Palermoite (original) (raw)

A valid IMA mineral species - grandfathered

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About PalermoiteHide

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Formula:

Li2SrAl4(PO4)4(OH)4

Li may be replaced by minor Na, and Sr by minor Ca.

Colour:

Colorless, white, pale pink

Lustre:

Sub-Adamantine, Vitreous

Crystal System:

Orthorhombic

Name:

For its occurrence at the Palermo #1 Mine, North Groton, New Hampshire, USA.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3066:9

IMA Classification of PalermoiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of PalermoiteHide

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8.BH.25

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1

41.7.1.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
7 : (AB)7(XO4)4Zq

19.5.5

19 : Phosphates
5 : Phosphates of Sr and Ba

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ple IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PalermoiteHide

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Colour:

Colorless, white, pale pink

Cleavage:

Perfect
{001}, perfect; on {100}, fair

Fracture:

Sub-Conchoidal, Fibrous

Density:

3.22 g/cm3 (Measured) 3.26 g/cm3 (Calculated)

Optical Data of PalermoiteHide

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RI values:

_n_α = 1.627 _n_β = 1.642 _n_γ = 1.644

2V:

Measured: 20° , Calculated: 38°

δ = 0.017

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

r > v or r < v

Chemistry of PalermoiteHide

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Mindat Formula:

Li2SrAl4(PO4)4(OH)4

Li may be replaced by minor Na, and Sr by minor Ca.

Crystallography of PalermoiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 11.556(5) Å, b = 15.847(7) Å, c = 7.315(4) Å

Ratio:

a:b:c = 0.729 : 1 : 0.462

Unit Cell V:

1,339.58 ų (Calculated from Unit Cell)

Comment:

Space Group: Imcb

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0000463 Palermoite Moore P B, Araki T (1975) Palermoite, SrLi2[Al4(OH)4(PO4)4]: Its atomic arrangement and relationship to carminite, Pb2[Fe4(OH)4(AsO4)4] American Mineralogist 60 460-465 1975 Palermo pegmatite, near North Groton, New Hampshire, USA 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.089 Å (100)
4.360 Å (64)
3.129 Å (60)
2.905 Å (53)
3.320 Å (52)
2.596 Å (48)
2.436 Å (46)

Geological EnvironmentHide

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Type Occurrence of PalermoiteHide

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Place of Conservation of Type Material:

Harvard University, Cambridge, Massachusetts, USA, 101342.

Geological Setting of Type Material:

Other Language Names for PalermoiteHide

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Relationship of Palermoite to other SpeciesHide

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Other Members of Palermoite Group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.BH. Peterchinite Zn3Zn2(OH)6As[O3(OH)3] Mon. 2/m : _B_2/m
8.BH. Reznitskyite CaMg(VO4)F Mon. 2/m : _B_2/b
8.BH. Cuprozheshengite Pb4CuZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Zheshengite Pb4ZnZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Crimsonite PbFe3+2(PO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.05 Thadeuite Ca(Mg,Fe2+)3(PO4)2(OH,F)2 Orth. 222 : _C_2221
8.BH.10 Panasqueiraite CaMg(PO4)(OH) Mon.
8.BH.10 Isokite CaMg(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Lacroixite NaAl(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Arsenatrotitanite NaTi(AsO4)O Mon. 2/m : _B_2/b
8.BH.10 Maxwellite NaFe3+(AsO4)F Mon. 2/m : _P_2/m
8.BH.10 Durangite NaAl(AsO4)F Mon. 2/m : _B_2/b
8.BH.10 Kononovite NaMg(SO4)F Mon. 2/m : _B_2/b
8.BH.15 Drugmanite Pb2Fe3+(PO4)(PO3OH)(OH)2 Mon. 2/m : _P_21/b
8.BH.20 Nigelcookite PbFe2+2V3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Cirrolite Ca3Al2(PO4)3(OH)3 (?)
8.BH.20 Penikisite Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Perloffite Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Bjarebyite Group
8.BH.20 Strontioperloffite SrMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumboperloffite PbMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Johntomaite BaFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Bjarebyite (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Kulanite Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.25 Bertossaite (Li,Na)2(Ca,Fe2+,Mn2+)Al4(PO4)4(OH,F)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Natropalermoite Na2SrAl4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.30 Sewardite CaFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.30 Carminite PbFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.35 Adelite CaMg(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite PbCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Cobaltaustinite CaCo(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Nickelaustinite CaNi(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Gabrielsonite PbFe3+(As3+O3)O Orth. m _m_2 : P m _c_21
8.BH.35 Conichalcite CaCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Arsendescloizite PbZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite-alpha PbCu(AsO4)(OH)
8.BH.35 Gottlobite CaMg(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Austinite CaZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Hermannroseite CaCu(PO4)(OH) Orth. 222 : _P_212121
8.BH.35 Tangeite CaCu(VO4)(OH) Orth. 222 : _P_212121
8.BH.40 Čechite PbFe2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.40 Khorixasite (Bi0.67◻0.33)Cu(VO4)(OH) Mon. 2/m : _P_2/m
8.BH.40 Mottramite PbCu(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Descloizite PbZn(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Pyrobelonite PbMn2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.45 Bayldonite PbCu3(AsO4)2(OH)2 Mon. 2/m : _B_2/b
8.BH.45 Vésigniéite BaCu3(VO4)2(OH)2 Mon. 2/m : _B_2/m
8.BH.50 Paganoite NiBi(AsO4)O Tric. 1 : _P_1
8.BH.55 Jagowerite BaAl2(PO4)2(OH)2 Tric.
8.BH.55 Harrisonite Ca(Fe2+,Mg)6(PO4)2(SiO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.BH.60 Attakolite CaMn2+Al4(SiO3OH)(PO4)3(OH)4 Mon. 2/m : _B_2/m
8.BH.65 Leningradite PbCu3(VO4)2Cl Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
8.BH.70 Katiarsite KTiO(AsO4) Orth. m _m_2 : P n _a_21
8.BH.70 Yurgensonite K2SnTiO2(AsO4)2 Orth. m _m_2 : P n _a_21
8.BH.75 Melanarsite K3Cu7Fe3+O4(AsO4)4 Mon. 2/m : _B_2/b
8.BH.80 Evseevite Na2Mg(AsO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.80 Moraskoite Na2Mg(PO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.85 Piccoliite NaCaMn3+2(AsO4)2O(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P b c m

Other InformationHide

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Notes:

Fluoresces white in direct X-ray beam.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for PalermoiteHide

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Reference List:

Schumer, Benjamin N., Yang, Hexiong, Downs, Robert T. (2017) Natropalermoite, Na2SrAl4(PO4)4(OH)4, a new mineral isostructural with palermoite, from the Palermo No. 1 mine, Groton, New Hampshire, USA. Mineralogical Magazine, 81 (4) 833-840 doi:10.1180/minmag.2016.080.133

Localities for PalermoiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

China
Fujian Nanping Yanping District Nanping pegmatite field Pegmatite No. 31 Rao +7 other references
Italy
Liguria Savona Province Toirano Carmo di Loano Mt. (Giogo di Toirano) Cortesogno L. et al. (1987) +2 other references
USA
Connecticut Middlesex County East Hampton (Chatham) Cobalt State Forest Quarry No. 2 (State Forest #2 Mica Mine; Carini Quarry) Schooner (1961)
Maine Oxford County Paris Mount Mica Quarry King et al. (1994)
New Hampshire Grafton County Groton Palermo No. 1 Mine (TL) Mrose (1953) +1 other reference
Rockingham County Raymond Meyers et al. (1956)
Smith No. 1 Mine Smith (2005)