Lacroixite (original) (raw)

A valid IMA mineral species - grandfathered

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About LacroixiteHide

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Colour:

Colourless, light yellow, light green, almost white; colourless in transmitted light.

Lustre:

Sub-Vitreous, Resinous, Dull

Specific Gravity:

3.126 - 3.29

Crystal System:

Monoclinic

Name:

Named in 1914 by František Slavik in honor of Antoine François Alfred Lacroix [February 4, 1863, Macon, Saône-et-Loire, France - March 12, 1948, Paris, France], a famous French mineralogist.

Frequently occurs as grains and rods in the altered margins of blocky crystals and grains of amblygonite or montebrasite embedded in granite pegmatite matrix. Not usually found in montebrasite crystals extending into cavities. Pure grains of lacroixite are uncommon.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2310:4

8e5f44b5-cf36-443e-92d1-0af05f14930e

IMA Classification of LacroixiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of LacroixiteHide

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8.BH.10

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1

41.5.5.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
5 : (AB)2(XO4)Zq

22.1.2

22 : Phosphates, Arsenates or Vanadates with other Anions
1 : Phosphates, arsenates or vanadates with fluoride

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Lac IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LacroixiteHide

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Sub-Vitreous, Resinous, Dull

Colour:

Colourless, light yellow, light green, almost white; colourless in transmitted light.

Cleavage:

Poor/Indistinct
Parallel to (111) and 111) only.

Fracture:

Irregular/Uneven

Density:

3.126 - 3.29 g/cm3 (Measured) 3.29 g/cm3 (Calculated)

Optical Data of LacroixiteHide

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RI values:

_n_α = 1.546 _n_β = 1.563 _n_γ = 1.580

2V:

Measured: 89° , Calculated: 88°

δ = 0.034

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Inclined

Chemistry of LacroixiteHide

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Mindat Formula:

NaAl(PO4)F

Crystallography of LacroixiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 6.414 Å, b = 8.207 Å, c = 6.885 Å
β = 115.47°

Ratio:

a:b:c = 0.782 : 1 : 0.839

Unit Cell V:

327.20 ų (Calculated from Unit Cell)

Morphology:

Usually massive or intergrown with other minerals. Rarely observed as fragmentary crystals.

Comment:

Pseudo-orthorhombic

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0000996 Lacroixite Lahti S I, Pajunen A (1985) New data on lacroixite, NaAlFPO4 American Mineralogist 70 849-855 1985 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.73 Å (51)
4.627 Å (32)
3.155 Å (100)
2.895 Å (98)
2.476 Å (57)
2.166 Å (43)
1.578 Å (27)

Geological EnvironmentHide

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Type Occurrence of LacroixiteHide

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General Appearance of Type Material:

intergrowths, alteration rims, druses

Place of Conservation of Type Material:

Charles University, Prague, Czech Republic, 7400;
Harvard University, Cambridge, Massachusetts, USA, 86746.

Geological Setting of Type Material:

Associated Minerals at Type Locality:

Reference:

Slavik, M.F. (1914) Sur les fluorophosphates ternaires de Al2O3, RO et R2O (morinite, ježekite, lacroixite). Bulletin de la Société Française de Minéralogie et de Cristallographie: 37: 152-162.

