Penikisite (original) (raw)

A valid IMA mineral species

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About PenikisiteHide

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Formula:

Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3

Crystal System:

Monoclinic

Name:

After Gunar Penikis (1936-1979), geophysicist and prospector of Ross River, Yukon Territory, one of the early explorers (1974-1975) in partnership with A. Kulan of the Rapid Creek area localities. It is pronounced PĔNĪ•KĬSAIT.

Kulanite-Penikisite Series.

It has the same general appearance as kulanite and both species can be found in the same crystal. The penikisite zones are generally near the edges of mixed kulanite-penikisite crystals. These zones do not follow the crystal outlines. The penikisite zones are paler and the kulanite zones are darker.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3148:2

60723637-19c0-4d47-8b97-e8043255c7e8

IMA Classification of PenikisiteHide

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IMA Formula:

BaMg2Al2(PO4)3(OH)3

Type description reference:

Classification of PenikisiteHide

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8.BH.20

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1

41.9.1.2

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
9 : (AB)5(XO4)3Zq

19.5.11

19 : Phosphates
5 : Phosphates of Sr and Ba

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Pks IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PenikisiteHide

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Transparency:

Transparent, Translucent

Streak:

Very pale green to white

Cleavage:

Distinct/Good
Two fair to good cleavages {O10} and {100}

Density:

3.79(2) g/cm3 (Measured) 3.82 g/cm3 (Calculated)

Comment:

Measured with a Berman balance

Optical Data of PenikisiteHide

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RI values:

_n_α = 1.684(2) _n_β = 1.688(2) _n_γ = 1.705(2)

2V:

Measured: 52° to 56°, Calculated: 54°

δ = 0.021

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

very strong asymmetrical dispersion with dispersion of the optic axes r>>y.

Optical Extinction:

X ~ Y > Z

Comments:

X grass-green, Y blue-green, Z pale pink

Comments:

b~Y and c:Z=-6°, although b:Y ranges from 0° to 19°

Chemistry of PenikisiteHide

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Mindat Formula:

Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3

Crystallography of PenikisiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 8.9577(4) Å, b = 12.0150(5) Å, c = 4.9070(2) Å
β = 100.505(2)°, γ = °

Ratio:

a:b:c = 0.746 : 1 : 0.408

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0019754 Penikisite Bowman M G, Downs R T, Yang H (2013) Penikisite, BaMg2Al2(PO4)3(OH)3, isostructural with bjarebyite Acta Crystallographica E69 i4-i5 2013 Mayo Mining District, Yukon Territory, Canada 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.81 Å (60)
3.094 Å (100)
3.028 Å (60)
2.915 Å (80)
2.684 Å (60)
2.6494 Å (70)

Geological EnvironmentHide

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Type Occurrence of PenikisiteHide

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General Appearance of Type Material:

The same as kulanite. Well formed blue to green crystals.

Place of Conservation of Type Material:

The Royal Ontario Museum, Toronto, Ontario, Canada (ROM No. M34172).

Associated Minerals at Type Locality:

Reference:

Mandarino, J.A., Sturman, B.D., Corlett, M.I. (1977) Penikisite, the magnesium analogue of kulanite, from the Yukon Territory, Canada. The Canadian Mineralogist: 15: 393-395.

Synonyms of PenikisiteHide

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Other Language Names for PenikisiteHide

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Relationship of Penikisite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

2 photos of Penikisite associated with Kulanite Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3

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8.BH. Crimsonite PbFe3+2(PO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH. Reznitskyite CaMg(VO4)F Mon. 2/m : _B_2/b
8.BH. Cuprozheshengite Pb4CuZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Zheshengite Pb4ZnZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Peterchinite Zn3Zn2(OH)6As[O3(OH)3] Mon. 2/m : _B_2/m
8.BH.05 Thadeuite Ca(Mg,Fe2+)3(PO4)2(OH,F)2 Orth. 222 : _C_2221
8.BH.10 Durangite NaAl(AsO4)F Mon. 2/m : _B_2/b
8.BH.10 Isokite CaMg(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Lacroixite NaAl(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Maxwellite NaFe3+(AsO4)F Mon. 2/m : _P_2/m
8.BH.10 Panasqueiraite CaMg(PO4)(OH,F) Mon.
8.BH.10 Kononovite NaMg(SO4)F Mon. 2/m : _B_2/b
8.BH.10 Arsenatrotitanite NaTi(AsO4)O Mon. 2/m : _B_2/b
8.BH.15 Drugmanite Pb2(Fe3+,Al)(PO4)(PO3OH)(OH)2 Mon. 2/m : _P_21/b
8.BH.20 Bjarebyite (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Cirrolite Ca3Al2(PO4)3(OH)3 (?)
8.BH.20 Kulanite Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Perloffite Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Johntomaite BaFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Bjarebyite Group
8.BH.20 Strontioperloffite SrMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumboperloffite PbMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Nigelcookite PbFe2+2V3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.25 Bertossaite (Li,Na)2(Ca,Fe2+,Mn2+)Al4(PO4)4(OH,F)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Palermoite (Li,Na)2(Sr,Ca)Al4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Natropalermoite Na2SrAl4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.30 Carminite PbFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.30 Sewardite CaFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.35 Adelite CaMg(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Arsendescloizite PbZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Austinite CaZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Cobaltaustinite CaCo(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Conichalcite CaCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite PbCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Gabrielsonite PbFe3+(As3+O3)O Orth. m _m_2 : P m _c_21
8.BH.35 Nickelaustinite CaNi(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Tangeite CaCu(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite-alpha PbCu(AsO4)(OH)
8.BH.35 Gottlobite CaMg(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Hermannroseite CaCu(PO4)(OH) Orth. 222 : _P_212121
8.BH.40 Čechite PbFe2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.40 Descloizite PbZn(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Mottramite PbCu(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Pyrobelonite PbMn2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Khorixasite (Bi0.67◻0.33)Cu(VO4)(OH) Mon. 2/m : _P_2/m
8.BH.45 Bayldonite PbCu3(AsO4)2(OH)2 Mon. 2/m : _B_2/b
8.BH.45 Vésigniéite BaCu3(VO4)2(OH)2 Mon. 2/m : _B_2/m
8.BH.50 Paganoite NiBi(AsO4)O Tric. 1 : _P_1
8.BH.55 Harrisonite Ca(Fe2+,Mg)6(PO4)2(SiO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.BH.55 Jagowerite BaAl2(PO4)2(OH)2 Tric.
8.BH.60 Attakolite CaMn2+Al4(SiO3OH)(PO4)3(OH)4 Mon. 2/m : _B_2/m
8.BH.65 Leningradite PbCu3(VO4)2Cl Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
8.BH.70 Katiarsite KTiO(AsO4) Orth. m _m_2 : P n _a_21
8.BH.70 Yurgensonite K2SnTiO2(AsO4)2 Orth. m _m_2 : P n _a_21
8.BH.75 Melanarsite K3Cu7Fe3+O4(AsO4)4 Mon. 2/m : _B_2/b
8.BH.80 Moraskoite Na2Mg(PO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.80 Evseevite Na2Mg(AsO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.85 Piccoliite NaCaMn3+2(AsO4)2O(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P b c m

Fluorescence of PenikisiteHide

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Not fluorescent under short-wave and long-wave ultraviolet light

Other InformationHide

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Thermal Behaviour:

A weight loss of 3.88% and an endothermic peak at 71O C.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for PenikisiteHide

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Localities for PenikisiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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