Plumboperloffite (original) (raw)

A valid IMA mineral species

Formula:

PbMn2+2Fe3+2(PO4)3(OH)3

Specific Gravity:

4.416 (Calculated)

Crystal System:

Monoclinic

Name:

The name is for the relationship to perloffite with Pb dominating the X site.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:54657:1

7ca67e9b-e577-4df2-96bb-47c2ab536932

IMA Classification of PlumboperloffiteHide

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Type description reference:

Classification of PlumboperloffiteHide

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8.BH.20

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Pplf IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PlumboperloffiteHide

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Comment:

based on the hardness of other bjarebyite-group minerals.

Cleavage:

Perfect
excellent cleavage on {100}

Fracture:

Irregular/Uneven

Density:

4.416 g/cm3 (Calculated)

Optical Data of PlumboperloffiteHide

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RI values:

_n_α = 1.870(1) _n_β = 1.880(1) _n_γ = 1.890(1)

2V:

Measured: 88° (1), Calculated: 90.5°

δ = 0.020

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

Dispersion is apparently strong, based on extinction colours and the orientation is Y = b.

Comments:

The pleochroism in shades of yellow brown is X < Z < Y.

Chemistry of PlumboperloffiteHide

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Mindat Formula:

PbMn2+2Fe3+2(PO4)3(OH)3

Chemical AnalysisHide

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Empirical formulas:

Sample ID Empirical Formula
1 (Pb0.92Ca0.04Ba0.01K0.01)0.98(Mn2+1.84Fe2+0.13)1.97(Fe3+1.97Al0.03)v2.00(P3.01O11.94)(OH)3.06

Sample references:

ID Locality Reference Notes
1 Wiperaminga Hill West Quarry, Boolcoomatta Reserve, Pastoral Unincorporated Area, South Australia, Australia Elliott, P. & Kampf, A.R. (2023): Plumboperloffite, PbMn2+2Fe3+2(PO4)3(OH)3, a new member of the bjarebyite group from Wiperaminga Hill, South Australia, Australia. Mineralogical Magazine, 87, (in press). empirical formula basis: O=15

Crystallography of PlumboperloffiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 9.176(2) Å, b = 12.340(3) Å, c = 5.009(1) Å
β = 101.01(3)°

Ratio:

a:b:c = 0.744 : 1 : 0.406

Unit Cell V:

556.74 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.105 Å (40)
4.583 Å (30)
3.158 Å (100)
2.950 Å (42)
2.738 Å (58)
2.205 Å (30)
1.992 Å (29)
1.938 Å (57)

Comments:

From Type Description.

Geological EnvironmentHide

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Type Occurrence of PlumboperloffiteHide

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General Appearance of Type Material:

The mineral forms intergrowths of subparallel, thin tabular to bladed crystals. Individual crystals are up to 40 µm in length.

Place of Conservation of Type Material:

Type material is deposited in the mineralogical collections of the South Australian Museum, North Terrace, Adelaide, South Australia 5000, Australia, registration number G34868

Geological Setting of Type Material:

pegmatites belong to the beryl-columbite phosphate-rare element type in the classification of Černý

Associated Minerals at Type Locality:

Synonyms of PlumboperloffiteHide

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Relationship of Plumboperloffite to other SpeciesHide

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Other Members of this group:

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8.BH. Crimsonite PbFe3+2(PO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH. Reznitskyite CaMg(VO4)F Mon. 2/m : _B_2/b
8.BH. Cuprozheshengite Pb4CuZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Zheshengite Pb4ZnZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Peterchinite Zn3Zn2(OH)6As[O3(OH)3] Mon. 2/m : _B_2/m
8.BH.05 Thadeuite Ca(Mg,Fe2+)3(PO4)2(OH,F)2 Orth. 222 : _C_2221
8.BH.10 Durangite NaAl(AsO4)F Mon. 2/m : _B_2/b
8.BH.10 Isokite CaMg(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Lacroixite NaAl(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Maxwellite NaFe3+(AsO4)F Mon. 2/m : _P_2/m
8.BH.10 Panasqueiraite CaMg(PO4)(OH) Mon.
8.BH.10 Kononovite NaMg(SO4)F Mon. 2/m : _B_2/b
8.BH.10 Arsenatrotitanite NaTi(AsO4)O Mon. 2/m : _B_2/b
8.BH.15 Drugmanite Pb2Fe3+(PO4)(PO3OH)(OH)2 Mon. 2/m : _P_21/b
8.BH.20 Bjarebyite (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Cirrolite Ca3Al2(PO4)3(OH)3 (?)
8.BH.20 Kulanite Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Penikisite Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Perloffite Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Johntomaite BaFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Bjarebyite Group
8.BH.20 Strontioperloffite SrMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Nigelcookite PbFe2+2V3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.25 Bertossaite (Li,Na)2(Ca,Fe2+,Mn2+)Al4(PO4)4(OH,F)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Palermoite (Li,Na)2(Sr,Ca)Al4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Natropalermoite Na2SrAl4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.30 Carminite PbFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.30 Sewardite CaFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.35 Adelite CaMg(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Arsendescloizite PbZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Austinite CaZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Cobaltaustinite CaCo(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Conichalcite CaCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite PbCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Gabrielsonite PbFe3+(As3+O3)O Orth. m _m_2 : P m _c_21
8.BH.35 Nickelaustinite CaNi(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Tangeite CaCu(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite-alpha PbCu(AsO4)(OH)
8.BH.35 Gottlobite CaMg(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Hermannroseite CaCu(PO4)(OH) Orth. 222 : _P_212121
8.BH.40 Čechite PbFe2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.40 Descloizite PbZn(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Mottramite PbCu(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Pyrobelonite PbMn2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Khorixasite (Bi0.67◻0.33)Cu(VO4)(OH) Mon. 2/m : _P_2/m
8.BH.45 Bayldonite PbCu3(AsO4)2(OH)2 Mon. 2/m : _B_2/b
8.BH.45 Vésigniéite BaCu3(VO4)2(OH)2 Mon. 2/m : _B_2/m
8.BH.50 Paganoite NiBi(AsO4)O Tric. 1 : _P_1
8.BH.55 Harrisonite Ca(Fe2+,Mg)6(PO4)2(SiO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.BH.55 Jagowerite BaAl2(PO4)2(OH)2 Tric.
8.BH.60 Attakolite CaMn2+Al4(SiO3OH)(PO4)3(OH)4 Mon. 2/m : _B_2/m
8.BH.65 Leningradite PbCu3(VO4)2Cl Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
8.BH.70 Katiarsite KTiO(AsO4) Orth. m _m_2 : P n _a_21
8.BH.70 Yurgensonite K2SnTiO2(AsO4)2 Orth. m _m_2 : P n _a_21
8.BH.75 Melanarsite K3Cu7Fe3+O4(AsO4)4 Mon. 2/m : _B_2/b
8.BH.80 Moraskoite Na2Mg(PO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.80 Evseevite Na2Mg(AsO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.85 Piccoliite NaCaMn3+2(AsO4)2O(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P b c m

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for PlumboperloffiteHide

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Localities for PlumboperloffiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia (TL)
South Australia Pastoral Unincorporated Area Boolcoomatta Reserve (Boolcoomata Station) Wiperaminga Hill West Quarry (Wipperaminga Hill) (TL) Miyawaki et al. (2020) +1 other reference