Other Language Names for LacroixiteHide

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Simplified Chinese:锥晶石

Traditional Chinese:錐晶石

Relationship of Lacroixite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.BH. Crimsonite PbFe3+2(PO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH. Reznitskyite CaMg(VO4)F Mon. 2/m : _B_2/b
8.BH. Cuprozheshengite Pb4CuZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Zheshengite Pb4ZnZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Peterchinite Zn3Zn2(OH)6As[O3(OH)3] Mon. 2/m : _B_2/m
8.BH.05 Thadeuite Ca(Mg,Fe2+)3(PO4)2(OH,F)2 Orth. 222 : _C_2221
8.BH.10 Durangite NaAl(AsO4)F Mon. 2/m : _B_2/b
8.BH.10 Isokite CaMg(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Maxwellite NaFe3+(AsO4)F Mon. 2/m : _P_2/m
8.BH.10 Panasqueiraite CaMg(PO4)(OH) Mon.
8.BH.10 Kononovite NaMg(SO4)F Mon. 2/m : _B_2/b
8.BH.10 Arsenatrotitanite NaTi(AsO4)O Mon. 2/m : _B_2/b
8.BH.15 Drugmanite Pb2Fe3+(PO4)(PO3OH)(OH)2 Mon. 2/m : _P_21/b
8.BH.20 Bjarebyite (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Cirrolite Ca3Al2(PO4)3(OH)3 (?)
8.BH.20 Kulanite Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Penikisite Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Perloffite Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Johntomaite BaFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Bjarebyite Group
8.BH.20 Strontioperloffite SrMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumboperloffite PbMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Nigelcookite PbFe2+2V3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.25 Bertossaite (Li,Na)2(Ca,Fe2+,Mn2+)Al4(PO4)4(OH,F)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Palermoite (Li,Na)2(Sr,Ca)Al4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Natropalermoite Na2SrAl4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.30 Carminite PbFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.30 Sewardite CaFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.35 Adelite CaMg(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Arsendescloizite PbZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Austinite CaZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Cobaltaustinite CaCo(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Conichalcite CaCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite PbCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Gabrielsonite PbFe3+(As3+O3)O Orth. m _m_2 : P m _c_21
8.BH.35 Nickelaustinite CaNi(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Tangeite CaCu(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite-alpha PbCu(AsO4)(OH)
8.BH.35 Gottlobite CaMg(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Hermannroseite CaCu(PO4)(OH) Orth. 222 : _P_212121
8.BH.40 Čechite PbFe2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.40 Descloizite PbZn(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Mottramite PbCu(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Pyrobelonite PbMn2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Khorixasite (Bi0.67◻0.33)Cu(VO4)(OH) Mon. 2/m : _P_2/m
8.BH.45 Bayldonite PbCu3(AsO4)2(OH)2 Mon. 2/m : _B_2/b
8.BH.45 Vésigniéite BaCu3(VO4)2(OH)2 Mon. 2/m : _B_2/m
8.BH.50 Paganoite NiBi(AsO4)O Tric. 1 : _P_1
8.BH.55 Harrisonite Ca(Fe2+,Mg)6(PO4)2(SiO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.BH.55 Jagowerite BaAl2(PO4)2(OH)2 Tric.
8.BH.60 Attakolite CaMn2+Al4(SiO3OH)(PO4)3(OH)4 Mon. 2/m : _B_2/m
8.BH.65 Leningradite PbCu3(VO4)2Cl Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
8.BH.70 Katiarsite KTiO(AsO4) Orth. m _m_2 : P n _a_21
8.BH.70 Yurgensonite K2SnTiO2(AsO4)2 Orth. m _m_2 : P n _a_21
8.BH.75 Melanarsite K3Cu7Fe3+O4(AsO4)4 Mon. 2/m : _B_2/b
8.BH.80 Moraskoite Na2Mg(PO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.80 Evseevite Na2Mg(AsO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.85 Piccoliite NaCaMn3+2(AsO4)2O(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P b c m

Other InformationHide

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Notes:

Readily soluble in HCl and H2SO4.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for LacroixiteHide

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Reference List:

Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.

Localities for LacroixiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Argentina
Córdoba Province Calamuchita Department Río de Los Sauces District Angel Mine Demartis et al. (2014)
Cruz del Eje department Candelaria District Gigante pegmatite Kampf et al. (2010)
Australia
Victoria East Gippsland Shire Glen Valley Unnamed Pegmatite Eagle
Canada
Manitoba Lac-du-Bonnet area Bernic Lake Tanco Mine Groat et al. (1990)
Czech Republic
Karlovy Vary Region Cheb District Aš Vernéřov Breiter K.
Lázně Kynžvart Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/lacroixite.pdf)
Bílý Kámen pegmatite quarry Černý et al. (Weisser Stein)
Vysočina Region Jihlava District Puklice Puklice pegmatites Novák et al. (1996)
Velký Beranov Jeclov Jeclov granitic pegmatite Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/lacroixite.pdf)
Žďár nad Sázavou District Rožná Rožná pegmatite (Rozna; Roschna) Novák +4 other references
Rožná Hradisko P. Pauliš (2001)
Finland
Pirkanmaa Orivesi Eräjärvi area Viitaniemi pegmatite Sandström et al. (2009)
France
Auvergne-Rhône-Alpes Allier Vichy Échassières Beauvoir quarry Econ Geol (1995)
Nouvelle-Aquitaine Creuse Aubusson Soumans Montebras Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/lacroixite.pdf)
Montebras Mines Pirard et al. (2007) +1 other reference
Germany (TL)
Saxony Erzgebirgskreis Ehrenfriedersdorf Greifensteine (TL) Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/lacroixite.pdf) +3 other references
Japan
Fukuoka Prefecture Fukuoka City Nagatare (Nagatareyama; Nagatare mine) SHIROSE et al. (2014)
Portugal
Castelo Branco Idanha-a-Nova União de Freg de Segura e Zebreira Cerro Queimado Cathelineau et al. (2024)
Segura Mines (Segura mining field) Antunes et al. (2013)
Rwanda
Western Province Ngororero District Bwira Rubindi pegmatite (Kabilizi) European Journal of Mineralogy: 17 (5) +1 other reference
Muhororo Buranga pegmatite Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/lacroixite.pdf) +2 other references
Rongi Amblygonite Pegmatite Fransolet (1989)
Rusororo pegmatite Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/lacroixite.pdf)
Slovakia
Košice Region Gelnica District Henclová Surovec granite body Petrik et al. (2011)
Spain
Extremadura Badajoz Tres Arroyos Tres Arroyos pegmatite field Garate-Olave et al. (2020)
Sweden
Stockholm County Sigtuna Arlanda Norrskogen Weisz et al. (2013)
USA
Connecticut Middlesex County Portland Collins Hill Strickland pegmatite Strickland Quarry Schooner (circa 1985) +1 other reference
Maine Oxford County Hebron Mount Rubellite Mount Rubellite Quarries Handbook of Mineralogy (http://www.handbookofmineralogy.org/pdfs/lacroixite.pdf) +1 other reference
Tennessee Sevier County East Fork Mining District East Fork Mine (East Fork manganese mine) East Fork phosphorite bed Paris (2011)