru)AsS Mon.
2.EB.20 Gudmundite FeSbS Mon. 2/m : _P_21/b
2.EB.25 Mayingite IrBiTe Iso. m_3(2/m_3) : P _a_3
2.EB.25 Maslovite PtBiTe Iso. 23 : _P_213
2.EB.25 Paragersdorffite Ni(As,S)2 Iso. m_3(2/m_3) : P _a_3
2.EB.25 Orthogersdorffite NiAsS Orth. m _m_2 : P c _a_21
2.EB.25 Jolliffeite NiAsSe Iso. m_3(2/m_3) : P _a_3
2.EB.25 Cobaltite CoAsS Orth. m _m_2 : P c _a_21
2.EB.25 Testibiopalladite PdSbTe Iso.
2.EB.25 va Antimony-bearing Gersdorffite Ni(As,Sb)S
2.EB.25 Kalungaite PdAsSe Iso. m_3(2/m_3) : P _a_3
2.EB.25 Hollingworthite (Rh,Pt,Pd)AsS Iso. m_3(2/m_3) : P _a_3
2.EB.25 Michenerite PdBiTe Iso. 23 : _P_213
2.EB.25 Gersdorffite NiAsS Iso. 23 : _P_213
2.EB.25 Milotaite PdSbSe Iso. 23 : _P_213
2.EB.25 Tolovkite IrSbS Iso.
2.EB.25 Platarsite Pt(As,S)2 Iso. m_3(2/m_3) : P _a_3
2.EB.25 Willyamite CoSbS
2.EB.25 Changchengite IrBiS Iso. 23 : _P_213
2.EB.25 Kvačekite NiSbSe Iso. 23 : _P_213
2.EB.25 Krutovite NiAs2 Iso. 23 : _P_213
2.EB.25 Padmaite PdBiSe Iso. 432
2.EB.25 Ullmannite NiSbS Iso. 23 : _P_213
2.EB.25 Irarsite (Ir,Ru,Rh,Pt)AsS Iso. m_3(2/m_3) : P _a_3
2.EB.30 Urvantsevite Pd(Bi,Pb)2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
2.EB.35 Rheniite ReS2 Tric. 1 : _P_1

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KanatzidisiteHide

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Reference List:

Bindi, Luca, Zhou, Xiuquan, Deng, Tianqi, Li, Zhi, Wolverton, Christopher (2023) Kanatzidisite: A Natural Compound with Distinctive van der Waals Heterolayered Architecture. Journal of the American Chemical Society, 145 (33) 18227-18232

Localities for KanatzidisiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Hungary (TL)
Pest County Szob District Nagybörzsöny Alsó-Rózsa adit (TL) Bosi et al. (2023)